Dislocation Creep in Calcite Rocks with Evolving Microstructure

方解石岩石中的位错蠕变与演化的微观结构

• 批准号: 0510412
• 负责人: Brian Evans
• 金额: $ 38.15万
• 依托单位: Massachusetts Institute of Technology
• 依托单位国家: 美国
• 项目类别: Continuing grant
• 财政年份: 2005
• 资助国家: 美国
• 起止时间: 2005-07-01 至 2010-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0510412&HistoricalAwards=false
• 关键词: Dislocation; Creep; Calcite; Rocks; Evolving

Deformation during orogenic events at convergent margins is often localized along faults and shear zones within metasediments that include carbonate rocks. Thus, the microstructures within the rocks record an important part of the strain history of many tectonic events. The Helevetic Nappes are a classic example, but similar shear zones are common in most orogenic belts. Displacement along these features is often 10's of kilometers or more and these localized zones are probably critical in determining the overall strength of a rock mass with similar linear dimensions. Observations of exhumed shear zones show that the rocks are polyphase assemblages exhibiting a complex interplay of metamorphic reactions, grain size refinement, recrystallization, and internal deformation. To provide a detailed mechanical description of these features, constitutive relations must include the effect of evolving structure on strength. In general three or more interlinked laws are needed: an evolution equation describing the rate of change for each structural variable, a kinetic equation relating mechanical and thermodynamic loading and the structural variables to the rate of strain, and a kinematic equation involving a time integral of inelastic strain rate. Structure variables may be explicitly identified or implicitly determined without identification. Appropriate explicit state variables might include aspects of the dislocation microstructure or the grain size, as are common in studies of plasticity in metals. But because natural tectonic situations are more complex, a much broader class of state variables will be needed. Among these additional variables might be crystal lattice preferred orientation, progress variables for metamorphic reactions, solid-solution chemistry, porosity, and pore fluid fugacity. In this work, the evolution of the mechanical properties of calcite rocks deforming by dislocation creep is being measured and correlated with the microstructure. Initial studies indicate that changes in second-phase content, substitional magnesium impurities, and porosity are important parameters. The tests include some natural samples containing nanometer-sized graphite particles from shear zones in the Helvetic Nappes. Two-phase synthetic samples containing calcite + dolomite are also fabricated and deformed in the dislocation creep regime to understand the effect of second-phase dispersions on strength and on dynamic recrystallization. The mechanical tests include conventional triaxial compression and extension, loading in simple shear and loading in torsion. Microstructure observations are made using optical, scanning and transmission microscopes and detailed analyses of the chemistry of grain boundaries. One broad impact of the study is the development of a teaching collection of data and interpretations from mechanical tests, field observations, optical and TEM photomicrographs, and electron microprobe data that will be archived as part of the open courseware initiative at MIT.

在汇聚边缘的造山事件期间，变形通常局限在包括碳酸盐岩在内的变质沉积内的断层和剪切带上。因此，岩石内部的微构造记录了许多构造事件的应变历史的重要部分。高山推覆是一个典型的例子，但类似的剪切带在大多数造山带中都很常见。沿着这些特征的位移通常是10‘S公里或更多，这些局部带可能是确定具有相似线性尺寸的岩体的整体强度的关键。对折返剪切带的观察表明，岩石是多相组合，表现出变质反应、粒度细化、重结晶和内部变形的复杂相互作用。为了提供这些特征的详细力学描述，本构关系必须包括结构演变对强度的影响。一般而言，需要三个或三个以上相互关联的定律：描述每个结构变量的变化率的演化方程，将机械和热力学载荷和结构变量与应变率联系起来的动力学方程，以及涉及非弹性应变率的时间积分的运动学方程。结构变量可以显式标识或隐式确定而无需标识。适当的显式状态变量可以包括位错微结构或晶粒度的各个方面，这在金属塑性研究中很常见。但由于自然构造情况更为复杂，将需要更广泛的状态变量类别。在这些附加变量中，可能包括晶格择优取向、变质反应的进展变量、固溶体化学、孔隙度和孔隙流体逸度。本工作测量了位错蠕变作用下方解石岩力学性质的演化过程，并将其与微观结构进行了关联。初步研究表明，第二相含量、置换镁杂质和孔隙率的变化是重要的参数。这些测试包括一些含有纳米级石墨颗粒的天然样品，这些样品来自海尔维特推覆带的剪切带。还制备了含有方解石+白云石的两相合成样品，并在位错蠕变状态下变形，以了解第二相弥散对强度和动态再结晶的影响。力学试验包括常规的三轴压缩和拉伸、简单剪切加载和扭转加载。用光学显微镜、扫描显微镜和透射显微镜观察了显微组织，并对晶界的化学成分进行了详细的分析。这项研究的一个广泛影响是开发了一组教学数据和解释，这些数据和解释来自机械测试、现场观察、光学和透射电子显微镜照片以及电子探针数据，这些数据将作为麻省理工学院开放课程倡议的一部分存档。