Cyanogels: A Coordination Polymer Based System for the Synthesis of Solid-State Materials Via Sol-Gel Processing

氰凝胶：一种基于配位聚合物的系统，用于通过溶胶-凝胶加工合成固态材料

• 批准号: 0079169
• 负责人: Andrew Bocarsly
• 金额: $ 39.5万
• 依托单位: Princeton University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2000
• 资助国家: 美国
• 起止时间: 2000-08-15 至 2003-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0079169&HistoricalAwards=false
• 关键词: Cyanogels; Coordination; Polymer; Based; System

This award to Professor Andrew Bocarsly of Princeton University is a renewal of an earlier award and is supported by the Advanced Materials and Processing Program in the Chemistry Division. The focus of the award will be to develop the chemistry of cyanogels based on multi-metal cyanides prepared by sol-gel processing. Systemic development of cyanogel chemistry, their characterization for catalysis, and low temperature processing of them in ceramics, semiconductors and coatings for electrodes will be part of this award. Studies with cyanogel to absorb and preconcentrate carbon dioxide and finally to reduce to methanol will be carried out under this award. Also, multimetal cyanogel will be evaluated as electrocatalysts at low temperatures for combinatorial chemistry. Teaching and training of students in materials science at all levels from high school to graduate school including teachers from high school are parts of the award. Cyanogels prepared from multi-metal cyanides by sol-gel processing will be characterized for functional properties and for applications in catalysis, and for the preparation of ceramics, semiconductors and coatings for electrodes. Use of cyanogels for the absorption and preconcentration of carbon dioxide and its reduction of methanol, will have a lasting improvement in the environment in general, and in the energy sector in particular. In addition, the research program will provide a rich multidisciplinary education and training opportunity in materials chemistry to postdoctoral and graduate students, and students and teachers from high schools.

这一奖项授予普林斯顿大学的安德鲁·博卡斯莱教授，是对先前奖项的延续，并得到了化学系先进材料和加工计划的支持。该奖项的重点将是开发基于溶胶-凝胶工艺制备的多金属氰化物的氰凝胶的化学。氰凝胶化学的系统发展，它们的催化表征，以及它们在陶瓷、半导体和电极涂层中的低温处理将是该奖项的一部分。使用氰凝胶吸收和预浓缩二氧化碳并最终还原为甲醇的研究将在本奖项下进行。此外，多金属氰凝胶也将作为组合化学的低温电催化剂进行评估。该奖项包括对从高中到研究生院的各级学生进行材料科学方面的教学和培训，包括高中教师。由多金属氰化物通过溶胶凝胶法制备的氰凝胶将表征其功能特性以及在催化、陶瓷、半导体和电极涂层的制备中的应用。使用氰凝胶吸收和预浓缩二氧化碳并减少其对甲醇的影响，将对整个环境，特别是能源部门的环境产生持久的改善。此外，该研究项目将为博士后和研究生以及高中学生和教师提供丰富的材料化学多学科教育和培训机会。