Collaborative Research: Design and Study of Chalcogen-Containing Cationic Dyes for Photocatalysis

合作研究：光催化含硫阳离子染料的设计与研究

• 批准号: 1800599
• 负责人: Theresa McCormick
• 金额: $ 29.17万
• 依托单位: Portland State University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2018
• 资助国家: 美国
• 起止时间: 2018-07-01 至 2022-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1800599&HistoricalAwards=false
• 关键词: Collaborative; Research; Design; Study; Chalcogen

The development of methods to transform molecules into useful materials and products is a key challenge facing chemists. One common transformation is an oxidation reaction, where oxygen is added to or electrons are removed from a molecule. Oxidation reactions often rely on toxic reagents that produce a large amount of waste. The use of molecular oxygen could reduce both the cost of these reactions and the amount of waste produced. Molecular oxygen is also abundant in air. Scientists generally do not know how to use atmospheric oxygen to transform molecules into desired products. In this project, Dr. McCormick of Portland State University and Drs. Detty and Cook of the University at Buffalo are investigating dyes that can use energy from light to make desirable molecular transformations with atmospheric oxygen. By understanding how changing the structure of a dye influences its reactivity, it may be possible to control and target these oxidation reactions. Drs. McCormick, Detty, and Cook are dedicated to increasing education in areas of sustainability via the implementation of new courses. They provide research internships to students to increase their awareness of the impact of development on the environment and their role as scientists in creating sustainable solutions. The curriculum revisions may increase student engagement in issues of sustainability and photochemistry. The modules are disseminated to allow schools across the country to adopt the curriculum, which focuses on on principles of green chemistry, environmental protection, and renewable energy. A more engaged and informed science workforce may be better able to solve current and future problems of sustainability.Drs. McCormick, Detty, and Cook are supported by the Chemical Catalysis Program of the Chemistry Division to investigate chalcogen-containing dyes as photosensitizers for photocatalytic redox reactions. The use of photo-induced redox catalysis for synthetic transformations is of interest due to its potential for the green production of small molecules at both laboratory and industrial scale. The interchange of the chalcogen atoms (O, S, or Se to Te) in the xanthylium or pyrylium core of the dyes allows control of redox behavior in the dyes, as well as wavelengths of absorption, fluorescence yields and lifetimes, and triplet yields and lifetimes. The chalcogen-containing dyes function as photo-oxidants in that the excited state can accept an electron to give a one-electron oxidation of a substrate. The excited state can also intersystem-cross from singlet to triplet and then interact with ground-state oxygen to generate singlet-oxygen, which can function as a potent oxidant. This research may result in a decreased reliance on fossil fuels by providing a route to hydrogen peroxide production, decreasing carbon emissions.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

开发将分子转化为有用材料和产品的方法是化学家面临的关键挑战。一种常见的转化是氧化反应，其中氧被添加到分子中或电子被从分子中移除。氧化反应通常依赖于产生大量废物的有毒试剂。 使用分子氧可以降低这些反应的成本和产生的废物量。分子氧在空气中也很丰富。 科学家们通常不知道如何利用大气中的氧气将分子转化为所需的产品。在这个项目中，波特兰州立大学的麦考密克博士和布法罗大学的戴蒂博士和库克博士正在研究染料，这种染料可以利用光能与大气中的氧气进行理想的分子转化。通过了解改变染料的结构如何影响其反应性，有可能控制和靶向这些氧化反应。McCormick，Detty和Cook致力于通过实施新课程来增加可持续发展领域的教育。他们为学生提供研究实习机会，以提高他们对发展对环境的影响以及他们作为科学家在创造可持续解决方案方面的作用的认识。 课程修订可能会增加学生对可持续性和光化学问题的参与。这些单元的传播是为了使全国各地的学校采用侧重于绿色化学、环境保护和可再生能源原则的课程。一个更积极参与和知情的科学工作者可能更好地解决当前和未来的可持续性问题。麦考密克博士，Detty和库克由化学部的化学催化计划支持，研究含硫族元素的染料作为光催化氧化还原反应的光敏剂。由于光诱导氧化还原催化在实验室和工业规模上用于小分子的绿色生产的潜力，其用于合成转化的用途是令人感兴趣的。染料的黄嘌呤或吡喃核中硫族元素原子（O、S或Se至Te）的交换允许控制染料中的氧化还原行为，以及吸收波长、荧光产率和寿命，以及三重态产率和寿命。含硫族元素的染料用作光氧化剂，因为激发态可以接受电子以给出基底的单电子氧化。激发态也可以从单线态到三线态的系统间交叉，然后与基态氧相互作用产生单线态氧，单线态氧可以作为有效的氧化剂。 这项研究可能会通过提供一条生产过氧化氢的路线来减少对化石燃料的依赖，减少碳排放。该奖项反映了NSF的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。

项目成果

Singlet oxygen quantum yields determined by oxygen consumption

• DOI: 10.1016/j.jphotochem.2019.04.029
• 发表时间: 2019-06-01
• 期刊: JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
• 影响因子: 4.3
• 作者: Lutkus, Luke, V;Rickenbach, Sam S.;McCormick, Theresa M.
• 通讯作者: McCormick, Theresa M.

Empirical DFT Model to Predict Triplet Quantum Yield Through Singlet Oxygen Yields

通过单线态氧产率预测三线态量子产率的经验 DFT 模型

• DOI: 10.1002/cptc.202100205
• 发表时间: 2022
• 期刊: ChemPhotoChem
• 影响因子: 3.7
• 作者: Steinkamp, Bret A.;Lutkus, Luke V.;Lewis, Rob;McCormick, Theresa M.
• 通讯作者: McCormick, Theresa M.

Importance of Singlet Oxygen in Photocatalytic Reactions of 2-Aryl-1,2,3,4-tetrahydroisoquinolines Using Chalcogenorosamine Photocatalysts

• DOI: 10.1021/acs.organomet.9b00126
• 发表时间: 2019-06
• 期刊: Organometallics
• 影响因子: 2.8
• 作者: J. Clark;Jacqueline E. Hill;Irving D. Rettig;Joshua J. Beres;R. Ziniuk;Tymish Y. Ohulchanskyy;T. McCormick;M. Detty

Enrolling reactive oxygen species in photon-to-chemical energy conversion: fundamentals, technological advances, and applications

• DOI: 10.1080/23746149.2021.1950049
• 发表时间: 2021-01
• 期刊: Advances in Physics: X
• 作者: Irving D. Rettig;T. McCormick