U.S.-France Cooperative Research: Synthetic Applications of Non-Polymerizable Monomers in Living Cationic Polymerization; Kinetic and Mechanistic Studies

美法合作研究：不可聚合单体在活性阳离子聚合中的合成应用；

• 批准号: 9815239
• 负责人: Rudolf Faust
• 金额: $ 1.5万
• 依托单位: University of Massachusetts Lowell
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1999
• 资助国家: 美国
• 起止时间: 1999-07-01 至 2003-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9815239&HistoricalAwards=false
• 关键词: U.S.; France; Cooperative; Research; Synthetic

9815239FaustThis three-year award in support of U.S.-France collaborative research in polymer materials involves Rudolf Faust of the University of Massachusetts and Jean-Pierre Vairon of the Universite Pierre et Marie Curie. The objective of the research is to determine the kinetic and thermodynamic parameters of polymers via cationic routes. The US investigator brings to this collaboration expertise on the engineering of polymers. This is complemented by the French investigator's expertise in the kinetics and mechanistic studies of polymers. The collaboration also takes advantage of a unique, custom designed stop-flow device with UV-vis detection for fast reactions at the Universite Pierre et Marie Curie. The research will advance understanding of polymer structures and the elementary steps in polymerization. This knowledge is essential for synthesis of tailor-made polymers. Designer polymers have medical applications and can be used in drug delivery systems.

98152339浮士德这项为期三年的奖项旨在支持美法在高分子材料领域的合作研究，参与者包括马萨诸塞大学的鲁道夫·浮士德和皮埃尔与玛丽居里大学的让-皮埃尔·瓦朗。研究的目的是通过阳离子途径确定聚合物的动力学和热力学参数。美国研究者为这次合作带来了聚合物工程方面的专业知识。法国研究者在聚合物动力学和机理研究方面的专业知识补充了这一点。该合作还利用了皮埃尔和玛丽居里大学的一种独特的、定制设计的具有紫外-可见检测的快速反应止流装置。该研究将促进对聚合物结构和聚合基本步骤的理解。这些知识对于合成定制聚合物是必不可少的。设计聚合物具有医疗应用，可用于药物输送系统。