Selective Synthesis of Hydrocarbons from Syngas Using Binary Oxide Supported Cobalt-Nickel Alloy Catalysis

摘要CTS-9529182本研究的目的是考察一系列复合氧化物担载的钴镍催化剂上的一氧化碳加氢反应。一个主要的兴趣是汽油的产率和选择性-C5到C11碳氢化合物。对负载型催化剂进行了单独测试和与氢交换ZSM-5沸石的联合测试。考察了温度、压力、空速、一氧化碳/氢比、沸石/催化剂比等工艺参数对稳态产物分布的影响。这一奖项授予一所历史悠久的黑人学院，是根据《本科院校研究公告》颁发的。这项研究与从煤炭、天然气或生物质等非石油来源生产汽油有关。

ABSTRACT CTS-9529182 The objective of this research is the investigation of the hydrogenation of carbon monoxide over cobalt-nickel Fischer-Tropsch catalysts supported on a series of mixed oxides, including manganese-zirconium oxide, manganese-vanadium oxide, and niobium-zirconium oxide. A major interest is the yield and selectivity in the gasoline range - C5 to C11 hydrocarbons. The supported catalysts are tested alone as well as in combination with hydrogen-exchanged ZSM-5 zeolite. The effects of process variables such as temperature, pressure, space velocity, carbon monoxide/hydrogen ratio, and zeolite/catalyst ratio on steady-state product distributions are also investigated. This award to a historically black college is made under the Research in Undergraduate Institutions announcement. The research is relevant to the production of gasoline from nonpetroleum sources such as coal, natural gas or biomass.