Spin Switchable Ligands for Probing Multistate Reactivity in Bimetallic Complexes

自旋可切换配体用于探测双金属配合物中的多态反应性

• 批准号: 1416963
• 负责人: Jeremy Smith
• 金额: $ 18.66万
• 依托单位: Indiana University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2013
• 资助国家: 美国
• 起止时间: 2013-08-01 至 2015-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1416963&HistoricalAwards=false
• 关键词: Spin; Switchable; Ligands; Probing; Multistate

This award in the Chemical Synthesis (SYN) program in the Division of Chemistry at NSF supports a project by Professor Jeremy Smith from the Department of Chemistry and Biochemistry at New Mexico State University to carry out fundamental studies aimed at uncovering new reactivity of high-valent iron complexes. The project involves the use of tris(carbene)borate ligands to prepare novel iron(IV) complexes and the use of a range of simple transition metal carbonyl and nitrosyl complexes to systematically probe their electronic structures. The project is interdisciplinary in nature and involves synthetic inorganic chemistry, a variety of spectroscopic techniques, and the measurement of magnetic properties.The project could lead to the discovery of new reactivity patterns in iron(IV) complexes of potential relevance to nitrogen fixation (i.e., the conversion of atmospheric nitrogen to derivatives that can be assimilated by living organisms). In addition, this project will provide excellent interdisciplinary training of students, from undergraduate to post-doctoral, including those from groups historically underrepresented in the sciences.

NSF化学系化学合成(SYN)项目的这一奖项支持新墨西哥州立大学化学和生物化学系Jeremy Smith教授的一个项目，该项目旨在开展旨在揭示高价铁络合物新反应性的基础研究。该项目包括使用三(卡宾)硼酸盐配体制备新的铁(IV)配合物，并使用一系列简单的过渡金属羰基和亚硝基配合物来系统地探索它们的电子结构。该项目是跨学科的，涉及合成无机化学、各种光谱技术和磁性测量。该项目可能导致发现铁(IV)络合物中与固氮(即将大气中的氮转化为可被活体生物同化的衍生物)潜在相关的新的反应模式。此外，该项目将为学生提供优秀的跨学科培训，从本科生到博士后，包括那些在科学界历来代表性不足的学生。