Metal Complexes of Donor-Bridge-Acceptor Biradical Ligands: From Nanoscopic Electron Correlation to Inhibition of Back Electron Transfer

供体-桥-受体双自由基配体的金属配合物：从纳米电子关联到反向电子转移的抑制

• 批准号: 0910585
• 负责人: David Shultz
• 金额: $ 46.4万
• 依托单位: North Carolina State University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2009
• 资助国家: 美国
• 起止时间: 2009-09-01 至 2013-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0910585&HistoricalAwards=false
• 关键词: Metal; Complexes; Donor; Bridge; Acceptor

The Inorganic, Bioinorganic, and Organometallic Chemistry Program supports the efforts of Professor David A. Shultz of North Carolina State University for the examination of electron transfer and electron transport. The research group determines long-range intramolecular electron correlations modulated by ancillary ligand effects, synthesizes donor-bridge-acceptor biradical ligands with new bridges and investigates lifetimes and thermal stabilities of photoinduced valence tautomerism in various compounds. The PI has developed laboratory experiments on magnetochemistry and group theory and these will be incorporated into an "in-house" and a public textbook. He mentors a large percentage of African American and women students.

无机，生物无机和有机化学计划支持教授大卫A的努力。Shultz的北卡罗来纳州州立大学的电子转移和电子传输的检查。 该研究小组确定了由辅助配体效应调制的长程分子内电子相关性，合成了具有新桥的供体-桥-受体双自由基配体，并研究了各种化合物中光诱导价互变异构的寿命和热稳定性。PI已经开发了关于磁性化学和群论的实验室实验，这些实验将被纳入“内部”和公共教科书。 他指导了很大一部分非裔美国人和女学生。