Energetic and Structural Studies of Functional Group Pairs for Materials Research

用于材料研究的官能团对的能量和结构研究

• 批准号: 9423726
• 负责人: Mark Hollingsworth
• 金额: $ 33.65万
• 依托单位: Indiana University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1995
• 资助国家: 美国
• 起止时间: 1995-06-01 至 2000-05-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9423726&HistoricalAwards=false
• 关键词: Energetic; Structural; Studies; Functional; Group

In this project funded by the Advanced Materials Program of the Chemistry Division and the Solid State Chemistry program of the Division of Materials Research, Hollingsworth will design organic solids with specified structure, reactivity, and physical properties. The energetics of organic functional group interactions in the solid state will be developed by studying guest species in channel inclusion compounds. The interaction energies obtained will be useful in materials chemistry for facilitating supramolecular design and synthesis of new organic materials. The ultimate goal is to synthesize organic molecular crystals with the same degree of stereocontrol that is now commonly achieved in single molecule organic synthesis. %%% This research program represents a rational and holistic approach to understanding intermolecular forces in organic solids and is expected to greatly facilitate the design and development of new organic materials. Among the likely applications of this proposed research is the fabrication of devices with nonlinear optical properties useful in laser-based systems, such as communications.

在这个由化学先进材料计划资助的项目中， 司和司的固态化学计划 材料研究，霍林斯沃思将设计有机固体与 特定的结构、反应性和物理性质。 的能量学 有机官能团相互作用的固体状态将是 通过研究通道包合物中的客体物种而开发的。 的 所获得的相互作用能将在材料化学中用于 促进新有机化合物的超分子设计和合成， 材料. 最终目标是合成有机分子晶体 具有与现在通常实现的相同程度的立体控制， 单分子有机合成 %这项研究计划代表了一种理性和全面的方法， 了解有机固体中的分子间力，并有望 大大促进了新型有机材料的设计和开发。 这项研究的可能应用之一是 具有非线性光学特性的器件的制造 基于激光的系统，例如通信。