Optimization of the Electrical and Dielectric Properties of Hydrogen Bonded Solids for Fuel Cell and Other Applications

用于燃料电池和其他应用的氢键固体的电学和介电性能的优化

• 批准号: 0435221
• 负责人: Sossina Haile
• 金额: $ 41.3万
• 依托单位: California Institute of Technology
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2005
• 资助国家: 美国
• 起止时间: 2005-01-01 至 2007-12-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0435221&HistoricalAwards=false
• 关键词: Optimization; Electrical; Dielectric; Properties; Hydrogen

The goal of this research is to elucidate the correlation between hydrogen bonding, phase transitions and electrical properties in solid acid sulfates, selenates and phosphates. These compounds exhibit numerous structure types, in which the extent and type of hydrogen bonding vary dramatically. Moreover, dramatic changes in properties accompany structural phase transitions. A broad range of experimental techniques will be employed to characterize the materials (X-ray and neutron diffraction, IR, Raman, NMR and impedance spectroscopy, and thermal analysis) and will be complimented by computational simulations to predict phase transition behavior a priori. These comprehensive studies will guide efforts to (1) control the temperature at which the transitions occur, (2) increase the conductivity in the superprotonic phases and the spontaneous polarization in the ferroelectric phases, and (3) to synthesize hypothesized structures with desirable hydrogen-bonding features. Ultimately, room temperature superprotonic conductors and ferroelectrics may be achieved. The breadth of tools to be utilized, the relative ease with which the materials can be synthesized, and the high level of public interest in energy technologies, renders this an ideal system for training the next generation of materials chemists.%%%The goal of this research is to advance a fundamental understanding of a class of materials known as solid acids. This understanding will enable the optimization of properties and the development of new superprotonic conductors and ferroelectrics with enhanced performance. Proton conductors have applications in humidity and hydrogen sensors, fuel and electrolysis cells, and high energy density batteries, and ferroelectrics as capacitors and in electro-optical devices. Fuel cells, because of their relevance to a sustainable energy future, are the major drivers for this research. Solid acid compounds are a radical departure from traditional fuel cell materials. They offer potential benefits in terms of reduced complexity and cost of the fuel cell system. However, their incorporation into demonstration fuel cells is in its infancy, and consequently the materials are of too great a risk for industrial laboratories. On the other hand, the relative ease with which solid acid compounds can be synthesized as well as the broad range of characterization tools that will be employed in this work, render this project ideal for training students from the high school level through the post-doctoral scholar level. Student training ranging from short visits by high-school students, to senior theses by undergraduates, to in-depth training of doctoral students will be pursued. The combination of fundamental science, important technological consequences, and strong educational outreach justify federal support for this research.

本研究的目的是阐明固体酸性硫酸盐、硒酸盐和磷酸盐中氢键、相变和电性能之间的相关性。这些化合物表现出许多结构类型，其中氢键的程度和类型变化很大。此外，性质的急剧变化伴随着结构相变。将采用广泛的实验技术来表征材料（X射线和中子衍射、IR、拉曼、NMR和阻抗谱以及热分析），并将通过计算模拟来补充，以先验地预测相变行为。这些全面的研究将指导努力（1）控制发生转变的温度，（2）增加超质子相的电导率和铁电相中的自发极化，以及（3）合成具有理想氢键特征的假设结构。最终，可以实现室温超质子导体和铁电体。所使用的工具的广度，材料合成的相对容易性，以及公众对能源技术的高度兴趣，使其成为培训下一代材料化学家的理想系统。%这项研究的目标是推进对一类被称为固体酸的材料的基本理解。这种理解将使性能的优化和新的超质子导体和铁电体的开发具有增强的性能。质子导体在湿度和氢传感器、燃料和电解电池、高能量密度电池以及作为电容器的铁电体和电光器件中具有应用。由于燃料电池与可持续能源的未来相关，因此是这项研究的主要驱动力。固体酸化合物与传统的燃料电池材料截然不同。它们在降低燃料电池系统的复杂性和成本方面提供了潜在的好处。然而，将它们纳入示范燃料电池还处于起步阶段，因此这些材料对工业实验室来说风险太大。另一方面，固体酸化合物的合成相对容易，以及本工作中将使用的广泛表征工具，使该项目成为培训从高中水平到博士后学者水平的学生的理想选择。学生的培训范围从高中生的短期访问，到本科生的高级论文，再到博士生的深入培训。基础科学、重要的技术成果和强大的教育推广相结合，证明了联邦对这项研究的支持是合理的。