The Chemistry of Reduced Fullerenes

还原富勒烯的化学

• 批准号: 9404704
• 负责人: Mark Meier
• 金额: $ 28万
• 依托单位: University of Kentucky Research Foundation
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1994
• 资助国家: 美国
• 起止时间: 1994-09-01 至 1997-11-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9404704&HistoricalAwards=false
• 关键词: Chemistry; Reduced; Fullerenes

9404704 Meier The focus of this research is the preparation and characterization of reduced fullerenes, particularly those formed from the Birch reduction of C60. The chemical reactivity of these compopunds will be compared to that of the parent system. Substitution wih hydrogen atoms, alkyl groups, electron donating functional groups and electron withdrawing groups will all be used to modify the properties of the fullerenes. %%% With this award, the Synthetic Organic Program supports the research of Dr. Mark S. Meier of the Department of Chemistry of the University of Kentucky. Professor Meier will focus his work on the investigation of the chemical behavior of the class of compounds known as reduced fullerenes. These compounds have potential as materials having tailored electronic and optical properties.

9404704 Meier本研究的重点是还原富勒烯的制备和表征，特别是那些由C60的Birch还原形成的富勒烯。 这些复合物的化学反应性将与母体系统的化学反应性进行比较。 氢原子、烷基、给电子官能团和吸电子基团的取代都将用于改变富勒烯的性质。 有了这个奖项，合成有机计划支持博士的研究。肯塔基州大学化学系的Meier说。 Meier教授将把工作重点放在研究被称为还原富勒烯的化合物的化学行为上。 这些化合物具有作为具有定制的电子和光学性质的材料的潜力。