Spectroscopy and Dynamics of Anions

在这个由化学系实验物理化学项目资助的奖项中，W。科罗拉多大学的Carl Lineberger与他的博士后，研究生和本科生研究人员一起，将研究溶剂笼中一些阴离子/自由基的时间分辨光电子光谱，以及其光电离导致具有多个自由基中心的自由基的阴离子。其中HOOO-和1，3，5-脱氢苯阴离子是一些值得研究的分子阴离子，选择这些特殊的分子体系进行研究，对科学界具有广泛的意义。 Lineberger小组的研究将在聚合物科学和大气化学等领域产生影响。 许多分子靶点将提供有用的数据，挑战计算化学家。 除了培训高级研究生，Lineberger教授将继续在他的校园科学教育计划的领导。 该计划将选定课程的本科生带入研究实验室，在学年期间进行短期研究。

In this award, funded by the Experimental Physical Chemistry Program of the Division of Chemistry, Professor W. Carl Lineberger of the University of Colorado, together with his postdoctoral, graduate and undergraduate student researchers, will study the time-resolved photoelectron spectra of a number of anions/radicals in solvent cages, as well as anions whose photoionization result in radicals with multiple radical centers. Some of the interesting molecular anions to be studied include HOOO- and 1,3,5 dehydrobenzene anion.The particular molecular systems chosen for study are of broad interest to the scientific community. The research of the Lineberger group will have impact in the fields as diverse as polymer science and atmospheric chemistry. A number of the molecular targets will provide useful data with which to challenge computational chemists. In addition to training advanced research students, Prof. Lineberger will continue in his leadership of the Science Education Initiative on his campus. This program brings undergraduate students in selected courses into research laboratories for short periods of time during the academic year.