Preparation, Characterization, and Chemistry of Technetium Oxide Complexes

氧化锝配合物的制备、表征和化学

• 批准号: 9309001
• 负责人: Lynn Francesconi
• 金额: $ 1.8万
• 依托单位: CUNY Hunter College
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1993
• 资助国家: 美国
• 起止时间: 1993-07-01 至 1995-12-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9309001&HistoricalAwards=false
• 关键词: Preparation; Characterization; Chemistry; Technetium; Oxide

This award in the Research Planning Grant for women program is made by the Chemistry Division to Dr. Lynn C. Francesconi of the Chemistry Department, Hunter College-City University of New York. The bonding, structure, and reactivity of technitium-oxygen compounds would be investigated. During the planning period, two strategies for incorporating Tc, and its congener Re, into polyoxoanions of molybdenum and tungsten would be attempted. Successful completion of this preliminary research would allow work to proceed on synthesis of a wide variety of compounds containing technitium-oxygen bonds. A long-term goal of research in this area is to enable the separation or immobilization of technetium, which has a long-lived isotope common in nuclear waste site contaminants, in borosilicate or phosphate glasses.

该奖项在研究规划补助金的妇女计划是 化学部发给林恩C博士的弗兰切斯科尼 纽约市立大学亨特学院化学系 约克。 的成键、结构和反应性 将研究技术氧化合物。 期间 规划期间，纳入技术合作的两个战略， 同源物Re，转化为钼和钨的多氧阴离子 将会尝试。 圆满完成本次初步 研究将使综合广泛的 各种含有氧键的化合物。 一 该领域研究的长期目标是使 锝的分离或固定， 核废料场污染物中常见的长寿命同位素， 在硼硅酸盐或磷酸盐玻璃中。