EAGER: Subsulfide and Subselenide Chemistry
EAGER:亚硫化物和亚硒化物化学
基本信息
- 批准号:1041748
- 负责人:
- 金额:$ 20万
- 依托单位:
- 依托单位国家:美国
- 项目类别:Standard Grant
- 财政年份:2010
- 资助国家:美国
- 起止时间:2010-08-01 至 2012-07-31
- 项目状态:已结题
- 来源:
- 关键词:
项目摘要
This award in the Chemical Synthesis (SYN) program within the CHE Division supports work by Professor John F. Berry at the University of Wisconsin ? Madison to carry out fundamental studies of the redox properties of sulfur and selenium bound to transition metals. These studies will test the hypothesis that a new oxidation state of sulfur, subsulfide, can be stabilized by coordination to transition metals. This investigation involves examination of the electronic structure of previously reported sulfur/transition metal compounds, as well as newly designed compounds, using a variety of physical methods. Electrochemical and chemical reactivity of coordinated sulfur species will be investigated so that the electronic and chemical properties of the subsulfide ion may be elucidated.The oxidation and reduction chemistry of sulfur and the nature of sulfur-sulfur bonding are critical to many important biological problems and new technologies. The development of subsulfide chemistry can have a long-term impact on the understanding of disulfide bond formation in proteins, and can potentially lead to new technologies such as new catalytic processes and dyes for photovoltaic devices.
该奖项在化学合成(SYN)计划在CHE司支持教授约翰F。威斯康星州大学的贝瑞?麦迪逊进行基础研究的硫和硒结合到过渡金属的氧化还原性能。 这些研究将测试的假设,一个新的氧化态的硫,低硫化物,可以通过协调过渡金属稳定。 这项调查涉及检查以前报道的硫/过渡金属化合物的电子结构,以及新设计的化合物,使用各种物理方法。 研究配位硫物种的电化学和化学反应性,以便阐明硫代硫离子的电子和化学性质。硫的氧化和还原化学以及硫-硫键的性质对许多重要的生物学问题和新技术至关重要。 低硫化物化学的发展可以对蛋白质中二硫键形成的理解产生长期影响,并可能导致新的技术,如新的催化过程和光伏器件的染料。
项目成果
期刊论文数量(0)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
数据更新时间:{{ journalArticles.updateTime }}
{{
item.title }}
{{ item.translation_title }}
- DOI:
{{ item.doi }} - 发表时间:
{{ item.publish_year }} - 期刊:
- 影响因子:{{ item.factor }}
- 作者:
{{ item.authors }} - 通讯作者:
{{ item.author }}
数据更新时间:{{ journalArticles.updateTime }}
{{ item.title }}
- 作者:
{{ item.author }}
数据更新时间:{{ monograph.updateTime }}
{{ item.title }}
- 作者:
{{ item.author }}
数据更新时间:{{ sciAawards.updateTime }}
{{ item.title }}
- 作者:
{{ item.author }}
数据更新时间:{{ conferencePapers.updateTime }}
{{ item.title }}
- 作者:
{{ item.author }}
数据更新时间:{{ patent.updateTime }}
John Berry其他文献
Preliminary results of the Phase IIa trial of a folate binding protein (FBP) adjuvant cancer vaccine (E39+GM-CSF) in ovarian and endometrial cancer patients to prevent recurrence
- DOI:
10.1186/2051-1426-2-s3-p74 - 发表时间:
2014-11-06 - 期刊:
- 影响因子:10.600
- 作者:
Julia Greene;Erika Schneble;John Berry;Alfred Trappey;Timothy Vreeland;Guy Clifton;William McGuire;George Maxwell;Sathibalan Ponniah;George Peoples - 通讯作者:
George Peoples
Preliminary report of a clinical trial supporting the sequential use of an attenuated E39 peptide (E39') to optimize the immunologic response to the FBP (E39+GM-CSF) vaccine
- DOI:
10.1186/2051-1426-3-s2-p156 - 发表时间:
2015-11-04 - 期刊:
- 影响因子:10.600
- 作者:
