Heterogeneous Chemistry of Halogen-, Nitrogen- and Sulfur-Containing Acids and Salts
Heterogeneous Chemistry of Halogen-, Nitrogen- and Sulfur-Containing Acids and Salts
批准号:
9711970
负责人:
A. Castleman
金额:
$39.61万
依托单位国家:
美国
项目类别:
Continuing Grant
财政年份:
1997
资助国家:
美国
项目状态:
已结题
起止时间:
1997-09-01 至 2001-08-31
中文摘要
9711970卡斯特尔曼该项目是对含有卤素、氮和硫分子的电解液系统进行研究,这些分子对大气很重要。本工作的重点是通过分子簇方法研究电解质在水体系中的吸收/溶解以及相关的气粒转化过程。对于与大气现象高度相关的一组较小的电解液体系,也将研究电解液体系的热化学和反应机理。重点将主要放在卤素(作为酸的形式)、卤素含氧酸和盐,以及由氮和硫酸盐化合物组成的一些相关的电解液种类。两种光谱方法将被用来研究与电解液溶解有关的过程:(1)溶剂化时的共振电子态能量变化;(2)光耗尽。这项研究将使用配备适当可调谐激光的飞行时间质谱仪系统。该项目的结果将提供关于通过分子聚集发生的相互竞争的化学和物理过程的相对重要性的新信息。这些非均匀过程对于理解极地平流层冰晶对大气分子的吸收,以及对于阐明发生在对流层低层的气体到粒子的转化机制具有潜在的重要意义。
英文摘要
9711970 Castleman The project is a study of electrolyte systems that contain halogens, nitrogen and sulfur molecules which are important to the atmosphere. The main focus of the work is to study the uptake/dissolution of electrolytes in aqueous systems and related gas-to-particle processes via a molecular cluster approach. The thermochemistry and reaction mechanisms of electrolyte systems will also be investigated for a smaller set of electrolyte systems which have high relevance to atmospheric phenomena. The main emphasis will be on halogens (as the acid forms), halogen oxyacids and salts, and on some related electrolyte species composed of nitrogen and sulfate compounds. Two spectroscopic approaches will be employed to study the processes associated with electrolyte dissolution: (1) resonant electronic state energy change upon solvation; and (2) photodepletion. A time-of-flight mass spectrometer system configured with appropriate tunable lasers will be used for the research. Results from the project will provide new information on the relative importance of competing chemical and physical processes that occur via molecular aggregation. These heterogeneous processes have potential importance for understanding the uptake of atmospheric molecules by polar stratospheric ice crystals, and for elucidating gas-to-particle conversion mechanisms that occur in the lower troposphere.
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Solvated Salts and Acids: Contributions to Basic Understanding of Nucleation, Particle Growth, and Aerosol Chemistry
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批准号:0715014
-
项目类别:Continuing Grant
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资助金额:$56.08万
-
财政年份:2007
-
负责人:A. Castleman
-
依托单位:
Femtochemistry VII Conference - Washington DC
-
批准号:0521796
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项目类别:Standard Grant
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资助金额:$0.8万
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财政年份:2005
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负责人:A. Castleman
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依托单位:
Solvated Salts and Acids: Contributions to Basic Understanding of Nucleation, Particle Growth and Aerosol Chemistry
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批准号:0411954
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项目类别:Standard Grant
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资助金额:$62.26万
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财政年份:2004
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负责人:A. Castleman
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依托单位:
Contributions to Elucidating Heterogeneous Chemistry Involving Ice Crystals and Aqueous Aerosols
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批准号:0089233
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项目类别:Standard Grant
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资助金额:$37.37万
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财政年份:2001
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负责人:A. Castleman
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依托单位:
Developing Foundations for Catalyst Design: From Cluster Science to Industrial Applications
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批准号:9906341
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项目类别:Standard Grant
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资助金额:$36.0万
-
财政年份:1999
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负责人:A. Castleman
-
依托单位:
Designing Transition Metal Oxide Catlysts: From Cluster Science to Industrial Applications
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批准号:9632771
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项目类别:Standard Grant
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资助金额:$35.53万
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财政年份:1996
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负责人:A. Castleman
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依托单位:
Elucidating the Heterogeneous Chemistry of Nitrogen Containing Species Involving Aqueous Droplets, Ice Crystals and Gas-to-Particle Conversion
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批准号:9321660
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项目类别:Continuing Grant
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资助金额:$63.5万
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财政年份:1994
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负责人:A. Castleman
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依托单位:
U.S.-Japan Seminar: Dynamics, Photophysical and Photochemical Events Involving Clusters; March, 1994; Hawaii
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批准号:9217992
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项目类别:Standard Grant
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资助金额:$1.4万
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财政年份:1993
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负责人:A. Castleman
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依托单位:
US-Poland Research on Elucidating Mechanisms of HeterogenousChemical Reactions of Environmental Importance
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批准号:9208271
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项目类别:Standard Grant
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资助金额:$3.45万
