Self Assembly of One, Two and Three Dimensional Supramolecular Structures

在有机动力学项目的资助下，弗吉尼亚理工学院和州立大学的吉布森教授将开发将轮烷系统自组装成超分子结构的方法。这种方法取决于联吡啶盐和32-冠-10醚之间的主客体关系。一旦组装，结构将通过共价键的形成而稳定下来。规划了无数的结构主题，包括线性、分支和最终树状类型的建筑。这些类型的系统有望在光学和电子设备、催化和大众运输媒体领域进行新的冒险。通过轮烷和冠醚的自组装，设计了一类新的超分子结构。一旦通过共价键的形成进行组装和固定，就可以探索这些类型的结构的光和电子设备性能。此外，预计它们具有催化特性，并可用作大众运输介质。？？▓？▒？D h F？t─-F V 9V=RRV─9FevH─？R：\WWUSER\TEMPLATE\NORMAL.DOT

With funding from the Organic Dynamics Program, Professor Gibson of Virginia Polytechnic Institute and State University will develop the methodology of self assembling rotaxane systems into supramolecular structures. This methodology depends on the host-guest relationship between bipyridine salts and 32-crown-10 ethers. Once assembled, the structure will be stabilized with covalent bond formation. A myriad of structural motifs is planned and incudes linear, branched and ultimately dentritic type architecture. These types of systems hold promise for new ventures in the areas of photo and electro devices, catalysis and mass transport media. A new class of supramolecular structures is planned from the self assembly of rotaxanes and crown ethers. Once assembled and fixed via covalent bond formation, these types of structures can be explored for their photo and electro device properties. Further, they are anticipated to have catayltic properties and may be used as a mass transport media. + Ûª▓ ÑOh ª' +'ª▒0 Ý + ] $ H l + ¢ ╗ S u m m a r y I n f o r m a t i o n ( ++++++++++++ Û ++++++++++++ ++++++++++++ ++++++++++++ D h + F÷t ─- +F +V 9V=rRv ─+ 9FevH─ª + R:\WWUSER\TEMPLATE\NORMAL.DOT