Lattice Dynamics and Phase Transitions in Nanoscale Ferroelectric Heterostructures

纳米级铁电异质结构中的晶格动力学和相变

• 批准号: 0705127
• 负责人: Dmitri Tenne
• 金额: $ 24万
• 依托单位: Boise State University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2007
• 资助国家: 美国
• 起止时间: 2007-09-01 至 2011-12-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0705127&HistoricalAwards=false
• 关键词: Lattice; Dynamics; Phase; Transitions; Nanoscale

Non-technical abstract:Modern science and technology of electronic materials have moved rapidly towards artificially engineered structures at nanometer (one billionth of a meter) scales. Physical behavior of materials at nanoscale is principally different from that of macroscopic materials in many aspects. The objective of this project is experimental investigation of fundamental physical properties of nanoscale ferroelectrics - an interesting and practically important class of electronic materials with high potential for applications in various devices, such as computer memories or microwave electronic devices. Shrinking dimensions down to nanometer scale demand characterization techniques capable of probing the fundamental properties of ferroelectric nanostructures. This project will utilize optical spectroscopic techniques using ultraviolet light to probe the atomic vibrations in nanoscale ferroelectric materials, which are essential for understanding their practically important properties. The experimental results to be obtained will test the validity of current theories of ferroelectrics and will contribute to a comprehensive understanding of nanoscale ferroelectricity. The proposed research will be closely integrated into the educational program at Boise State University, actively involving undergraduate and graduate students in the cutting-edge research and training, and acting as a catalyst for the effective use of the state-of-the-art optical instrumentation for educational purposes. The project will enhance Boise State's strength in the field of condensed-matter physics and materials science, which aligns perfectly with Boise State's strategic goal of becoming a metropolitan research university.Technical abstract:Ferroelectrics are a class of materials possessing a spontaneous electric polarization, which can be switched by the application of an electric field. Ferroelectrics exhibit a wide variety of interesting properties making them extremely attractive for applications in various electronic and optoelectronic devices. In recent years, the science and technology of ferroelectrics have moved rapidly towards artificially engineered thin films and multilayer structures at nanometer scales. A fundamental property of ferroelectrics is the dynamics of crystal-lattice vibrations, which is related to many of their practically important properties. This project focuses on the experimental study of lattice vibrations and phase transitions in nanoscale ferroelectrics by the novel technique of ultraviolet Raman spectroscopy. It will address several issues of major importance for understanding nanoscale ferroelectricity, such as the effects of strain and reducing size on ferroelectric behavior. The experimental results will test the validity of current theories of ferroelectrics, and will contribute to a comprehensive understanding of nanoscale ferroelectricity. The proposed research will be closely integrated into the educational program at Boise State University, actively involving undergraduate and graduate students in research and training and acting as a catalyst for the effective use of the state-of-the-art optical instrumentation for educational purposes.

非技术摘要：现代电子材料科学技术已经迅速向纳米（十亿分之一米）尺度的人工工程结构发展。纳米材料的物理行为与宏观材料的物理行为在许多方面有很大的不同。该项目的目标是实验研究纳米铁电体的基本物理特性-这是一种有趣且实际重要的电子材料，具有在各种设备中应用的高潜力，例如计算机存储器或微波电子设备。将尺寸缩小到纳米尺度需要能够探测铁电纳米结构的基本性质的表征技术。该项目将利用紫外光的光谱技术来探测纳米铁电材料中的原子振动，这对于理解其实际重要的特性至关重要。所获得的实验结果将检验当前铁电理论的有效性，并将有助于对纳米铁电性的全面理解。拟议的研究将紧密结合到博伊西州立大学的教育计划，积极参与本科生和研究生的前沿研究和培训，并作为一个催化剂，有效地利用国家的最先进的光学仪器用于教育目的。该项目将增强博伊西州立大学在凝聚态物理和材料科学领域的实力，这与博伊西州立大学成为一所大都市研究型大学的战略目标完全一致。技术摘要：铁电体是一类具有自发极化的材料，它可以通过施加电场来切换。铁电体表现出各种有趣的性质，使它们在各种电子和光电器件中的应用极具吸引力。近年来，铁电体的科学和技术已经迅速地向纳米尺度的人工工程薄膜和多层结构发展。铁电体的一个基本性质是晶格振动的动力学，这与它们的许多实际重要性质有关。本计画主要利用紫外拉曼光谱新技术对奈米铁电体晶格振动与相转变进行实验研究。它将解决理解纳米铁电性的几个重要问题，如应变和减小尺寸对铁电行为的影响。实验结果将检验现有铁电理论的正确性，并将有助于对纳米铁电性的全面理解。拟议的研究将紧密结合到博伊西州立大学的教育计划，积极参与本科生和研究生的研究和培训，并作为一种催化剂，有效地利用国家的最先进的光学仪器用于教育目的。