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财政年份:1992
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负责人:A. Castleman
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依托单位:
Heterogeneous Atmospheric Chemistry: Elucidating the Importantce of Reactions Involving Aqueous Droplets and Ice Crystals Through Cluster Research
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批准号:9015855
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项目类别:Continuing Grant
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资助金额:$61.51万
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财政年份:1991
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负责人:A. Castleman
-
依托单位:
US-Austria Cooperative Research: Production and Stability (Unimolecular Decay) of Singly and Multiply Charged vdW Cluster Ions
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批准号:8813492
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项目类别:Standard Grant
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资助金额:$1.48万
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财政年份:1989
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负责人:A. Castleman
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依托单位:
Investigation of Aerosol Formation and Heterogeneous Chemistry on a Molecular Level: The Reactivity, Stability, and Photochemistry of Small Clusters of Atmospheric Interest
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批准号:8714095
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项目类别:Continuing Grant
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资助金额:$62.09万
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财政年份:1987
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负责人:A. Castleman
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依托单位:
U.S.-Austria Cooperative Research: Cluster Distributions, Origin of Magic Numbers, and Metastability of Cluster Ions Produced by Electron Impact and Photoionization (Chemistry)
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批准号:8420823
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项目类别:Standard Grant
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资助金额:$1.33万
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财政年份:1985
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负责人:A. Castleman
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依托单位:
Heterogeneous Chemistry Studies of the Formation, Stability,And Reactions of Small Clusters Important in Atmospheric Chemistry
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批准号:8212948
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项目类别:Standard Grant
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资助金额:$12.17万
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财政年份:1982
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负责人:A. Castleman
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依托单位:
Heterogeneous Chemistry Studies of the Formation, Stability,and Reactions of Small Clusters Important in Atmospheric Chemistry
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批准号:8204010
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项目类别:Continuing Grant
-
资助金额:$83.85万
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财政年份:1982
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负责人:A. Castleman
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依托单位:
Heterogeneous Chemistry: Studies of the Formation, Stability, and Reactions of Small Clusters Important in Gas-To-Particle Conversion Reactions in the Troposphere
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批准号:7913801
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项目类别:Continuing Grant
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资助金额:$34.64万
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财政年份:1979
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负责人:A. Castleman
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依托单位:
Heterogeneous Nucleation: the Properties of Small Clusters And Atmospheric Ions
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批准号:7614914
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项目类别:Standard Grant
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资助金额:$28.08万
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财政年份:1976
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负责人:A. Castleman
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依托单位:
Heterogeneous Nucleation- Nucleation About Ions, the Properties of Small Clusters and Atmospheric Ions
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批准号:7306388
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项目类别:Standard Grant
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资助金额:$2.5万
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财政年份:1973
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负责人:A. Castleman
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依托单位:
国内基金
海外基金
SCIENCE CHINA Chemistry
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批准号:21224001
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项目类别:专项基金项目
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资助金额:24.0万元
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批准年份:2012
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负责人:朱晓文
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依托单位:
Science China Chemistry
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批准号:21024801
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项目类别:专项基金项目
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资助金额:24.0万元
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批准年份:2010
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负责人:朱晓文
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依托单位:
运用Linkage Chemistry合成新型聚合物缀合物和刷形共聚物
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批准号:20974058
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项目类别:面上项目
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资助金额:12.0万元
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批准年份:2009
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负责人:袁金颖
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依托单位: