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U.S.-France Cooperative Research: Synthetic Strategies, Structural Aspects and Cooperative Behavior of Charge- Transfer Compounds.

美法合作研究：电荷转移化合物的合成策略、结构方面和合作行为。

基本信息

批准号：
9217191
负责人：
Kim Dunbar
金额：
$ 1.67万
依托单位：
Michigan State University
依托单位国家：
美国
项目类别：
Standard Grant
财政年份：
1993
资助国家：
美国
起止时间：
1993-06-01 至 1997-05-31
项目状态：
已结题

来源：
https://www.nsf.gov/awardsearch/showAward?AWD_ID=9217191&HistoricalAwards=false
关键词：
U.S.France Cooperative Research Synthetic

项目摘要

This three-year award supports U.S.-France cooperative research in inorganic and organometallic chemistry between Kim Dunbar of Michigan State University and Patrick Batail of the University of Paris, South (Orsay). The objective of the research is to develop low dimensional materials that have useful electrical and magnetic properties. The investigators will use dinuclear and cluster metal-metal bonded compounds as precursors to reactions with redox-active organic molecules which have functional groups capable of attaching to a metal. They will synthesize three main types of materials: (1) covalently-linked one dimensional materials consisting of alternating metal and p-organic groups; (2) network polymers comprised of cross-linked metal units; and (3) metal complexes of new phosphorus ligands. These are interesting materials because of their potential for electrical and magnetic properties. The Michigan State group brings to this collaboration experience in molecular chemistry. They have been involved in the synthesis of new metal precursors for the design of molecular based charge transfer polymers and materials. This is complemented by the French group's expertise in theoretical solid state chemistry, conductivity, magnetism, and their work on transition metal clusters. The collaboration allows the U.S. investigator to expand her research to the materials area by taking advantage of French expertise.

这个为期三年的奖项支持美国-法国合作研究在无机和有机金属化学方面，密歇根州立大学和密歇根大学的帕特里克巴特尔巴黎，南（奥赛）。研究的目的是开发低维材料，具有有用的电和磁性研究人员将使用双核和作为反应前体的簇合金属-金属键合化合物用具有官能团的氧化还原活性有机分子能够附着在金属上。他们将合成三种主要的材料类型：（1）共价连接的一维由交替的金属和p-有机基团组成的材料; (2)由交联的金属单元组成的网络聚合物;和 (3)新的磷配体的金属配合物。这些是有趣的材料，因为它们具有电和磁性。密歇根州立大学集团为这种协作体验带来了在分子化学中。他们参与了用于分子基电荷设计的新金属前体转移聚合物和材料。这一点得到了法国小组在理论固体化学方面的专业知识，导电性，磁性，以及他们在过渡金属方面的工作集群这项合作使美国调查人员能够利用以下优势将她的研究扩展到材料领域：法国专业知识