Radical Stability in Neutral and Anionic Systems (C06)

点击翻译按钮获取中文摘要

The influence of negatively charged functional groups on the stability and reactivity of biologically relevant radicals will be studied using theoretical and experimental methods. Of particular interest in these studies will be peptide radicals. In collaborative projects with the Knochel and Trauner groups we will furthermore use theroetical methods to elucidate elements of stereocontrol in cyclization reactions and in reactions of organometallic systems.