Development of a Wide-Field Transient Absorption Microscope for Applications to Two-Dimensional Perovskite Quantum Wells

开发应用于二维钙钛矿量子井的宽视场瞬态吸收显微镜

• 批准号: 1763207
• 负责人: Andrew Moran
• 金额: $ 44.48万
• 依托单位: University of North Carolina at Chapel Hill
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2018
• 资助国家: 美国
• 起止时间: 2018-08-01 至 2024-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1763207&HistoricalAwards=false
• 关键词: Development; Wide; Field; Transient; Absorption

With support from the Chemical Measurement and Imaging Program in the Division of Chemistry and the Atomic, Molecular, and Optical Experimental Physics Program (AMO-E) in the Division of Physics, Professor Moran at the University of North Carolina, Chapel Hill, is developing a microscope capable of imaging electron movement in perovskite crystals. This work is motivated by the potential for solar energy harvesting demonstrated by perovksites. The perovskite crystals targeted in this project have two-dimensional (2D) shapes where the faces of the crystals have millimeter-scale dimensions. Such 2D perovskites absorb light in the visible range and are relatively resistant to humidity, which is desirable for harnessing solar energy. Professor Moran and his team plan to simultaneously monitor multiple places on the crystal surface to get statistical information on electron movement in the crystals. The information from these experiments can be used to guide material synthesis to make better solar energy conversion devices. Graduate and undergraduate students involved in this project become proficient in chemistry, computer programming, machining, electronics, and optics as the research group is building most of their own equipment. In addition, Professor Moran and his students supervise laboratory exercises that illustrate the principles of optics and solar cells for middle and high-school students in collaboration with the Morehead Planetarium on the UNC campus.Professor Moran at the University of North Carolina, Chapel Hill is developing a diffractive optic-based transient absorption microscope capable of imaging electron diffusion in two-dimensional (2D) perovskite quantum wells. The quantum wells targeted have garnered attention for their stabilities under humid conditions and large exciton binding energies. In addition, the research team is investigating layered systems that consist of "stacks" of quantum wells in which the band gap decreases with respect to height in the film. Thus, electronic excitations are funneled from the bottom to the top of the film in these layered perovskites. The diffractive optic-based microscope employed in this research acquires transient absorption data at 41 locations on the sample surface in a single experiment. Signals are simultaneously detected at two probe wavelengths using a pair of array detectors (e.g., wavelengths corresponding to energy donor and acceptor quantum wells). In studies of exfoliated crystals, diffusivities of excitons are being measured at a number of excitation wavelengths to establish a quantitative relationship between the carrier diffusivity and excitation energy. Statistical distributions of diffusion rates are generated by analyzing the dynamics at 41 different spots on the sample. The information derived from these experiments can be used to guide materials synthesis and device engineering. Graduate and undergraduate students becoming proficient in computer programming, machining, electronics, and optics as the research group is building most of their own equipment.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

