US-Jordan Cooperative Research: Experimental and Modeling Studies of Surface Growth on TiO2 Particles

0137689莫里森描述：该奖项是为了支持俄亥俄州克利夫兰凯斯西储大学化学工程系Philip莫里森教授和约旦伊尔比德约旦科技大学（JUST）化学工程系Lua'y Zeatoun博士的合作项目。 在最近的工作中，在凯斯西方，活塞压缩方法被用来研究高分压动力学的TiCl 4氧化，并通过分析数据的模型被开发用于预测的分数转化TiCl 4。 这项工作没有考虑到非均相反应，将发生在表面上的二氧化钛颗粒，因为他们的核。在这项研究中，合作科学家计划通过进行实验和建模研究来研究表面反应在TiO 2形成中的作用。 莫里森博士在凯斯韦斯特的团队将通过在反应气体中加入TiO 2颗粒并进行压缩实验来测量表面反应速率。Zeatoun博士在JUST的团队将对气相和表面反应中发生的扩散反应过程进行数值模拟。范围：两个合作者计划联合收割机他们在实验工作和数学建模方面的专业知识来处理一个有趣的科学问题。PI拥有丰富的经验，并可以使用凯斯西储的广泛设施。 这位约旦科学家有建模经验。 这项研究将提高我们对TiO2b颗粒形成过程的理解，并且在纳米尺度的应用中特别有用。 该项目符合INT支持互利合作项目的标准。国际科学和工程办公室以及化学和运输系统司为该项目提供支助。

0137689Morrison Description: This award is for support of a cooperative project by Professor Philip Morrison, Department of Chemical Engineering, Case Western Reserve University, Cleveland, Ohio and Dr. Lua'y Zeatoun, Department of Chemical Engineering, Jordan University of Science and Technology (JUST), Irbid, Jordan. In recent work at Case Western, a piston compression method was used to study high partial pressure kinetics of TiCl4 oxidation, and by analyzing the data a model was developed for predicting the fractional conversion of TiCl4. This work does not take into account heterogeneous reactions that will occur on the surfaces of the TiO2 particles as they nucleate. In this research the collaborating scientists plan to study the role of surface reactions in TiO2 formation by conducting experimental and modeling research. Dr. Morrison's team at Case Western will measure experimentally the surface reaction rate by seeding the reactive gas with TiO2 particles and performing compression experiments. Dr. Zeatoun's team at JUST will perform numerical simulations of the diffusion-reaction process occurring in both the gas phase and on the surface reactions.Scope: The two collaborators plan to combine their expertise in experimental work and in mathematical modeling in dealing with an interesting scientific problem. The PI has considerable experience and has access to extensive facility at Case Western. The Jordanian scientist has experience in modeling. This research should improve our understanding of the process of formation of TiO2b particles and should be especially useful in applications of nano-scale. The project meets INT criteria for support of cooperative projects that are mutually beneficial. Support for this project is provided by the Office of International Science and Engineering and the Division of Chemical and Transport Systems.