Collaborative Research: Rear-arc Magmatism in the Northern Volcanic Zone of the Andes: Processes and Timescales in a Continental Rear-arc Setting

本研究的总体目标是研究南美洲安第斯山脉北部火山岩带（NVZ）的弧后岩石形成过程。NVZ是这项研究的理想选择，因为它在许多方面与其他经过充分研究的弧线相似，但它表现出NVZ独有的特征。这项研究很重要，因为我们有机会了解南美洲从俯冲影响的熔融为主转变为morb型岩石成因的过程。除主要目的外，还将评价一个钙碱性弧后活火山（El Reventador）岩浆上升和脱气的时间尺度，这对控制弧后地区岩浆活动的时间尺度具有重要意义。新的数据集将用于测试弧后岩浆作用的现有模型，同时开发可应用于未来弧研究的新模型。拟议的研究将包括对厄瓜多尔弧后火山进行区域深入的地球化学研究，采用实地研究、分析工作和地球化学模拟相结合的方法。岩石成因过程将利用主微量元素结合放射性成因同位素（Pb、Sr、Nd）和u系列对整个岩石和矿物分离物进行表征。将特别注意矿物，以表征熔体包裹体和成分变化，揭示精细尺度的岩石成因指纹。时间尺度（即结晶和脱气速率，年龄）将通过测量矿物分离物和整个岩石中的238U-， 230Th-, 226Ra， 210Pb-和210Po核素来确定，使用WHOI和怀俄明大学和爱荷华州的设施。严格表征矿物，并将完成使用电子探针和二次离子质谱设备在加州大学洛杉矶分校。这些数据将用于评估熔体形成的对比模型。知识价值。这项研究对于了解安第斯大陆弧和一般弧的弧后过程的性质至关重要。NVZ的独特之处在于岩浆成分的多样性（钙碱性和碱性），后弧位于南美克拉通的边界，以及俯冲的卡内基岭（可能）的影响。与其他弧后火山的相似之处为比较我们的数据和测试模型提供了坚实的基础。u系列核素在火成岩地球化学中的应用已被证明可用于确定弧火山的熔化和分异时间尺度，最近还用于确定熔化和分异过程。这些目前在厄瓜多尔的活火山提供了一个机会，使用u系列核素来研究融化过程和岩浆的时间尺度在弧后的设置。更广泛的影响。该项目的广泛影响包括向学生推广地球科学、促进国际交流和强调科学对社会的重要性。将一个互动网站作为实地研究的一部分，将把实地经验直接带入美国和厄瓜多尔的课堂，并为学生提供一种科学发现的感觉，这种感觉可能对他们的生活产生长期和积极的影响。该项目有可能加强K-12学生的科学基础，对西班牙裔社区的少数民族学生产生重大影响。此外，这笔资金将支持一名研究生，并为加州州立大学洛杉矶分校的一名初级教员提供资金。该奖项由国际科学与工程办公室（OISE）共同资助。

The overarching goal of this research is to investigate rear-arc petrogenetic processes in the Northern Volcanic Zone (NVZ) of the South American Andes. The NVZ is ideal for this study because it is similar in many ways to other well-studied arcs, yet it exhibits characteristics that are unique to the NVZ. This research is important because we have the opportunity to learn about the processes that mark the transition from dominantly subduction-influenced melting to the regime of MORB-type petrogenesis in South America. In addition to the primary objective, timescales will be evaluated for magma ascent and degassing in an active, calc-alkaline rear-arc volcano (El Reventador), which is important for constraining the timescales of magmagenesis in the rear-arc region. The new data set will be used to test existing models of rear-arc magmatism, while developing new models that can be applied to future arc research. The proposed research will comprise a regional, in-depth, geochemical study of Ecuadorian rear-arc volcanoes using a combination of field research, analytical work and geochemical modeling. Petrogenetic processes will be characterized using major and trace elements combined with radiogenic isotopes (Pb, Sr, Nd) and U-series on whole rocks and mineral separates. Special attention will be given to minerals in order to characterize melt inclusions and compositional variation that reveal fine-scale petrogenetic fingerprints. Timescales (i.e. crystallization and degassing rates, ages) will be determined by measuring 238U-, 230Th-, 226Ra, and 210Pb- and 210Po nuclides in mineral separates and whole rocks, using facilities at WHOI and the Universities of Wyoming and Iowa. Rigorous characterization of minerals and will be accomplished using electron microprobe and secondary ion mass spectrometry facilities at UCLA. These data will be used to evaluate contrasting models for melt formation. Intellectual Merit. This research is critical for understanding the nature of rear-arc processes in the Andean continental arc and arcs in general. The uniqueness of the NVZ lies in the compositional diversity of magmas (calc-alkaline and alkaline), the location of the rear-arc at the boundary of the South American craton, and the (possible) influence of the subducting Carnegie Ridge. Similarities to other rear-arc volcanoes provide a strong foundation for comparing our data and testing models. The application of U-series nuclides to igneous geochemistry has proven useful for determining melting and differentiation timescales in arc volcanoes, and more recently for identifying melting and differentiation processes. These currently active volcanoes in Ecuador present an opportunity to use U-series nuclides to investigate melting processes and magmatic timescales in a rear-arc setting. Broader Impacts. The Broader Impacts of this project include promoting geoscience to students, fostering international communication and emphasizing the importance of science to society. Incorporation of an interactive website as part of the field research, will bring the field experiences directly into classrooms in the U.S. and Ecuador, and provide students a sense of scientific discovery that could have a long lasting and positive impact on their lives. This project has the potential to strengthen the scientific foundation of K-12 students, with a large impact on minority students in a dominantly Hispanic community. Additionally, this funding will support a graduate student and provide funding for a junior faculty member at California State University, Los Angeles.This award is co-funded by the Office of International Science and Engineering (OISE).