Gated Electron Transfer in Copper(II)/(I) Systems

铜 (II)/(I) 系统中的门控电子转移

• 批准号: 9817919
• 负责人: David Rorabacher
• 金额: $ 40.5万
• 依托单位: Wayne State University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 1999
• 资助国家: 美国
• 起止时间: 1999-03-01 至 2003-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=9817919&HistoricalAwards=false
• 关键词: Gated; Electron; Transfer; Copper; II

The Inorganic, Bioinorganic and Organometallic Chemistry Program of the Chemistry Division supports the research of Dr. David B. Rorabacher and Dr. Ronald R. Schroeder, Department of Chemistry, Wayne State University, and of Dr. Leo A. Ochrymowycz, Department of Chemistry, University of Wisconsin at Eau Claire. The project involves an investigation of the redox behavior of copper(II)/(I) systems in which electron transfer and conformational changes occur sequentially rather than by a concerted fashion. The results will be relevant in efforts of being able to manipulate structure to control gated electron transfer events.The results from this wide ranging proposal will be useful in addressing how gated electron transfer processes take place in biological systems. Results will also be of interest in the design of specific catalytic systems. Undergraduate and graduate students from both institutions will receive excellent training in photochemistry and in electron transfer chemistry.

化学部的无机、生物无机和有机化学项目支持大卫B博士的研究。Rorabacher和罗纳德R. Schroeder，韦恩州立大学化学系，和Leo A. Ochrymowycz，化学系，威斯康星州欧克莱尔大学。该项目涉及铜（II）/（I）系统的氧化还原行为的调查，其中电子转移和构象变化顺序发生，而不是通过协调一致的方式。结果将是相关的努力，能够操纵结构控制门控电子转移events. Results从这个广泛的建议将是有用的，在解决如何门控电子转移过程发生在生物系统中。结果也将在特定的催化系统的设计感兴趣。来自这两个机构的本科生和研究生将接受光化学和电子转移化学方面的优秀培训。