MRI: Acquisition of a Multipurpose X-Ray Diffractometer Enhancing Single-Crystal Structural Capabilities for the Midwest Region
MRI:购买多用途 X 射线衍射仪,增强中西部地区的单晶结构能力
基本信息
- 批准号:0923449
- 负责人:
- 金额:$ 50万
- 依托单位:
- 依托单位国家:美国
- 项目类别:Standard Grant
- 财政年份:2009
- 资助国家:美国
- 起止时间:2009-08-01 至 2012-07-31
- 项目状态:已结题
- 来源:
- 关键词:
项目摘要
This award is funded under the American Recovery and Reinvestment Act of 2009 (Public Law 111-5).With this award from the Major Research Instrumentation (MRI) program, Kristin Bowman-James and colleague Victor W. Day from the University of Kansas, Department of Chemistry will acquire a single crystal X-ray diffractometer with a high intensity copper source to support research in 1) anion and cation coordination chemistry, 2) azulene-based organometallic species as platforms for molecular charge transport systems, 3) studies of structural, electronic, and reactivity properties of peroxomanganese(III) complexes, 4) applications of organopalladium chemistry to new synthetic methodologies, 5) decarboxylative metalation and cross-coupling reactions and synthesis of chemical libraries via C-H functionalization, and 6) mechanism of heme capture by the hemophore secreted by pseudomonas aeruginosa.The technique of single-crystal X-ray crystallography allows accurate and precise determination of the full three dimensional structure of a molecule, including bond distances and angles, and it provides accurate information about the spatial arrangement of molecules relative to the neighboring molecules. The high intensity X-ray source will facilitate the study of compounds that produce small crystals or those that diffract poorly. These studies will have an impact in a number of areas ranging from synthetic organic and inorganic chemistry to systems of biological interest and materials research. This instrument will be an integral part of teaching as well as research.
该奖项是根据2009年美国复苏和再投资法案(公法111-5)资助的。来自堪萨斯大学化学系的Day将获得一台具有高强度铜源的单晶X射线衍射仪,以支持以下研究:1)阴离子和阳离子配位化学,2)基于甘菊环的有机金属物种作为分子电荷传输系统的平台,3)过氧锰(III)络合物的结构,电子和反应性特性的研究,4)有机钯化学在新合成方法中的应用,5)脱羧金属化和交叉偶联反应以及通过C-H官能化合成化学库,(6)铜绿假单胞菌分泌的血红素捕获血红素的机制。射线晶体学允许准确和精确地确定分子的完整三维结构,包括键距和角度,并且它提供关于分子相对于相邻分子的空间排列的准确信息。高强度X射线源将有助于研究产生小晶体或结晶性差的化合物。这些研究将在许多领域产生影响,从合成有机和无机化学到生物系统和材料研究。该仪器将成为教学和研究的一个组成部分。
项目成果
期刊论文数量(0)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
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Kristin Bowman-James其他文献
Kristin Bowman-James的其他文献
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{{ truncateString('Kristin Bowman-James', 18)}}的其他基金
INFEWS N/P/H20: Supramolecular Recognition and Catalysis Targeting Phytate, an Organic Sink for Phosphate in the Human Phosphorus Cycle
INFEWS N/P/H20:针对植酸的超分子识别和催化,植酸是人类磷循环中磷酸盐的有机库
- 批准号:
1710535 - 财政年份:2017
- 资助金额:
$ 50万 - 项目类别:
Continuing Grant
RII Track-1: Microbiomes of Aquatic, Plant, and Soil Systems across Kansas
RII Track-1:堪萨斯州水生、植物和土壤系统的微生物组
- 批准号:
1656006 - 财政年份:2017
- 资助金额:
$ 50万 - 项目类别:
Cooperative Agreement
Collaborative Research: Imaging and Controlling Ultrafast Dynamics of Atoms, Molecules, and Nanostructures
合作研究:原子、分子和纳米结构的超快动力学成像和控制
- 批准号:
1430493 - 财政年份:2014
- 资助金额:
$ 50万 - 项目类别:
Cooperative Agreement
Prairie Light: Next Generation Networking for Mid-continent Science
Prairie Light:中大陆科学的下一代网络
- 批准号:
1006860 - 财政年份:2010
- 资助金额:
$ 50万 - 项目类别:
Standard Grant
Excellence Empowered by a Diverse Academic Workforce: Chemists, Chemical Engineers and Materials Scientists with Disabilities
多元化的学术队伍赋予卓越的力量:残疾化学家、化学工程师和材料科学家
- 批准号:
0854967 - 财政年份:2009
- 资助金额:
$ 50万 - 项目类别:
Standard Grant
Phase VI: Climate Change and Energy: Basic Science, Impacts, and Mitigation
第六阶段:气候变化和能源:基础科学、影响和缓解
- 批准号:
0903806 - 财政年份:2009
- 资助金额:
$ 50万 - 项目类别:
Cooperative Agreement
Collaborative Research: EPSCoR RII Track 2 Oklahoma and Kansas: A cyberCommons for Ecological Forecasting
合作研究:EPSCoR RII Track 2 俄克拉荷马州和堪萨斯州:生态预测的网络共享
- 批准号:
0919443 - 财政年份:2009
- 资助金额:
$ 50万 - 项目类别:
Cooperative Agreement
Architectural Design of Supramolecular Hosts from Simple Amide/Amine Building Blocks
简单酰胺/胺构建模块的超分子主体的结构设计
- 批准号:
0809736 - 财政年份:2008
- 资助金额:
$ 50万 - 项目类别:
Continuing Grant
Phase V: Building Research Infrastructure to Address Grand Challenge Problems in Ecological Forecasting and Biomaterials Design
第五阶段:建设研究基础设施以解决生态预测和生物材料设计中的重大挑战问题
- 批准号:
0553722 - 财政年份:2006
- 资助金额:
$ 50万 - 项目类别:
Continuing Grant
Amide and Thioamide Macrocyclic Anion Receptors
酰胺和硫代酰胺大环阴离子受体
- 批准号:
0316623 - 财政年份:2003
- 资助金额:
$ 50万 - 项目类别:
Standard Grant
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