Catalytic Asymmetric Allylic Oxidation, Epoxidation, and Dihydroxylation

催化不对称烯丙基氧化、环氧化和二羟基化

• 批准号: 9501867
• 负责人: Merritt Andrus
• 金额: $ 21万
• 依托单位: Purdue Research Foundation
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1995
• 资助国家: 美国
• 起止时间: 1995-04-15 至 1998-03-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9501867&HistoricalAwards=false
• 关键词: Catalytic; Asymmetric; Allylic; Oxidation; Epoxidation

The focus of this research is the development of methods for allylic oxidation using chiral Cu(I) complexes and peresters to give chiral non-racemic allylesters. The focus of the educational plan involves the development of course content for both undergraduate and graduate students. With this CAREER award, the Synthetic Organic Program is supporting the research and educational plan of Dr. Merritt B. Andrus of the Department of Chemistry at Purdue University. Professor Andrus will focus his research efforts on the development of new methods for the catalytic asymmetric oxidation of olefins. The focus of Professor Andrus' educational plan involves the development of course content for both undergraduate and graduate students.

本研究的重点是开发使用手性 Cu(I) 配合物和过酸酯进行烯丙基氧化以得到手性非外消旋烯丙酯的方法。教育计划的重点涉及本科生和研究生课程内容的开发。 凭借这一职业奖，合成有机项目正在支持普渡大学化学系 Merritt B. Andrus 博士的研究和教育计划。 安德鲁斯教授的研究重点是开发烯烃催化不对称氧化的新方法。 安德鲁斯教授的教育计划的重点是为本科生和研究生开发课程内容。