RUI: Condensed Phase Effects on Structure and Bonding in Nitrile Donor-Acceptor Complexes

RUI：凝聚相对腈供体-受体复合物结构和键合的影响

• 批准号: 0407824
• 负责人: James Phillips
• 金额: $ 18.3万
• 依托单位: University of Wisconsin-Eau Claire
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2004
• 资助国家: 美国
• 起止时间: 2004-07-01 至 2008-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0407824&HistoricalAwards=false
• 关键词: RUI; Condensed; Phase; Effects; Structure

In this project, funded by the Experimental Physical Chemistry Program of the Chemistry Division, Prof. James Phillips of University of Wisconsin - Eau Claire (UWEC) will conduct experimental and theoretical research on the spectroscopy of donor-acceptor complexes produced in low-temperature, inert matrices (matrix isolation spectroscopy). The details of the experimental spectra, combined with theoretical studies, will be used to gain an understanding of the bonding in these complexes, and the subtle influences that the matrix has on the bonding.This research project will make a positive impact on the science program of UWEC in that the research program is geared towards studying significant scientific problems and is carried out entirely by undergraduate students. The work will expose UWEC students to modern spectroscopic and theoretical techniques. Prof. Phillips has also developed collaborations with industrial and research university colleagues that help to enrich the experiences for UWEC students. Additionally, the majority of the students at UWEC are female and roughly half are low-income/first generation college students - groups that are historically underrepresented in the sciences, and roughly half of UWEC's students matriculate to PhD programs.

在该项目中，由化学部实验性化学计划资助，威斯康星大学 - 欧克莱尔大学（UWEC）的詹姆斯·菲利普斯教授（UWEC）将对以低温，惰性矩阵（Matrix隔离光谱镜）生产的供体 - 受体 - 受体 - 受体 - 受体复合物进行实验和理论研究。 实验光谱的细节以及理论研究将用于了解这些络合物中的粘结，以及矩阵对键合的微妙影响。这项研究项目将对UWEC的科学计划产生积极的影响，因为研究计划旨在研究重大的科学问题，并且全部不足。 这项工作将使UWEC学生了解现代光谱和理论技术。 菲利普斯教授还与工业和研究大学的同事建立了合作，有助于丰富UWEC学生的经验。 此外，UWEC的大多数学生都是女性，大约一半是低收入/第一代大学生 - 从历史上讲，这些学生在科学中的人数不足，而UWEC的学生中大约有一半的学生与博士学位课程相关。