Metal Complexes of Donor-Bridge-Acceptor Biradical Ligands: From Nanoscopic Electron Correlation to Inhibition of Back Electron Transfer

无机、生物无机和有机金属化学项目支持北卡罗莱纳州立大学David A. Shultz教授对电子转移和电子传递的研究。研究小组确定了由辅助配体效应调制的远距离分子内电子相关性，合成了具有新桥的供体-桥-受体双基配体，并研究了各种化合物的光诱导价互变异构的寿命和热稳定性。PI已经开发了关于磁化学和群论的实验室实验，这些实验将被纳入“内部”和公共教科书。他指导了很大比例的非裔美国人和女性学生。

The Inorganic, Bioinorganic, and Organometallic Chemistry Program supports the efforts of Professor David A. Shultz of North Carolina State University for the examination of electron transfer and electron transport. The research group determines long-range intramolecular electron correlations modulated by ancillary ligand effects, synthesizes donor-bridge-acceptor biradical ligands with new bridges and investigates lifetimes and thermal stabilities of photoinduced valence tautomerism in various compounds. The PI has developed laboratory experiments on magnetochemistry and group theory and these will be incorporated into an "in-house" and a public textbook. He mentors a large percentage of African American and women students.