New Multifunctional Transition Metal Oxides with Correlated Electronic Properties

具有相关电子特性的新型多功能过渡金属氧化物

基本信息

  • 批准号:
    1507252
  • 负责人:
  • 金额:
    $ 45万
  • 依托单位:
  • 依托单位国家:
    美国
  • 项目类别:
    Continuing Grant
  • 财政年份:
    2015
  • 资助国家:
    美国
  • 起止时间:
    2015-08-01 至 2019-07-31
  • 项目状态:
    已结题

项目摘要

Non-Technical AbstractWith support from the Solid State and Materials Chemistry program in the Division of Materials Research, the focus of this research is the synthesis and characterization of new transition metal oxides with low-dimensional, strongly interacting electronic properties to discover new multifunctional polar and magnetic electronic materials with fundamentally important and technologically useful behavior. The emphasis of the program is the detailed characterization of the structure and physical properties to understand the structure-property relationships. It has been demonstrated repeatedly that fundamental research of this type provides the basis for discovering new materials, which lead to novel phenomena and useful applications. The proposed work will impact the training and education of Postdoctoral fellows, graduate and undergraduate students in the PI's laboratory in the experimental synthesis and characterization of new functional solid state materials. Collaborative work of the PI with other scientists and condensed matter theorists nationally and internationally provides additional broader impact for the scientific training and education of students. These studies are expected to yield not only critical insight for the control of the properties of novel electronic and magnetic materials, but also to provide broader impacts for potential applications of the discovered materials in microelectronics and magneto-electronics for computers, sensors and communications. These are critical areas for maintaining US technological leadership worldwide. Technical AbstractThe focus of the experimental program is the synthesis and characterization of new functional transition metal compounds with strongly correlated electronic properties that are on the verge of electronic and structural instabilities, and to fine-tune the competing electronic interactions through the unstable region in a controlled way. Experience shows that materials with novel behavior are likely to be discovered, when lattice, spin, charge, orbital and other electronic interactions compete. Such competing interactions can lead to interesting and useful properties, including metal-to-insulator transition, magnetic ordering, spin and charge density wave instabilities, multiferroic, magnetoelectric behavior and superconductivity. In low-dimensional materials the interplay of competing interactions is enhanced. Systems of interest include: (1) Transition metal Ruddlesden-Popper (RP) layered phases, AO(ABO)n; (2) Layered double perovskites, AA'BB'O6; (3) Quadruple perovskites AA'3B4O12; (4) AA'BB' O6 new non-centrosymmetric corundum phases. These complex, strongly correlated electronic materials share the common feature of an interplay between localized and itinerant degrees of freedom, a highly variable conduction electron band-width, which may be tuned by changing e.g., the crystal structure, chemical composition, external strain and degree of disorder. The variability of band-width leads to a variety of important phenomena, including metal-insulator transitions (or sharp crossovers) driven by variation of temperature, magnetic field, illumination, pressure, lattice distortion and other variables. We expect that in the vicinity of these transitions the transport, electronic and magnetic properties will also change dramatically and will be tunable. The effort is a systematic study of unique synthetic routes including solid state, high pressure, "chemo douche" hydrothermal for the stabilization of new and interesting transition metal compounds. Crystal growth (essential to study anisotropic properties) of promising new phases will be attempted by e.g., flux growth, chemical vapor transport, and electrolysis. The characterization of properties by a battery of physical measurements including x-ray and neutron diffraction, electron diffraction and transmission electron microscopy, temperature dependent transport, specific heat, dielectric and magnetic properties measurements will be carried out.
在材料研究部固态和材料化学计划的支持下,本研究的重点是合成和表征具有低维、强相互作用电子性质的新型过渡金属氧化物,以发现具有基本重要和技术有用行为的新型多功能极性和磁性电子材料。该计划的重点是对结构和物理性质的详细表征,以了解结构与性质的关系。已经反复证明,这种类型的基础研究为发现新材料提供了基础,新材料导致了新的现象和有用的应用。拟议的工作将影响PI实验室的博士后研究员、研究生和本科生在新功能固态材料的实验合成和表征方面的培训和教育。国际和平研究所与国内外其他科学家和凝聚态理论家的合作工作为学生的科学培训和教育提供了更广泛的影响。这些研究不仅有望为控制新型电子和磁性材料的性能提供重要的见解,而且还将为所发现的材料在计算机、传感器和通信的微电子学和磁电子学中的潜在应用提供更广泛的影响。这些都是保持美国在全球技术领先地位的关键领域。技术摘要实验计划的重点是合成和表征具有强相关电子性质的新型功能过渡金属化合物,这些化合物处于电子和结构不稳定的边缘,并以可控的方式微调通过不稳定区域的竞争电子相互作用。经验表明,当晶格、自旋、电荷、轨道和其他电子相互作用相互竞争时,具有新颖行为的材料很可能被发现。这种相互竞争的相互作用可以产生有趣和有用的性质,包括金属到绝缘体的转变、磁有序、自旋和电荷密度波不稳定性、多铁性、磁电行为和超导电性。在低维材料中,竞争相互作用的相互作用被增强。感兴趣的系统包括:(1)过渡金属Ruddlesden-Popper(RP)层状相,AO(ABO)n;(2)层状双钙钛矿,AA‘BB’O6;(3)四重钙钛矿AA‘3B4O12;(4)AA’BB‘O6新的非中心对称刚玉相。这些复杂的、强相关的电子材料共有一个共同的特征,即定域自由度和巡回自由度之间的相互作用,高度可变的传导电子带宽,可以通过改变晶体结构、化学成分、外部应变和无序程度来调节。带宽的变化导致了许多重要的现象,包括由温度、磁场、光照、压力、晶格变形等变量驱动的金属-绝缘体转变(或急剧交叉)。我们预计,在这些转变附近,输运、电子和磁性也将发生巨大变化,并将是可调的。这项工作是对独特的合成路线进行系统研究,包括固态、高压、“化学冲洗”水热,以稳定新的和有趣的过渡金属化合物。例如,将通过助熔剂生长、化学气相传输和电解来尝试生长(对研究各向异性性质至关重要)有前途的新相的晶体生长。将通过一系列物理测量来表征性能,包括X射线和中子衍射、电子衍射和透射电子显微镜、随温度变化的输运、比热、介电和磁性测量。

