CAREER: Controlling the Morphology of Polymer/Fullerene Solar Cells

职业：控制聚合物/富勒烯太阳能电池的形态

• 批准号: 1151468
• 负责人: Gila Stein
• 金额: $ 50万
• 依托单位: University of Houston
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2012
• 资助国家: 美国
• 起止时间: 2012-06-01 至 2017-02-28
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1151468&HistoricalAwards=false
• 关键词: CAREER; Controlling; Morphology; Polymer; Fullerene

TECHNICAL SUMMARY: The objective of this research program is to identify the critical morphological parameters that control optoelectronic function in polymer/fullerene solar cells. The active layer in polymer-based solar cells is usually prepared by arresting the phase separation of a polymer/fullerene blend. The structures formed with this non-equilibrium process are difficult to control and accurately characterize, so it is hard to understand how film morphology influences the device efficiency. This award will develop three integrated tasks to investigate the effects of domain size, interfacial area and polymer crystallinity on charge generation, recombination, and transport processes, respectively. First, conductive polymer nanostructures are prepared by electron-beam patterning. These nanostructures are solvent-resistant and thermally-stable, and variables such as nanostructure geometry, polymer crystallinity, and polymer cross-link density are all tunable. Second, the optoelectronic performance of model nanostructure/fullerene solar cells is evaluated with established spectroscopic and device characterization techniques. Last, domain size, interfacial area, and crystallinity are accurately quantified with detailed analysis of X-ray scattering data. A particular focus of this work is interfacial engineering: It is hypothesized that polymer/fullerene interfacial composition profiles can be controlled through polymer cross-link density (in addition to annealing temperature and time), offering a simple route to study the effects of interfaces on charge generation and losses. The knowledge acquired through these systematic studies will identify the optimal design attributes for a benchmark polymer/fullerene system and guide morphology optimization for a variety of high-performance materials. NON-TECHNICAL SUMMARY: Polymer-based solar cells show promise for low-cost solar energy conversion, but the technology will not be viable as an alternative source of energy until the power output is improved. This research program facilitates those improvements by establishing a system to study the relationships between active layer structure and electronic function. These findings will help optimize the efficiency of polymer-based solar cells. Education and outreach activities are integrated with this research program in four ways. First, the PI encourages research participation for a diverse pool of high school, undergraduate and graduate students, and participates in numerous K-12 outreach programs that introduce polymer science to under-represented groups in science and engineering. Second, students will be equipped with the necessary skills for multidisciplinary research through a new nanofabrication course and a multi-institutional workshop that will teach the fundamentals of X-ray scattering. Third, through connections to the local Houston materials industry, students will learn about commercialization of polymers for energy conversion and storage. Finally, to enhance the global awareness of student participants, the PI will coordinate complementary research collaborations with the Korea Advanced Institute of Science and Technology.

技术概要：本研究计划的目的是确定控制聚合物/富勒烯太阳能电池光电功能的关键形态参数。聚合物基太阳能电池中的活性层通常通过阻止聚合物/富勒烯共混物的相分离来制备。 这种非平衡过程形成的结构难以控制和准确表征，因此很难理解薄膜形态如何影响器件效率。该奖项将开发三个综合任务，分别研究畴大小，界面面积和聚合物结晶度对电荷产生，复合和传输过程的影响。首先，通过电子束图案化制备导电聚合物纳米结构。这些纳米结构是耐溶剂和热稳定的，并且诸如纳米结构几何形状、聚合物结晶度和聚合物交联密度的变量都是可调的。其次，模型纳米结构/富勒烯太阳能电池的光电性能进行评估与建立光谱和设备表征技术。最后，域的大小，界面面积和结晶度准确地量化与详细的X射线散射数据的分析。这项工作的一个特别的重点是界面工程：据推测，聚合物/富勒烯界面组成的配置文件可以通过聚合物交联密度（除了退火温度和时间）控制，提供了一个简单的路线来研究界面上的电荷产生和损失的影响。通过这些系统研究获得的知识将确定基准聚合物/富勒烯系统的最佳设计属性，并指导各种高性能材料的形态优化。非技术性总结：基于聚合物的太阳能电池显示出低成本太阳能转换的前景，但在功率输出得到改善之前，该技术作为替代能源是不可行的。本研究计画借由建立一个系统来研究活性层结构与电子功能之间的关系，以促进这些改善。这些发现将有助于优化聚合物太阳能电池的效率。教育和推广活动以四种方式与本研究计划相结合。首先，PI鼓励高中，本科生和研究生的多元化人才库的研究参与，并参加了许多K-12推广计划，介绍聚合物科学在科学和工程的代表性不足的群体。其次，学生将通过一个新的纳米纤维课程和一个多机构研讨会，将教授X射线散射的基础知识，配备必要的技能，多学科研究。第三，通过与休斯顿当地材料行业的联系，学生将了解用于能源转换和储存的聚合物的商业化。最后，为了提高学生参与者的全球意识，PI将与韩国科学技术高级研究所协调互补的研究合作。