New Catalytic Applications of Perfluorinated Phosphine Complexes

全氟膦配合物的催化新应用

• 批准号: 0911739
• 负责人: Dean Roddick
• 金额: $ 43.75万
• 依托单位: University of Wyoming
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2009
• 资助国家: 美国
• 起止时间: 2009-09-01 至 2013-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0911739&HistoricalAwards=false
• 关键词: New; Catalytic; Applications; Perfluorinated; Phosphine

This research award in the Inorganic, Bioinorganic and Organometallic Chemistry program supports work by Professor Dean M. Roddick at the University of Wyoming to carry out fundamental studies on the coordination properties and catalytic activity of new classes of fluorinated transition metal compounds. Exceptionally active olefin oligomerization platinum catalysts have been identified. Expansion of this chemistry to related platinum, palladium, and nickel systems provides a new approach to the efficient synthesis of olefin-derived products. The chemistry of novel acceptor pincer complexes of platinum, iridium, and ruthenium provides a foundation for the development of new, more active alkane dehydrogenation and hydrogen transfer catalysts.New catalysts and approaches to the conversion of simple olefins to complex products (polymers, plastics, etc.) impact a large cross section of chemical industry. The development of efficient approaches to selective hydrocarbon chemistry remains a primary modern challenge, and has critical ramifications in the creation of major chemical feedstocks in a post-fossil fuel world economy.

这项研究奖在无机，生物无机和有机化学计划支持教授院长M。罗迪克在怀俄明州大学进行的基础研究的配位性能和催化活性的新类别的氟化过渡金属化合物。 已经鉴定出异常活性的烯烃低聚铂催化剂。 这种化学扩展到相关的铂，钯，镍系统提供了一种新的方法来有效地合成烯烃衍生产品。 铂、铱和钌的新型受体钳形络合物的化学性质为开发新型、活性更高的烷烃脱氢和氢转移催化剂提供了基础。影响了化学工业大部分领域。 开发选择性碳氢化合物化学的有效方法仍然是一个主要的现代挑战，并在后化石燃料世界经济中产生主要化学原料方面具有重要影响。