International Collaboration in Chemistry: Preparation and Utilization of SF5-Containing Building Blocks

化学国际合作：含SF5砌块的制备和利用

• 批准号: 1124859
• 负责人: Joseph Thrasher
• 金额: $ 34.9万
• 依托单位: Clemson University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2011
• 资助国家: 美国
• 起止时间: 2011-09-01 至 2015-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1124859&HistoricalAwards=false
• 关键词: International; Collaboration; Chemistry; Preparation; Utilization

An International Collaboration in Chemistry (ICC) between two laboratories in the area of fluorine chemistry, one from the inorganic side - Professor Joseph Thrasher of Clemson University and the other from the organic side - Professor Günter Haufe of the University of Münster, Germany, funded by the Chemical Synthesis (SYN) Program of NSF's Chemistry Division (with contribution from the Office of International Science and Engineering) and its German counterpart the Deutsche Forschungsgemeinschaft (DFG), seeks to advance transformative research in the emerging field of pentafluorosulfanyl (SF5) chemistry. This research activity involves developing new or improved synthetic routes to key SF5-containing building blocks as well as using these building blocks to introduce the SF5 group into complex organic structures, energetic materials, and polymers. Fluorine has a prestigious position in many areas of organic chemistry with products involved in everyday life, e.g., medicinal and agrochemicals, as well as novel materials. The development of viable methods for the simple introduction of the SF5 group into organic compounds could enhance the likelihood of obtaining materials with improved performance in many areas of application. Broader impacts include the development of a pipeline of motivated, interested students prepared to undertake careers in STEM disciplines, particularly in the field of fluorine chemistry. Along with the scientific exchange, the cultural and language exchange during this research is expected to result in the dissemination of this work to the general public.

氟化学领域两个实验室之间的国际化学合作（ICC），一个来自无机方面 - 克莱姆森大学的 Joseph Thrasher 教授，另一个来自有机方面 - 德国明斯特大学的 Günter Haufe 教授，由 NSF 化学部化学合成 (SYN) 计划（由国际科学与工程办公室提供）及其德国同行资助 德国研究协会 (DFG) 致力于推进五氟硫基 (SF5) 化学这一新兴领域的变革性研究。 这项研究活动涉及开发新的或改进的关键含 SF5 结构单元的合成路线，以及使用这些结构单元将 SF5 基团引入复杂的有机结构、含能材料和聚合物中。 氟在有机化学的许多领域都享有盛誉，其产品涉及日常生活，例如医药和农用化学品以及新型材料。 开发将 SF5 基团简单引入有机化合物的可行方法可以提高在许多应用领域获得性能改进的材料的可能性。 更广泛的影响包括培养一批积极主动、感兴趣的学生，准备从事 STEM 学科的职业，特别是在氟化学领域。 除了科学交流之外，研究期间的文化和语言交流预计将导致这项工作向公众传播。