项目成果

期刊论文数量(0)
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Martha Greenblatt其他文献

Ion-selective sensors based on molybdenum bronzes
  • DOI:
    10.1007/s100080100249
  • 发表时间:
    2002-08-01
  • 期刊:
  • 影响因子:
    2.600
  • 作者:
    Pavel Shuk;Ulrich Guth;Martha Greenblatt
  • 通讯作者:
    Martha Greenblatt
Nonmetallic metal toward a pressure-induced bad-metal state in two-dimensional Cu3LiRu2O6
非金属金属在二维 Cu3LiRu2O6 中走向压力诱导的不良金属态
  • DOI:
    10.1039/c9cc06691h
  • 发表时间:
    2020
  • 期刊:
  • 影响因子:
    4.9
  • 作者:
    Bin Huang;Ziyi Liu;Yifeng Han;Shuang Zhao;Meixia Wu;Corey E Frank;Martha Greenblatt;Mark Croft;Nicholas F Quackenbush;Sizhan Liu;Trevor A Tyson;Lei Zhang;Junliang Sun;Pengfei Shan;Jianhong Dai;Xiaohui Yu;Jinguang Cheng;Man-Rong Li
  • 通讯作者:
    Man-Rong Li
Polar and Magnetic Mn2FeMO6 (M: Nb, Ta) with LiNbO3‐Type Structure: High‐Pressure Synthesis.
  • DOI:
    10.1002/chin.201344012
  • 发表时间:
    2013-10
  • 期刊:
  • 影响因子:
    0
  • 作者:
    Martha Greenblatt
  • 通讯作者:
    Martha Greenblatt
Reversible Structural Transformation between Polar Polymorphs of Li2GeTeO6
Li2GeTeO6 极性多晶型之间的可逆结构转变
  • DOI:
    10.1021/acs.inorgchem.8b03114
  • 发表时间:
    2019
  • 期刊:
  • 影响因子:
    4.6
  • 作者:
    Mei-Huan Zhao;Wei Wang;Yifeng Han;Xueli Xu;Zhigao Sheng;Yaojin Wang;Meixia Wu;Christoph P. Grams;Joachim Hemberger;David Walker;Martha Greenblatt;Man-Rong Li
  • 通讯作者:
    Man-Rong Li

Martha Greenblatt的其他文献

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{{ truncateString('Martha Greenblatt', 18)}}的其他基金

