Resonant Ultrasound Studies of Complex Chromium and Vanadium Oxide Spinels

复合铬、钒氧化物尖晶石的共振超声研究

• 批准号: 0804719
• 负责人: Veerle Keppens
• 金额: $ 33万
• 依托单位: University of Tennessee Knoxville
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2008
• 资助国家: 美国
• 起止时间: 2008-08-01 至 2012-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0804719&HistoricalAwards=false
• 关键词: Resonant; Ultrasound; Studies; Complex; Chromium

NON-TECHNICAL ABSTRACTOne of the most exciting themes of modern condensed matter physics is the discovery and investigation of novel phenomena and new forms of order in materials systems of ever increasing complexity. It is one of the goals of our proposed program to study the elastic properties (i.e. how a material responds to strain) of a set of novel, complex materials called spinels. The elastic response of these spinels can be quite exotic, and our research program will explore if the behavior can be understood with recently developed theories. Graduate students will gain in-depth experience in the field of elastic properties and low temperature physics, and will acquire skills in various techniques in materials science. This proposal includes the development of outreach activities to high-school students. Special efforts will be made to reach female students.TECHNICAL ABSTRACTThis research program is designed to systematically study the elastic response of a set of complex transition metal oxides (TMOs) that we believe are ideal for elastic property studies: chromium and vanadium spinel oxides. Specifically, the compounds we intend to study have the formula AB2O4, where the B cation is Cr3+ or V3+ and the A cation is Zn2+, Mg2+, Cd2+, Mn2+, or Co2+. These materials are cubic at room temperature, and have only 3 elastic moduli. As the materials are cooled, they all undergo structural and magnetic phase transitions that are currently the subject of intense experimental and theoretical interest. The relevant physics involves crystalline distortions to relieve magnetic frustration (the spin-Teller effect), orbital ordering and spin-orbit interactions in a t2g manifold, and magnetic control of orbital occupation. RUS will be used routinely from 2-400 K and in magnetic fields up to 9 Tesla to obtain the elastic moduli. Pulse-echo measurements will be performed as appropriate. The elastic response of a solid is a measure of the material?s ?strain susceptibility? to strains of different symmetries. Near phase transitions, it can provide information about the coupling of the order parameter to strain. This knowledge is indispensable for understanding the physics of complex TMOs. Graduate students will gain in-depth experience in the field of elastic properties and low temperature physics, and will acquire skills in various techniques in materials science. This proposal includes the development of outreach activities to high-school students. Special efforts will be made to reach female students.

非技术摘要现代凝聚态物理学最令人兴奋的主题之一是发现和研究不断增加的复杂材料系统中的新现象和新的有序形式。我们提出的计划的目标之一是研究一组称为尖晶石的新型复杂材料的弹性特性（即材料如何响应应变）。这些尖晶石的弹性反应可能是相当奇特的，我们的研究计划将探索是否可以用最近发展的理论来理解这种行为。研究生将在弹性性能和低温物理领域获得深入的经验，并将获得材料科学中各种技术的技能。这项建议包括开展面向高中生的外联活动。技术摘要本研究计划旨在系统地研究一组复杂的过渡金属氧化物（TMOs）的弹性响应，我们认为这是理想的弹性性能研究：铬和钒尖晶石氧化物。 具体而言，我们打算研究的化合物具有式AB 2 O 4，其中B阳离子是Cr 3+或V3+，A阳离子是Zn 2+、Mg 2+、Cd 2+、Mn 2+或Co 2+。 这些材料在室温下是立方体，并且只有3个弹性模量。 当材料被冷却时，它们都经历了结构和磁性相变，这是目前实验和理论研究的热点。 相关的物理学涉及晶体扭曲以减轻磁挫折（自旋-泰勒效应），t2g流形中的轨道排序和自旋-轨道相互作用，以及轨道占据的磁性控制。 罗斯将在2 - 400 K和高达9特斯拉的磁场中常规使用，以获得弹性模量。将酌情进行脉冲回波测量。 固体的弹性响应是对材料的一种度量？是什么？应变敏感性不同对称性的菌株。 在相变附近，它可以提供有关序参量与应变耦合的信息。这些知识对于理解复杂TMO的物理特性是必不可少的。研究生将在弹性性能和低温物理领域获得深入的经验，并将获得材料科学中各种技术的技能。这项建议包括开展面向高中生的外联活动。将特别努力帮助女学生。