From Carbon-Rich Bowls to Nanobelts and Warped Nanographene: Self-Assembly and Metal Ion Intercalation Upon Multi-Charging

从富碳碗到纳米带和翘曲纳米石墨烯：多次充电时的自组装和金属离子嵌入

• 批准号: 1608628
• 负责人: Marina Petrukhina
• 金额: $ 45万
• 依托单位: SUNY at Albany
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2016
• 资助国家: 美国
• 起止时间: 2016-09-15 至 2021-02-28
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1608628&HistoricalAwards=false
• 关键词: Carbon; Rich; Bowls; Nanobelts; Warped

This NSF award by the Macromolecular, Supramolecular and Nanochemistry Program of the Chemistry Division supports the project by Professor Marina A. Petrukhina, a faculty member in the Department of Chemistry at the State University of New York at Albany. This project is to explore a diverse set of novel nanocarbon materials ranging from carbon bowls to nanobelts and warped nanographene. Studies of the addition of several electrons by novel nanostructured systems may improve our understanding of their fundamental properties. The research may also expand the applications of carbon-rich materials in several technological fields ranging from electronics to energy storage. This research lies at the interface of organometallic, supramolecular and nanochemistry and provides unique educational and research experiences for graduate and undergraduate students at the University at Albany. The project is designed to engage the students in a modern interdisciplinary research in synthetic, structural and materials chemistry and thus, to prepare them for successful careers in chemistry.This research includes a broad fundamental investigation of chemical reduction processes occurring on novel curved and strained nanocarbon systems with different structural topologies ranging from carbon-rich bowl-shaped polyarenes to nanobelts and warped nanographene sheets. This diverse set of structurally well-defined carbon materials provides unique opportunities to study their multi-electron uptake properties at the molecular level. Specifically, investigations of the structural consequences of adding multiple electrons to the curved and bent surfaces are being pursued. Studies of alkali metal intercalation and self-assembly trends related to the non-planar and highly charged carbanions is also studied. As a result, this research may improve our fundamental understanding of the redox behavior and electron transport properties of carbonaceous nanomaterials having different structures and nanosized dimensions. The project may assist in describing alkali metal ion intercalation in between non-planar carbon surfaces, which is important for the advancement of carbon-based anode materials in energy storage devices. This fundamental research may advance the materials chemistry applications of curved carbon-rich polyarenes and enhance education opportunities for graduate and undergraduate students at the University at Albany. The education plan targets training of the next generation of materials chemists, including women and minorities, and is well integrated with the research.

该NSF奖由化学系的大分子、超分子和纳米化学项目授予，支持Marina A.位于奥尔巴尼的纽约州立大学化学系教员Petrukhina说。该项目旨在探索一系列新颖的纳米碳材料，从碳碗到纳米带和扭曲的纳米石墨烯。通过研究新型纳米结构体系的多电子加成，可以提高我们对其基本性质的理解。 这项研究还可能扩大富碳材料在从电子到储能等多个技术领域的应用。 这项研究是在有机金属，超分子和纳米化学的接口，并提供了独特的教育和研究经验的研究生和本科生在奥尔巴尼大学。该项目旨在让学生参与合成，结构和材料化学的现代跨学科研究，从而为他们在化学领域的成功职业做好准备。该研究包括对新型弯曲和应变纳米碳系统的化学还原过程进行广泛的基础研究，这些系统具有不同的结构拓扑结构，从富含碳的碗状聚芳烃到纳米带和扭曲的纳米石墨烯片。这种结构明确的碳材料提供了在分子水平上研究其多电子吸收特性的独特机会。具体而言，正在研究向弯曲表面添加多个电子的结构后果。 研究了与非平面和高电荷碳负离子相关的碱金属插层和自组装趋势。因此，本研究可能会提高我们的氧化还原行为和电子传输性能的碳纳米材料具有不同的结构和纳米尺寸的基本理解。该项目可能有助于描述碱金属离子在非平面碳表面之间的嵌入，这对于能量存储设备中碳基阳极材料的进步非常重要。这项基础研究可能会推进弯曲富碳聚芳烃的材料化学应用，并提高奥尔巴尼大学研究生和本科生的教育机会。教育计划的目标是培训下一代材料化学家，包括妇女和少数民族，并与研究很好地结合起来。

项目成果

Dimerization of indenocorannulene radicals: imposing stability through increasing strain and curvature

茚并环烯自由基的二聚化：通过增加应变和曲率来增强稳定性

• DOI: 10.1039/d0qo00686f
• 发表时间: 2020
• 期刊: Organic Chemistry Frontiers
• 影响因子: 5.4
• 作者: Rogachev, Andrey Yu.;Zhu, Yikun;Zhou, Zheng;Liu, Shuyang;Wei, Zheng;Petrukhina, Marina A.
• 通讯作者: Petrukhina, Marina A.

Dianion and Dication of Tetracyclopentatetraphenylene as Decoupled Annulene‐within‐an‐Annulene Models

四环戊四亚苯基的双阴离子和双阳离子作为解耦环烯 — 内环烯模型

• DOI: 10.1002/anie.202115316
• 发表时间: 2021
• 期刊: Angewandte Chemie International Edition
• 作者: Miyoshi, Hirokazu;Sugiura, Ryosuke;Kishi, Ryohei;Spisak, Sarah N.;Wei, Zheng;Muranaka, Atsuya;Uchiyama, Masanobu;Kobayashi, Nagao;Chatterjee, Shreyam;Ie, Yutaka
• 通讯作者: Ie, Yutaka

Mono‐reduced Corannulene: To Couple and Not to Couple in One Crystal

单还原冠环烯：在一个晶体中耦合和不耦合

• DOI: 10.1002/chem.201902992
• 发表时间: 2019
• 期刊: Chemistry – A European Journal
• 作者: Rogachev, Andrey Yu.;Alkan, Melisa;Li, Jingbai;Liu, Shuyang;Spisak, Sarah N.;Filatov, Alexander S.;Petrukhina, Marina A.
• 通讯作者: Petrukhina, Marina A.

Compressing Double [7]Helicene by Successive Charging with Electrons

通过电子连续充电压缩双[7]Helicene

• DOI: 10.1002/anie.202005852
• 发表时间: 2020
• 期刊: Angewandte Chemie International Edition
• 作者: Zhou Zheng;Fu Lin;Hu Yunbin;Wang Xiao-Ye;Wei Zheng;Narita Akimutsu;Müllen Klaus;Petrukhina Marina A.
• 通讯作者: Petrukhina Marina A.

Charging OBO‐Fused Double [5]Helicene with Electrons

• DOI: 10.1002/anie.201908658
• 发表时间: 2019-09
• 期刊: Angewandte Chemie (International Ed. in English)
• 作者: Zheng Zhou;Xiao-Ye Wang;Zheng Wei;K. Müllen;M. Petrukhina