US-Germany Cooperative Research: Synthesis of Hydrogen from Diesel Fuels

美德合作研究：柴油合成氢气

• 批准号: 0339819
• 负责人: Lanny Schmidt
• 金额: --
• 依托单位: University of Minnesota-Twin Cities
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2004
• 资助国家: 美国
• 起止时间: 2004-01-01 至 2007-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0339819&HistoricalAwards=false
• 关键词: US; Germany; Cooperative; Research; Synthesis

0339819SchmidtThis award supports Lanny Schmidt and students from the University of Minnesota-Twin Citiesin a collaboration with Olaf Deutschmann of the Institute of Chemical Engineering at the University of Karlruhe, Germany. The funding establishes a collaborative program for modeling the partial oxidation of diesel fuel and its components to produce hydrogen and light hydrocarbons for fuel cells and related applications. This program will build on past collaborations between the principal investigators on developing detailed models partial oxidation of methane. These will include mechanism development, simulations of experimental results, and predictions of process behavior. The models constructed will provide fundamental information on mechanisms of hydrocarbon reactions. There are currently no detailed models of hydrocarbon oxidation reactions, either homogeneous or on surfaces, which have been developed in sufficient detail for simulating fuel reforming to hydrogen. Development of these models will also have significant fundamental impact on interpreting experimental results and on theoretical bases for kinetic model development. Furthermore, the models will be crucial in developing technologies for fuel reforming for fuel cells because they require processing of complex mixtures of alkanes. Such models are essential in designing these important energy-producing technologies.

0339819施密特该奖项支持兰尼施密特和明尼苏达大学双城分校的学生与德国卡尔鲁厄大学化学工程学院的奥拉夫·多伊奇曼合作。 这笔资金建立了一个合作项目，用于模拟柴油及其组分的部分氧化，以生产用于燃料电池和相关应用的氢气和轻烃。 该计划将建立在主要研究人员之间过去的合作基础上，开发甲烷部分氧化的详细模型。 这些将包括机制开发，实验结果的模拟和过程行为的预测。所建立的模型将提供有关烃类反应机理的基本信息。 目前还没有详细的烃氧化反应模型，无论是均匀的还是在表面上，已经开发出足够详细的模拟燃料重整为氢。 这些模型的发展也将对解释实验结果和动力学模型发展的理论基础产生重大的根本性影响。 此外，这些模型在开发燃料电池燃料重整技术方面至关重要，因为它们需要处理复杂的烷烃混合物。 这些模型对于设计这些重要的能源生产技术至关重要。