Radical Stability in Neutral and Anionic Systems (C06)

中性和阴离子体系中的自由基稳定性 (C06)

• 批准号: 206304480
• 金额: --
• 依托单位: Department Chemie
• 依托单位国家: 德国
• 项目类别: Collaborative Research Centres
• 财政年份: 2011
• 资助国家: 德国
• 起止时间: 2010-12-31 至 2018-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/206304480?language=en
• 关键词: Radical; Stability; Neutral; Anionic; Systems

The influence of negatively charged functional groups on the stability and reactivity of biologically relevant radicals will be studied using theoretical and experimental methods. Of particular interest in these studies will be peptide radicals. In collaborative projects with the Knochel and Trauner groups we will furthermore use theroetical methods to elucidate elements of stereocontrol in cyclization reactions and in reactions of organometallic systems.

将使用理论和实验方法研究带负电荷的官能团对生物相关自由基的稳定性和反应性的影响。在这些研究中特别感兴趣的是肽自由基。在与Knochel和Trauner小组的合作项目中，我们将进一步使用理论方法来阐明环化反应和有机金属体系反应中的立体控制元素。