The Electrochemical Polymerization of Bis-2-Pyrrolyl Conjugated Monomers to Form Highly Conducting Polymers

双-2-吡咯基共轭单体的电化学聚合形成高导电聚合物

• 批准号: 9307732
• 负责人: John Reynolds
• 金额: $ 27万
• 依托单位: University of Florida
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1993
• 资助国家: 美国
• 起止时间: 1993-08-01 至 1996-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9307732&HistoricalAwards=false
• 关键词: Electrochemical; Polymerization; Bis; Pyrrolyl; Conjugated

9307732 Reynolds This award is made in the Advanced Materials and Processing Program in support of the collaborative research of Professors Reynolds and Katritzky at the University of Florida. Support is provided by the Divisions of Chemistry and Materials Research. Novel bis-2-pyrrolyl conjugated monomers containing substituted benzenes, carbazoles and fluorenes as internal units will be synthesized and electrochemically polymerized to highly conducting polymers. The main goal of the research is to develop a fundamental understanding of the electropolymerization and film-deposition processes that occur during oxidative polymerization and to direct the electrosynthesis to form polymers with enhanced properties. %%% Polypyrroles with higher degrees of long range order will be synthesized which will have higher electrical conductivities and improved environmental stabilities relative to presently available polymers. These aspects are important in electrostatic charge dissipation and electric field grading applications. ***

9307732雷诺兹该奖项是在先进材料和加工计划，以支持雷诺兹教授和Katritzky在佛罗里达大学的合作研究。支持由化学和材料研究部门提供。 将合成含有取代苯、咔唑和芴作为内部单元的新型双-2-吡咯基共轭单体，并通过电化学聚合得到高导电聚合物。该研究的主要目标是对氧化聚合过程中发生的电聚合和膜沉积过程有一个基本的了解，并指导电合成形成具有增强性能的聚合物。 将合成具有更高长程有序度的聚吡咯，其相对于目前可用的聚合物将具有更高的电导率和改善的环境稳定性。这些方面在静电荷耗散和电场分级应用中是重要的。 ***