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Preparation of Iridium(I) Complexes and Investigation of Their Electronic Excited States: A University/Community College Research Collaboration

铱(I)配合物的制备及其电子激发态的研究：大学/社区学院的研究合作

基本信息

批准号：
9975385
负责人：
Glenn Crosby
金额：
$ 24.8万
依托单位：
Washington State University
依托单位国家：
美国
项目类别：
Standard Grant
财政年份：
2000
资助国家：
美国
起止时间：
2000-05-15 至 2003-04-30
项目状态：
已结题

来源：
https://www.nsf.gov/awardsearch/showAward?AWD_ID=9975385&HistoricalAwards=false
关键词：
Preparation Iridium Complexes Investigation Their

项目摘要

Dr. Glenn Crosby of Washington State University is supported by the Inorganic, Bioinorganic, and Organometallic Chemistry program, and by the Office of Interdisciplinary Programs, of the Mathematics and Physical Sciences Division for a program of research dealing with the preparation of iridium(I) complexes, and investigation of their electronic excited states. This research will involve students and faculty members of community colleges located in (mainly rural) eastern Washington as coworkers. This research program will carry out the synthesis of a carefully designed series of complexes of iridium, and study the luminescence and related properties of these materials. One objective of the research will be to understand, on a fundamental level, how the internal electronic structure, and the photophysical behavior, of these complexes resembles and differs from the corresponding characteristics of related platinum complexes. A second main objective of the project will be to increase the number of students at community colleges in eastern Washington who continue their education in science beyond the community college level. Many such students are Hispanics or Native Americans. Community college students and faculty members will carry out parts of this research during summers. Recruitment of outstanding community college students and faculty to participate in this program will be aided by a network of teachers in eastern Washington who have previous connections with the Principal Investigator and are familiar with his research.

华盛顿州立大学的Glenn Crosby博士得到了无机、生物无机和有机金属化学项目以及数学和物理科学部跨学科项目办公室的支持，他的研究项目涉及铱(I)配合物的制备及其电子激发态的研究。这项研究将涉及位于华盛顿州东部（主要是农村）的社区学院的学生和教师作为同事。本研究计划将进行精心设计的一系列铱配合物的合成，并研究这些材料的发光和相关性质。研究的一个目标是在基本层面上了解这些配合物的内部电子结构和光物理行为与相关铂配合物的相应特征的相似和不同之处。该项目的第二个主要目标是增加华盛顿州东部社区大学继续接受社区大学水平以外科学教育的学生人数。许多这样的学生是西班牙裔或美洲原住民。社区学院的学生和教职员工将在夏季进行部分研究。招募优秀的社区大学学生和教师参与该项目将得到华盛顿东部教师网络的帮助，这些教师之前与首席研究员有联系，并熟悉他的研究。