Synthetic Applications of Photocycloadditions

光环加成的合成应用

• 批准号: 9319512
• 负责人: Michael Crimmins
• 金额: $ 24.3万
• 依托单位: University of North Carolina at Chapel Hill
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1994
• 资助国家: 美国
• 起止时间: 1994-03-01 至 1998-02-28
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9319512&HistoricalAwards=false
• 关键词: Synthetic; Applications; Photocycloadditions

9319512 Crimmins The focus of this research is the study of the effects of substitution on the tethering chain in intramolecular enone-olefin photocycloadditions with regard to stereochemical control. The photoproducts will serve as precursors for the synthesis of a variety of natural product types including taxusin, magellaninone, serratinine and lubiminol. %%% With this renewal award, the Synthetic Organic Program is supporting the research of Dr. Michael T. Crimmins of the Department of Chemistry at the University of North Carolina, Chapel Hill. Professor Crimmins will focus his work on the use of photocycloadditons for the synthesis of a number of interesting natural products. ***

小行星9319512 本研究的重点是研究 分子内束缚链上的取代 烯酮-烯烃光环加成反应 控制 光产物将作为前体， 合成多种天然产物类型，包括 红豆杉素、麦哲伦酮、锯齿素和鲁比米诺。 %有了这个更新奖，合成有机计划是 支持Michael T.共和党人 北卡罗来纳州大学化学系， 查佩尔山。 布雷明斯教授将把他的工作重点放在 用于合成许多 有趣的天然产品。 ***