A top-down approach to synthesising high-value fluorocarbons

自上而下合成高价值碳氟化合物的方法

• 批准号: FT220100738
• 负责人: A/Prof Rowan Young
• 金额: $ 64.17万
• 依托单位: The University of Queensland
• 依托单位国家: 澳大利亚
• 项目类别: ARC Future Fellowships
• 财政年份: 2023
• 资助国家: 澳大利亚
• 起止时间: 2023-05-01 至 2027-04-30
• 项目状态: 未结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/FT220100738
• 关键词: top; down; approach; synthesising; value

Fluorocarbons' ability to impart high stability, solubility, and unique reactivity to host molecules renders them invaluable in agrochemicals, pharmaceuticals, polymers and surfactants. Their robustness also renders them environmentally persistent. There are no industrially utilised methods for the re-purposing or recycling of fluorocarbons. This project aims to generate new methods for the selective activation of carbon-fluorine bonds in polyfluorocarbons, allowing their incorporation or repurposing into high value chemicals and/or easy derivitisation to access a plethora of new fluorocarbon products. Expected outcomes will allow new processing methods to value add to fluorocarbons while preventing their environmental release.

氟碳化合物具有高稳定性、溶解度和宿主分子的独特反应性，因此在农用化学品、药品、聚合物和表面活性剂中具有不可替代的价值。它们的健壮性也使它们具有环境持久性。目前还没有工业上使用的重新利用或回收氟碳化合物的方法。该项目旨在产生选择性活化多氟碳化合物中的碳氟键的新方法，使其能够并入或重新用于高价值化学品和/或易于衍生，以获得大量新的氟碳产品。预期的结果将允许新的加工方法为氟碳化合物增值，同时防止其向环境释放。