CAREER: Colloids with programmable surfaces: A polymer approach to self-assembly

职业：具有可编程表面的胶体：自组装的聚合物方法

• 批准号: 1653465
• 负责人: Stefano Sacanna
• 金额: $ 76.5万
• 依托单位: New York University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2017
• 资助国家: 美国
• 起止时间: 2017-06-01 至 2024-05-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1653465&HistoricalAwards=false
• 关键词: CAREER; Colloids; programmable; surfaces; polymer

Non-Technical DescriptionThere is a fascinating way of imparting new properties to a material that does not require altering its chemical composition, but rather changing the structural arrangement of matter within the material itself. Creating an underlying microstructure can enable bulk materials to interact with energy in unique and unconventional ways. The result are emerging new properties that do not normally exist in nature. The practical realization of such materials, however, is not straightforward, as it requires creating microscopic features that are regularly spaced throughout a three-dimensional object. While this is not achievable via a classic top-down approach, colloidal self-assembly offers a conceptually simple route to impart such microscopic order in a bottom-up fashion.The principal investigator seeks to discover novel methodologies to manipulate and rationally assemble microscopic building blocks into complex micro-architectures and ultimately into functional new materials. Inexpensive polymers and simple electrostatic charges are used to mediate the binding interactions between the building blocks, thus effectively imparting assembly information. The results are complex "soups" of colloidal building blocks from which new materials are expected to self-assemble and emerge.The inherent interdisciplinary character of the project, which naturally bridges between chemistry, physics, and material science, offers a broad range of teaching opportunities from high school to graduate students. Educational and broader outreach goals include the development of a publicly available "colloidal library" - a Web Portal that connects students with research experts from various fields of science and industry.Technical DescriptionWhile the whole field of colloidal self-assembly is rapidly converging towards the use of DNA to mediate particle interactions and impart precise assembly instructions, this research addresses a new and intriguing DNA-free approach to programmable self-assembly. The research team investigates polymer-mediated colloidal interactions and proposes them as new general tools for manipulating and assembling colloidal matter. Building on the principal investigator's expertise in synthetic colloidal chemistry and soft-matter physics, the project aims to: (i) develop a modular synthetic platform for the rapid prototyping of polymer-coated colloids, (ii) use the resulting colloidal model systems to study a broad range of polymer-mediated colloidal interactions (both enthalpy and entropy driven), and (iii) use this knowledge to develop inexpensive and scalable methodologies to program the self-assembly behavior of complex colloidal fluids.This project lays the foundation for the next generation of programmable self-assembling colloidal materials.

非技术性描述有一种令人着迷的方法可以赋予材料新的特性，而不需要改变其化学成分，而是改变材料本身的物质结构排列。创建底层微观结构可以使散装材料以独特和非传统的方式与能量相互作用。结果是出现了自然界中通常不存在的新特性。然而，这种材料的实际实现并不简单，因为它需要创建在整个三维物体中规则间隔的微观特征。虽然这是无法通过经典的自上而下的方法实现的，但胶体自组装提供了一种概念上简单的途径，以自下而上的方式赋予这种微观秩序。首席研究员寻求发现新的方法来操纵和合理组装微观构建块到复杂的微结构中，并最终成为功能性新材料。廉价的聚合物和简单的静电荷用于介导结构单元之间的结合相互作用，从而有效地传递组装信息。其结果是复杂的“汤”的胶体积木，新材料有望自组装和出现。该项目固有的跨学科性质，自然桥梁之间的化学，物理和材料科学，提供了广泛的教学机会，从高中到研究生。教育和更广泛的推广目标包括开发一个公开的“胶体图书馆”-一个门户网站，连接学生与来自科学和工业各个领域的研究专家。技术说明虽然胶体自组装的整个领域正在迅速收敛到使用DNA来介导粒子相互作用和传递精确的组装指令，这项研究提出了一种新的和有趣的无DNA的可编程自组装方法。研究小组研究了聚合物介导的胶体相互作用，并提出将其作为操纵和组装胶体物质的新通用工具。基于首席研究员在合成胶体化学和软物质物理学方面的专业知识，该项目旨在：（i）开发用于聚合物包覆胶体的快速原型制作的模块化合成平台，（ii）使用所得胶体模型系统来研究广泛的聚合物介导的胶体相互作用（焓和熵驱动），以及（iii）利用这些知识来开发廉价且可扩展的方法来编程自-该项目为下一代可编程自组装胶体材料奠定了基础。

项目成果

Patchy particles made by colloidal fusion

• DOI: 10.1038/nature23901
• 发表时间: 2017-10-12
• 期刊: NATURE
• 影响因子: 64.8
• 作者: Gong, Zhe;Hueckel, Theodore;Sacanna, Stefano
• 通讯作者: Sacanna, Stefano

Targeted assembly and synchronization of self-spinning microgears

• DOI: 10.1038/s41567-018-0227-4
• 发表时间: 2018-11-01
• 期刊: NATURE PHYSICS
• 影响因子: 19.6
• 作者: Aubret, Antoine;Youssef, Mena;Palacci, Jeremie
• 通讯作者: Palacci, Jeremie

The odd free surface flows of a colloidal chiral fluid

• DOI: 10.1038/s41567-019-0603-8
• 发表时间: 2019-11-01
• 期刊: NATURE PHYSICS
• 影响因子: 19.6
• 作者: Soni, Vishal;Bililign, Ephraim S.;Irvine, William T. M.
• 通讯作者: Irvine, William T. M.

Self-organization in dipolar cube fluids constrained by competing anisotropies

受竞争各向异性约束的偶极立方流体中的自组织

• DOI: 10.1039/c7sm02174g
• 发表时间: 2018
• 期刊: Soft Matter
• 影响因子: 3.4
• 作者: Rossi, Laura;Donaldson, Joe G.;Meijer, Janne-Mieke;Petukhov, Andrei V.;Kleckner, Dustin;Kantorovich, Sofia S.;Irvine, William T.;Philipse, Albert P.;Sacanna, Stefano
• 通讯作者: Sacanna, Stefano

Mix-and-Melt Colloidal Engineering

• DOI: 10.1021/acsnano.8b00521
• 发表时间: 2018-04-01
• 期刊: ACS NANO
• 影响因子: 17.1
• 作者: Hueckel, Theodore;Sacanna, Stefano
• 通讯作者: Sacanna, Stefano