Collaborative Research: Design and Study of Chalcogen-Containing Cationic Dyes for Photocatalysis

开发将分子转化为有用材料和产品的方法是化学家面临的一个关键挑战。一种常见的转化是氧化反应，即在分子中加入氧或从分子中除去电子。氧化反应往往依赖于产生大量废物的有毒试剂。使用分子氧可以降低这些反应的成本和产生的废物量。空气中也有丰富的分子氧。科学家们通常不知道如何利用大气中的氧气将分子转化为所需的产物。在这个项目中，波特兰州立大学的麦考密克博士和约翰？布法罗大学的蒂蒂和库克正在研究一种染料，这种染料可以利用光能与大气中的氧气进行理想的分子转化。通过了解改变染料的结构如何影响其反应性，可能有可能控制和靶向这些氧化反应。Drs。麦考密克、迪蒂和库克致力于通过实施新课程来增加可持续发展领域的教育。他们为学生提供研究实习机会，以提高他们对发展对环境影响的认识，以及他们作为科学家在创造可持续解决方案方面的作用。课程修订可能会增加学生对可持续性和光化学问题的参与。这些模块被分发给全国各地的学校，以便采用以绿色化学、环境保护和可再生能源原则为重点的课程。一支更积极参与、更有见识的科学队伍或许能更好地解决当前和未来的可持续性问题。McCormick， dety和Cook得到化学部门化学催化项目的支持，研究含硫染料作为光催化氧化还原反应的光敏剂。利用光诱导氧化还原催化进行合成转化是人们感兴趣的，因为它在实验室和工业规模上都有可能实现小分子的绿色生产。硫原子（O， S或Se to Te）在染料的黄嘌呤或吡啶核中的交换允许控制染料的氧化还原行为，以及吸收波长，荧光产率和寿命，以及三重态产率和寿命。含硫染料起光氧化剂的作用，因为激发态可以接受电子使底物发生单电子氧化。激发态也可以在系统间从单重态过渡到三重态，然后与基态氧相互作用产生单重态氧，它可以作为一种强氧化剂。这项研究可能会通过提供过氧化氢生产途径，减少碳排放，从而减少对化石燃料的依赖。该奖项反映了美国国家科学基金会的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。

The development of methods to transform molecules into useful materials and products is a key challenge facing chemists. One common transformation is an oxidation reaction, where oxygen is added to or electrons are removed from a molecule. Oxidation reactions often rely on toxic reagents that produce a large amount of waste. The use of molecular oxygen could reduce both the cost of these reactions and the amount of waste produced. Molecular oxygen is also abundant in air. Scientists generally do not know how to use atmospheric oxygen to transform molecules into desired products. In this project, Dr. McCormick of Portland State University and Drs. Detty and Cook of the University at Buffalo are investigating dyes that can use energy from light to make desirable molecular transformations with atmospheric oxygen. By understanding how changing the structure of a dye influences its reactivity, it may be possible to control and target these oxidation reactions. Drs. McCormick, Detty, and Cook are dedicated to increasing education in areas of sustainability via the implementation of new courses. They provide research internships to students to increase their awareness of the impact of development on the environment and their role as scientists in creating sustainable solutions. The curriculum revisions may increase student engagement in issues of sustainability and photochemistry. The modules are disseminated to allow schools across the country to adopt the curriculum, which focuses on on principles of green chemistry, environmental protection, and renewable energy. A more engaged and informed science workforce may be better able to solve current and future problems of sustainability.Drs. McCormick, Detty, and Cook are supported by the Chemical Catalysis Program of the Chemistry Division to investigate chalcogen-containing dyes as photosensitizers for photocatalytic redox reactions. The use of photo-induced redox catalysis for synthetic transformations is of interest due to its potential for the green production of small molecules at both laboratory and industrial scale. The interchange of the chalcogen atoms (O, S, or Se to Te) in the xanthylium or pyrylium core of the dyes allows control of redox behavior in the dyes, as well as wavelengths of absorption, fluorescence yields and lifetimes, and triplet yields and lifetimes. The chalcogen-containing dyes function as photo-oxidants in that the excited state can accept an electron to give a one-electron oxidation of a substrate. The excited state can also intersystem-cross from singlet to triplet and then interact with ground-state oxygen to generate singlet-oxygen, which can function as a potent oxidant. This research may result in a decreased reliance on fossil fuels by providing a route to hydrogen peroxide production, decreasing carbon emissions.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.