在化学系化学测量和成像项目以及物理系原子、分子和光学实验物理项目（AMO-E）的支持下，查佩尔山北卡罗来纳州大学的莫兰教授正在开发一种能够对钙钛矿晶体中的电子运动进行成像的显微镜。这项工作的动机是钙钛矿所展示的太阳能收集潜力。该项目中针对的钙钛矿晶体具有二维（2D）形状，其中晶体的表面具有毫米级尺寸。这种2D钙钛矿吸收可见光范围内的光并且相对耐湿，这对于利用太阳能是期望的。 Moran教授和他的团队计划同时监测晶体表面的多个位置，以获得晶体中电子运动的统计信息。从这些实验中获得的信息可以用来指导材料合成，以制造更好的太阳能转换装置。参与该项目的研究生和本科生精通化学、计算机编程、机械加工、电子和光学，因为研究小组正在建造他们自己的大部分设备。此外，Moran教授和他的学生们还负责指导实验室练习，这些实验室练习是与莫雷黑德天文馆（Morehead Planetarium）合作进行的，旨在为初中和高中学生讲解光学和太阳能电池的原理。位于查佩尔山的北卡罗来纳州大学的Moran教授正在开发一种基于衍射光学的瞬态吸收显微镜，能够对二维钙钛矿量子威尔斯中的电子扩散进行成像。目标量子威尔斯已获得关注，其在潮湿条件下的稳定性和大的激子结合能。此外，该研究小组正在研究由量子威尔斯“堆栈”组成的分层系统，其中带隙随薄膜高度而减小。因此，在这些层状钙钛矿中，电子激发从膜的底部到顶部成漏斗状。 在这项研究中采用的基于衍射光学的显微镜在一个单一的实验中获得在样品表面上的41个位置的瞬态吸收数据。使用一对阵列检测器（例如，对应于能量施主和受主量子威尔斯阱的波长）。在剥离晶体的研究中，在许多激发波长下测量激子的扩散率，以建立载流子扩散率和激发能量之间的定量关系。扩散速率的统计分布是通过分析样品上41个不同点的动力学而产生的。从这些实验中得到的信息可以用来指导材料合成和器件工程。研究生和本科生成为精通计算机编程，机械加工，电子和光学的研究小组正在建立自己的大部分设备。这个奖项反映了NSF的法定使命，并已被认为是值得通过评估使用基金会的智力价值和更广泛的影响审查标准的支持。

项目成果

Origin of layered perovskite device efficiencies revealed by multidimensional time-of-flight spectroscopy

多维飞行时间光谱揭示层状钙钛矿器件效率的起源

• DOI: 10.1063/5.0072976
• 发表时间: 2022
• 期刊: The Journal of Chemical Physics
• 作者: Ouyang, Zhenyu;Zhou, Ninghao;McNamee, Meredith G.;Yan, Liang;Williams, Olivia F.;Gan, Zijian;Gao, Ran;You, Wei;Moran, Andrew M.
• 通讯作者: Moran, Andrew M.

Probing Carrier Transport in Layered Perovskites with Nonlinear Optical and Photocurrent Spectroscopies

• DOI: 10.1021/acs.jpcc.1c00654
• 发表时间: 2021-04
• 期刊: Journal of Physical Chemistry C
• 影响因子: 3.7
• 作者: Ninghao Zhou;Zhenyu Ouyang;M. McNamee;Olivia F. Williams;Zhenkun Guo;Liang Yan;Jun Hu;W. You;Andrew M. Moran

Uncovering Transport Mechanisms in Perovskite Materials and Devices with Recombination-Induced Action Spectroscopies

• DOI: 10.1021/acs.jpcc.2c08851
• 发表时间: 2023-02-02
• 期刊: JOURNAL OF PHYSICAL CHEMISTRY C
• 影响因子: 3.7
• 作者: McNamee, Meredith G.;Ouyang, Zhenyu;Moran, Andrew M.
• 通讯作者: Moran, Andrew M.

Elucidation of Quantum-Well-Specific Carrier Mobilities in Layered Perovskites

层状钙钛矿中量子阱特定载流子迁移率的阐明

• DOI: 10.1021/acs.jpclett.0c03596
• 发表时间: 2021
• 期刊: The Journal of Physical Chemistry Letters
• 作者: Zhou, Ninghao;Ouyang, Zhenyu;Yan, Liang;McNamee, Meredith G.;You, Wei;Moran, Andrew M.
• 通讯作者: Moran, Andrew M.

Nonlinear Photocurrent Spectroscopy of Layered 2D Perovskite Quantum Wells

层状二维钙钛矿量子阱的非线性光电流光谱

• DOI: 10.1021/acs.jpclett.9b02959
• 发表时间: 2019
• 期刊: The Journal of Physical Chemistry Letters
• 作者: Zhou, Ninghao;Hu, Jun;Ouyang, Zhenyu;Williams, Olivia F.;Yan, Liang;You, Wei;Moran, Andrew M.
• 通讯作者: Moran, Andrew M.