Metal Complexes of Donor-Bridge-Acceptor Biradical Ligands: From Nanoscopic Electron Correlation to Inhibition of Back Electron Transfer

无机化学、生物无机化学和金属有机化学项目支持北卡罗来纳州立大学大卫·A·舒尔茨教授研究电子传递和电子传递的努力。该研究小组确定了受辅助配体效应调节的长程分子内电子关联，合成了具有新桥联的给体-桥-受体双自由基配体，并研究了各种化合物中光致价互变的寿命和热稳定性。该协会已经开发了关于磁化学和群论的实验室实验，这些实验将被纳入一本“内部”和一本公共教科书。他指导了很大比例的非裔美国人和女性学生。

The Inorganic, Bioinorganic, and Organometallic Chemistry Program supports the efforts of Professor David A. Shultz of North Carolina State University for the examination of electron transfer and electron transport. The research group determines long-range intramolecular electron correlations modulated by ancillary ligand effects, synthesizes donor-bridge-acceptor biradical ligands with new bridges and investigates lifetimes and thermal stabilities of photoinduced valence tautomerism in various compounds. The PI has developed laboratory experiments on magnetochemistry and group theory and these will be incorporated into an "in-house" and a public textbook. He mentors a large percentage of African American and women students.