Exploring the Chemistry of ansa-Chromocene Complexes: Their Fundamental Reactivity and Potential Application as Homogeneous Catalysts

探索 ansa-二茂铬络合物的化学：它们的基本反应性和作为均相催化剂的潜在应用

• 批准号: 9816730
• 负责人: Pamela Shapiro
• 金额: $ 35万
• 依托单位: Regents of the University of Idaho
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1999
• 资助国家: 美国
• 起止时间: 1999-03-01 至 2003-04-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9816730&HistoricalAwards=false
• 关键词: Exploring; Chemistry; ansa; Chromocene; Complexes

Dr. Pamela Shapiro, Department of Chemistry, University of Idaho, is supported by the Inorganic, Bioinorganic and Organometallic Chemistry Program of the Chemistry Division to (i) explore the chemistry and possible catalytic applications of new (bent) ansa-chromocene systems to polymerization processes, (ii) modify the ansa-metallocene ligand framework to potentially improve the catalytic properties, and (iii) examine the behavior of these systems under high hydrogen, ethylene, carbon monoxide (and others) gas pressures. The latter objective will involve a collaboration with scientists at the Pacific Northwest National Laboratories (PNNL).Two benefits will accrue from this NSF support: (1) development and characterization of new, potentially useful ansa-metallocene homogeneous catalysts to improve certain polymerization processes, and (2) expose graduate and undergraduate students and post-doctoral associates of the University of Idaho to cutting-edge technology and learn state-of-the-art techniques through a collaborative partnership with the scientific staff of the Pacific Northwest National Laboratories.

爱达荷州大学化学系Pamela Shapiro博士得到化学系无机、生物无机和有机化学项目的支持，以（i）探索新（弯曲）柄型茂金属体系在聚合过程中的化学和可能的催化应用，（ii）修饰柄型茂金属配体骨架以潜在地改善催化性能，以及（iii）检查这些系统在高氢气、乙烯、一氧化碳（和其他）气体压力下的行为。后一个目标将涉及与太平洋西北国家实验室（PNNL）的科学家合作。NSF的支持将带来两个好处：（1）开发和表征新的、潜在有用的柄型-茂金属均相催化剂以改进某些聚合方法，以及（2）让爱达荷州大学的研究生、本科生和博士后接触尖端技术，并学习最先进的技术。通过与太平洋西北国家实验室的科学工作人员的合作伙伴关系，