U.S.-EGYPT Cooperative Research: Magnetic Nano-Composite as Photocatalyst Prepared by the Sol-Gel Technique for Degradation of Organic Dyes

美国-埃及合作研究：溶胶-凝胶技术制备磁性纳米复合材料作为光催化剂降解有机染料

• 批准号: 0809185
• 负责人: Wolfgang Sigmund
• 金额: $ 3万
• 依托单位: University of Florida
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2008
• 资助国家: 美国
• 起止时间: 2008-08-01 至 2010-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0809185&HistoricalAwards=false
• 关键词: U.S.; EGYPT; Cooperative; Research; Magnetic

0809185SigmundThis project supports collaborative research by Dr. Wolfgang Sigmund, Department of Materials Science and Engineering, University of Florida, Gainesville and Dr. Reda Ouf, Central Metallurgical Research and Development Institute (CMRDI), Helwan, Egypt. The objective of this project is a study on ?Magnetic Nano-composite as Photocatalysts Prepared by Sol-Gel Technique for Degradation of Organic Dyes?. Technical Merit: The pollution of water resources by sewage and industrial wastes with toxic or organic compounds presents a serious problem. TiO2 nanoparticles have large specific surface areas and high catalytic performance allow reactions to convert these compounds in presence of UV light on their surface. However, their effective commercial applications are hindered by two serious disadvantages. The first is the agglomeration of the nano-powders resulting in an adverse effect on catalyst performance. The second is the separation and recovery of TiO2 nano-powders from wastewater is difficult. The aim of this project is to develop a photocatalyst that is magnetic, photoactive, and stable using a wet synthesis method, for easy removal and recovery from slurry-type photoreactor. Specific aims include: (i) developing a reproducible synthesis method based on the sol-gel process for preparing magnetic photocatalyst, by coating a magnetic material with TiO2; (ii) characterizing the physical and chemical properties of the prepared samples, and (iii) studying their photocatalytic performance by degrading dye as the model organic compound The intellectual merit of this proposal is an enhanced understanding of magnetic photocatalytic nanocomposites for degradation of organic compounds that might be useful for environmental remediation.Broader Impact: The broader impact is the education of graduate and undergraduate students in the U.S. and the education of young Egyptian researchers thus fostering the international bondsbetween Egypt and the US. Furthermore, the exchange program will provide a scientificand cultural experience for the US undergraduate and graduate students that allows them to grow into teachers for other US students and bring international experience to the companies or government units that they will work with in the future. Additionally, the photocatalysts, if proven successful, can be applied in the U.S., in Egypt or other developing countries to purify water and remediate the environment. This project is being supported under the US-Egypt Joint Fund Program, which provides grants to scientists and engineers in both countries to carry out these cooperative activities.

0809185 Sigmund该项目支持位于盖恩斯维尔的佛罗里达大学材料科学与工程系的Wolfgang Sigmund博士和位于埃及赫勒万的中央冶金研究与发展研究所（CMRDI）的Reda Ouf博士的合作研究。 这个项目的目的是研究？溶胶-凝胶法制备磁性纳米复合光催化剂降解有机染料。技术优点：含有有毒或有机化合物的污水和工业废物对水资源的污染是一个严重的问题。TiO 2纳米颗粒具有大的比表面积和高催化性能，允许在其表面上存在UV光的情况下反应转化这些化合物。然而，它们的有效商业应用受到两个严重缺点的阻碍。首先是纳米粉末的团聚，导致对催化剂性能的不利影响。二是废水中TiO 2纳米粉体的分离回收困难。本项目的目的是利用湿法合成方法开发磁性、光活性和稳定的光催化剂，以便于从浆料型光反应器中去除和回收。具体目标包括：（i）开发基于溶胶-凝胶法的可重复合成方法，通过用TiO 2涂覆磁性材料来制备磁性光催化剂;（ii）表征所制备的样品的物理和化学性质，以及（iii）以降解染料为模型有机化合物，研究其光催化性能。更广泛的影响：更广泛的影响是美国研究生和本科生的教育以及埃及年轻研究人员的教育，从而促进了埃及和美国之间的国际纽带。 此外，该交流项目将为美国本科生和研究生提供科学和文化体验，使他们能够成长为其他美国学生的教师，并将国际经验带到他们未来将与之合作的公司或政府单位。此外，如果证明成功，光催化剂可以在美国应用，在埃及或其他发展中国家净化水和修复环境。 该项目得到了美国-埃及联合基金方案的支持，该方案向两国的科学家和工程师提供赠款，以开展这些合作活动。