CAREER: The Relationship Between Surface Conductivity and Surface Reaction Pathways

职业：表面电导率与表面反应途径之间的关系

• 批准号: 9523936
• 负责人: Kirk Schulz
• 金额: $ 24.9万
• 依托单位: Michigan Technological University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1995
• 资助国家: 美国
• 起止时间: 1995-08-15 至 2000-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9523936&HistoricalAwards=false
• 关键词: CAREER; Relationship; Between; Surface; Conductivity

ABSTRACT Kirk Schulz This is an investigation of the variations in reactivity for desulfurization of several alkyl and cyclic organosulfur compounds on model molybdenum sulfide catalysts as a function of surface conductivity. Among issues addressed are selectivity changes as a function of surface conductivity, the catalytic activity of sulfur vacancies, the correlation of surface conductivity with catalytic activity of sulfide materials, and the similarities and differences between sulfided single crystals and single crystals of sulfides. The issues addressed in this study are important in extending the very successful empirical technology for desulfurizing crude oil to other systems such as flue gas and wastewater. This is a Faculty Early Career Development award. It includes an effort to introduce a "writing-across-the curriculum" (WAC) program to improve presentation skills of chemical engineering undergraduates, the development of a tool to assess writing skills, and the application of this tool to assess the effectiveness of this approach. ***

柯克·舒尔茨 本文研究了几种烷基和环状有机硫化合物在硫化钼模型催化剂上的脱硫反应活性随表面电导率的变化。 所解决的问题包括作为表面电导率函数的选择性变化、硫空位的催化活性、表面电导率与硫化物材料催化活性的相关性以及硫化单晶和硫化物单晶之间的相似性和差异。 在这项研究中所解决的问题是非常重要的经验技术扩展到其他系统，如烟道气和废水的原油。 这是一个教师早期职业发展奖。 它包括努力引入一个“跨课程写作”（WAC）计划，以提高化学工程本科生的表达能力，开发一个工具来评估写作技能，并应用该工具来评估这种方法的有效性。 ***