Low - Dimensional Transition Metal Oxides with Correlated Electronic Properties: Synthesis and Characterization
具有相关电子性质的低维过渡金属氧化物:合成与表征
  • 批准号:
    0966829
  • 财政年份:
    2010
  • 资助金额:
    $ 45万
  • 项目类别:
    Continuing Grant
2007 Conference on Solid State Chemistry II: Solid State Chemistry for Advanced Materials Gordon Research Conference; Oxford, UK; 2007
2007年固体化学会议II:先进材料固体化学戈登研究会议;
  • 批准号:
    0703006
  • 财政年份:
    2007
  • 资助金额:
    $ 45万
  • 项目类别:
    Standard Grant
Transition Metal Oxides with Correlated Electronic Properties: Synthesis and Characterization
具有相关电子性质的过渡金属氧化物:合成和表征
  • 批准号:
    0541911
  • 财政年份:
    2006
  • 资助金额:
    $ 45万
  • 项目类别:
    Continuing Grant
The 2005 Solid State Chemistry II Gordon Conference; June 5-10, 2005; II Ciocco, Barga, Italy
2005年固态化学II戈登会议;
  • 批准号:
    0502692
  • 财政年份:
    2005
  • 资助金额:
    $ 45万
  • 项目类别:
    Standard Grant
2004 Solid State Chemistry II Gordon Research Conference; Colby-Sawyer State College, New London, NH; July 25-30, 2004
2004年固态化学II戈登研究会议;
  • 批准号:
    0415325
  • 财政年份:
    2004
  • 资助金额:
    $ 45万
  • 项目类别:
    Standard Grant
Symposium on Solid State Chemistry-MARM 2003, Princeton, NJ, June 8-11
固态化学研讨会 - MARM 2003,新泽西州普林斯顿,6 月 8-11 日
  • 批准号:
    0328128
  • 财政年份:
    2003
  • 资助金额:
    $ 45万
  • 项目类别:
    Standard Grant
Transition Metal Oxides with Correlated Electronic Properties: Synthesis and Characterization
具有相关电子性质的过渡金属氧化物:合成和表征
  • 批准号:
    0233697
  • 财政年份:
    2003
  • 资助金额:
    $ 45万
  • 项目类别:
    Continuing Grant
Quasi-Low-Dimensional Transition Metal Compounds: Synthesis and Characterization
准低维过渡金属化合物:合成与表征
  • 批准号:
    9907963
  • 财政年份:
    2000
  • 资助金额:
    $ 45万
  • 项目类别:
    Continuing Grant
Quasi-Low-Dimensional Reduced Transition Metal Compounds: Synthesis and Characterization
准低维还原过渡金属化合物:合成与表征
  • 批准号:
    9613106
  • 财政年份:
    1997
  • 资助金额:
    $ 45万
  • 项目类别:
    Continuing Grant
U.S.-China Cooperative Research: Design of New Solid Electrolyte Composites by Dispersion of Conducting Salts in Microporous Solids
中美合作研究:通过导电盐在微孔固体中的分散设计新型固体电解质复合材料
  • 批准号:
    9412815
  • 财政年份:
    1995
  • 资助金额:
    $ 45万
  • 项目类别:
    Standard Grant

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New multifunctional ligation strategies for tuning transition metal reactivity
用于调节过渡金属反应性的新型多功能连接策略
  • 批准号:
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  • 财政年份:
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  • 批准号:
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  • 财政年份:
    2009
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    $ 45万
  • 项目类别:
    University Faculty Award
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  • 财政年份:
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用于调节过渡金属反应性的新型多功能连接策略
  • 批准号:
    312624-2008
  • 财政年份:
    2008
  • 资助金额:
    $ 45万
  • 项目类别:
    Discovery Grants Program - Individual
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用于调节过渡金属反应性的新型多功能连接策略
  • 批准号:
    312624-2005
  • 财政年份:
    2007
  • 资助金额:
    $ 45万
  • 项目类别:
    Discovery Grants Program - Individual
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用于调节过渡金属反应性的新型多功能连接策略
  • 批准号:
    314950-2005
  • 财政年份:
    2007
  • 资助金额:
    $ 45万
  • 项目类别:
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用于调节过渡金属反应性的新型多功能连接策略
  • 批准号:
    314950-2005
  • 财政年份:
    2006
  • 资助金额:
    $ 45万
  • 项目类别:
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用于调节过渡金属反应性的新型多功能连接策略
  • 批准号:
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