The Development of Novel Cyclopentadienyl Ligands ContainingGroup 13 Element (B, A1 and Ga) Heteroannular Bridges

含13族元素（B、A1、Ga）异环桥的新型环戊二烯基配体的研制

• 批准号: 9213875
• 负责人: Pamela Shapiro
• 金额: $ 1.8万
• 依托单位: Regents of the University of Idaho
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 1992
• 资助国家: 美国
• 起止时间: 1992-08-01 至 1994-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9213875&HistoricalAwards=false
• 关键词: Development; Novel; Cyclopentadienyl; Ligands; ContainingGroup

This research planning grant will enable Dr. Pamela Shapiro to initiate a research program which entails the synthesis of bent metallocene complexes with novel heteroannular bridges. The bridges will involve the group 13 elements B, Al, or Ga. These have the virtue of presenting an opportunity for switching between different reaction states through coordination with Lewis bases. The effect of chiral Lewis bases will also be investigated and it will be determined whether chirality can be induced at the metal center. %%% Research planning grants are awarded to women who have not yet been awarded federal funding for their research. Dr. Shapiro is a new faculty member at the University of Idaho and will be initiating a research program leading to the preparation of a class of novel catalytic molecules which could become commercially important in the polymer industry.

这项研究计划拨款将使帕梅拉·夏皮罗博士能够启动一项研究计划，该计划需要合成具有新型杂环桥的弯曲茂金属络合物。这些桥梁将涉及13族元素B、Al或Ga。它们的优点是提供了通过与Lewis碱配位在不同反应状态之间切换的机会。手性Lewis碱的影响也将被研究，并将确定是否可以在金属中心诱导手性。%研究规划补助金授予尚未获得联邦研究资助的妇女。夏皮罗博士是爱达荷大学的一名新教员，他将启动一项研究计划，以制备一类可能在聚合物行业具有重要商业意义的新型催化分子。