Electron Delocalization in Linear Heterotrimetallic Compounds

线性异三金属化合物中的电子离域

• 批准号: 2246913
• 负责人: John Berry
• 金额: $ 58.72万
• 依托单位: University of Wisconsin-Madison
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2023
• 资助国家: 美国
• 起止时间: 2023-06-01 至 2026-05-31
• 项目状态: 未结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=2246913&HistoricalAwards=false
• 关键词: Electron; Delocalization; Linear; Heterotrimetallic; Compounds

With the support of the Chemical Synthesis program in the Division of Chemistry, Professor John F. Berry of the University of Wisconsin – Madison will study how stringing three metal atoms together alters the electronic structures of these model molecular wires. The supported work includes synthesis of molecule-scale wire-like compounds that contain metal-metal bonds between similar or different metal atoms. Measurement of physical properties and computational analyses will allow for an assessment of the ability of these molecules to transport charge through these metal-metal bonds. These and related studies are important for advancing toward goals in the field of quantum computing, as they provide new opportunities for us to learn how to control spins and charge flow through synthetic molecule-scale devices. Collaborative projects with researchers in the US as well as in Italy will be pursued. The team will design and play leadership roles in science communication initiatives, presentations that highlight connections between arts and science, outreach efforts aimed at broadening participation in science by underrepresented groups, and other service- or education-related projects. The proposed work thus has the potential to broadly impact the discipline of inorganic chemistry and the field of chemistry as a whole, and has implications in areas of physics, electrical engineering, and computer science.The specific goals of this research project are to develop synthetic methods that allow for the fine control of the axial and equatorial ligands that support heterotrimetallic extended metal atom chains, as well as the metal atom identities and types of metal-metal interactions. Control over the axial linking groups will allow for these molecules to be effectively integrated into molecular circuitry so that charge transport measurements can be made. Expansion of the types of metal atoms included in these heterometallic molecules from first- and second-row transition elements (e.g., nickel and molybdenum) to lanthanide and main group elements is a major goal. Modification of the equatorial ligands as well as metal identities should allow for the filled orbital energy levels (the molecular analog of the “Fermi” level in metals) to be tuned. The Berry research team anticipates that it will be possible to access new molecules having carboxylate-derived axial ligands that will help us to test linking group effects in molecular conductivity measurements. Discovery of new types of metal-metal interactions has the potential to uncover molecular diode-like behavior, and multidimensional spectroscopy measurements are designed to provide insight into the coupling between low-energy metal-metal vibrations within the chain and electron transfer.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

在化学系的化学合成项目的支持下，约翰·F.威斯康星州-麦迪逊大学的贝瑞将研究将三个金属原子串在一起如何改变这些模型分子线的电子结构。支持的工作包括合成分子尺度的线状化合物，这些化合物包含相似或不同金属原子之间的金属-金属键。物理性质的测量和计算分析将允许评估这些分子通过这些金属-金属键传输电荷的能力。这些和相关的研究对于推进量子计算领域的目标非常重要，因为它们为我们提供了新的机会来学习如何通过合成分子级设备控制自旋和电荷流。将继续与美国和意大利的研究人员开展合作项目。该团队将设计并在科学传播活动中发挥领导作用，突出艺术与科学之间的联系，旨在扩大代表性不足群体参与科学的外联工作，以及其他服务或教育相关项目。因此，本研究计划将对无机化学和整个化学领域产生广泛的影响，并在物理学、电子工程和计算机科学领域产生影响。本研究项目的具体目标是开发能够精细控制支持异三金属延伸金属原子链的轴向和赤道配体的合成方法，以及金属原子身份和金属-金属相互作用的类型。对轴向连接基团的控制将允许这些分子有效地整合到分子电路中，从而可以进行电荷传输测量。包括在这些异金属分子中的金属原子的类型从第一和第二行过渡元素（例如，镍和钼）到镧系元素和主族元素是主要目标。赤道配位体的修改以及金属身份应该允许填充轨道能级（金属中“费米”能级的分子模拟）被调整。Berry研究小组预计，将有可能获得具有羧酸衍生轴向配体的新分子，这将有助于我们在分子电导率测量中测试连接基团效应。新型金属-金属相互作用的发现有可能揭示分子二极管样行为，多维光谱测量旨在深入了解链内低能金属-金属振动和电子转移之间的耦合。该奖项反映了NSF的法定使命，并被认为值得通过使用基金会的智力价值和更广泛的影响审查标准进行评估来支持。