Doreen Jackson;Na Qiao;Julia M Greene;Diane Hale;John Berry;Alfred Trappey;Timothy Vreeland;Guy Clifton;Nuhad Ibrahim;Annie Toms;George E Peoples;Elizabeth A Mittendorf - 通讯作者:
Elizabeth A Mittendorf
Developing mathematical modelling skills: The role of CAS
- DOI:
10.1007/bf02655824 - 发表时间:
2002-10-01 - 期刊:
- 影响因子:2.400
- 作者:
John Berry - 通讯作者:
John Berry
Correlation of HER2/neu antibody response to clinical response in a Phase II trial of the ae37+gm-csf her2 peptide vaccine
- DOI:
10.1186/2051-1426-2-s3-p90 - 发表时间:
2014-11-06 - 期刊:
- 影响因子:10.600
- 作者:
Julia Greene;Erika Schneble;Jonathan Martin;Maddie Flores;Alfred Trappey;John Berry;Timothy Vreeland;Diane Hale;Guy Clifton;Sonia A Perez;Michael Papamichail;George Peoples;Elizabeth Mittendorf;Sathibalan Ponniah - 通讯作者:
Sathibalan Ponniah
Damage control resuscitation in a patient on extracorporeal life support with empyema
- DOI:
10.1016/j.jcrc.2013.07.035 - 发表时间:
2013-12-01 - 期刊:
- 影响因子:
- 作者:
John Berry;Jason Mccartt;Slava Belenkiy;Timothy Park;Andrew Cap;Jeremy Cannon - 通讯作者:
Jeremy Cannon
John Berry的其他文献
{{
item.title }}
{{ item.translation_title }}
- DOI:
{{ item.doi }} - 发表时间:
{{ item.publish_year }} - 期刊:
- 影响因子:{{ item.factor }}
- 作者:
{{ item.authors }} - 通讯作者:
{{ item.author }}
{{ truncateString('John Berry', 18)}}的其他基金
Electron Delocalization in Linear Heterotrimetallic Compounds
线性异三金属化合物中的电子离域
- 批准号:
2246913 - 财政年份:2023
- 资助金额:
$ 20万 - 项目类别:
Standard Grant
Electron Delocalization in Linear Heterotrimetallic Compounds
线性异三金属化合物中的电子离域
- 批准号:
1953924 - 财政年份:2020
- 资助金额:
$ 20万 - 项目类别:
Standard Grant
Linear Heterotrimetallic Coordination Compounds: Metal Atom Core and Axial Site Manipulation
线性异三金属配位化合物:金属原子核和轴向位点操纵
- 批准号:
1664999 - 财政年份:2017
- 资助金额:
$ 20万 - 项目类别:
Continuing Grant
CNIC: U.S.-Netherlands Project Development for Research on the Zebrafish (Danio rerio) as a Toxicological Model Using Magnetic Resonance Spectroscopy and Imaging Techniques
CNIC:美国-荷兰利用磁共振波谱和成像技术研究斑马鱼(Danio rerio)毒理学模型的项目开发
- 批准号:
1427797 - 财政年份:2014
- 资助金额:
$ 20万 - 项目类别:
Standard Grant
Coordination Complexes with Multiple Inorganic Functional Groups
具有多个无机官能团的配位配合物
- 批准号:
1300464 - 财政年份:2013
- 资助金额:
$ 20万 - 项目类别:
Standard Grant
CAREER: Metal-Metal Multiply Bonded Redox-active Scaffolds for Transition Metals
职业:过渡金属的金属-金属多重键合氧化还原活性支架
- 批准号:
0745500 - 财政年份:2008
- 资助金额:
$ 20万 - 项目类别:
Continuing Grant
U.S.-Finland Cooperative Research: New Techniques for Ensuring Sound Spheroidal Graphite Iron Castings with BetterYield
美国-芬兰合作研究:确保球墨铸铁件品质优良、成品率更高的新技术
- 批准号:
8712793 - 财政年份:1988
- 资助金额:
$ 20万 - 项目类别:
Continuing Grant
Computer Aided Design for Casting and Solidification Technology (CADCAST)
铸造和凝固技术计算机辅助设计 (CADCAST)
- 批准号:
8612019 - 财政年份:1987
- 资助金额:
$ 20万 - 项目类别:
Continuing Grant
Collaborative Research: Computer Aided Design for Castings
协作研究:铸件计算机辅助设计
- 批准号:
8211524 - 财政年份:1983
- 资助金额:
$ 20万 - 项目类别:
Continuing Grant
Travel to Sweden to Examine Programmable Automation Develop-Ments in Metal Casting Industries, June 1983; and Visit University of Wales, United Kingdom
前往瑞典考察金属铸造行业可编程自动化的发展,1983 年 6 月;
- 批准号:
8312829 - 财政年份:1983
- 资助金额:
$ 20万 - 项目类别:
Standard Grant