Hydrothermal Brines: New Media for the Synthesis and Crystal Growth of Materials

热液:材料合成和晶体生长的新介质

基本信息

  • 批准号:
    1808371
  • 负责人:
  • 金额:
    $ 54.07万
  • 依托单位:
  • 依托单位国家:
    美国
  • 项目类别:
    Standard Grant
  • 财政年份:
    2018
  • 资助国家:
    美国
  • 起止时间:
    2018-06-15 至 2022-05-31
  • 项目状态:
    已结题

项目摘要

Non-Technical SummaryThis project explores new solid-state materials with potentially useful properties. The funding from the Solid State and Materials Chemistry Program supports continued development of a novel approach to synthesis of new materials, specifically a high temperature hydrothermal technique in which reactions are performed in water at exceptionally high temperatures (700 degrees C) and pressures (20,000 psi). These conditions are similar to those deep within the Earth, and often result in formation of high quality single crystals of new products. Such extreme reaction conditions are almost unknown in any other laboratories in the world. Because of this, compounds can be prepared that are completely new and unanticipated, and challenge existing theories of structure and bonding. Many of these unusual new materials have unexpectedly useful properties. Some can be used in lasers, ultrahigh resolution micromachining, new magnetic devices and possibly quantum communication and quantum computers. This research is directly applicable to one of the NSF Big Ideas: "The Quantum Leap: Leading the Next Quantum Revolution". The new techniques used in this program typically lead to crystals of exceptional size and quality, therefore they can be studied in greater detail than many other materials. The comprehensive investigation of these new crystal materials provides important insights into the next generation of new materials. Because the techniques employed in this research are used almost nowhere else in the world, the students in this program learn a unique skill set enabling them to stand out as the next generation of researchers.Technical SummaryThis program, funded by the Solid State and Materials Chemistry program in the Division of Materials Research, is a next-stage extension of high temperature hydrothermal synthesis as a route to new solid-state compounds. The primary emphasis in this project is on the investigation of a new class of mineralizers, namely hydrothermal brines. Brines are fluids containing concentrated salts like halides and carbonates. Such fluids have received almost no systematic laboratory study, but preliminary investigation suggests that they are excellent media for the synthesis and single crystal growth of an enormous new class of interesting compounds. The program focuses on open shell first row transition metal ions that are complexed by a range of oxyanion building blocks. These include vanadates, phosphates, germanates, gallates, stannates and other related building blocks containing a variety of structural and bridging characteristics. The new crystals exhibit a number of attractive physical properties including acentricity, polarity and frustrated magnetic behavior. The research targets specific types of compounds with these desirable properties for new piezoelectrics, multiferroics and similar materials. Because the synthesis techniques employed in this research are used almost nowhere else in the world, the students in this program learn a unique skill set enabling them to stand out as the next generation of researchers.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.
非技术摘要该项目探索具有潜在有用特性的新型固态材料。来自固态和材料化学计划的资金支持继续开发新材料合成的新方法,特别是高温水热技术,其中反应在极高的温度(700摄氏度)和压力(20,000 psi)下在水中进行。这些条件与地球深处的条件相似,通常会形成高质量的新产品单晶。这种极端的反应条件在世界上任何其他实验室几乎都是未知的。正因为如此,可以制备出全新的和未预料到的化合物,并挑战现有的结构和键合理论。这些不寻常的新材料中有许多具有意想不到的有用特性。其中一些可以用于激光器、高分辨率微机械加工、新的磁性设备,还可能用于量子通信和量子计算机。这项研究直接适用于NSF的一个大想法:“量子飞跃:领导下一次量子革命”。该计划中使用的新技术通常会导致晶体的特殊尺寸和质量,因此它们可以比许多其他材料更详细地研究。对这些新晶体材料的全面研究为下一代新材料提供了重要的见解。由于该研究所采用的技术在世界上几乎没有其他地方使用,因此该项目的学生将学习一套独特的技能,使他们能够脱颖而出,成为下一代研究人员。技术概述该项目由材料研究部的固态和材料化学项目资助,是高温水热合成作为新固态化合物路线的下一阶段延伸。该项目的主要重点是调查一类新的矿化剂,即热液卤水。盐水是含有像卤化物和碳酸盐这样的浓盐的流体。这种流体几乎没有得到系统的实验室研究,但初步研究表明,它们是合成和单晶生长的一个巨大的新一类有趣的化合物的优良介质。该计划的重点是开壳层的第一行过渡金属离子是复杂的一系列含氧阴离子积木。这些包括钒酸盐、磷酸盐、锗酸盐、没食子酸盐、锡酸盐和含有各种结构和桥接特征的其他相关构建块。新晶体表现出许多有吸引力的物理性质,包括偏心性,极性和受抑磁行为。该研究的目标是特定类型的化合物,这些化合物具有新的压电体,多铁性和类似材料的理想特性。由于该研究中使用的合成技术在世界上几乎没有其他地方使用,因此该项目的学生学习了独特的技能,使他们能够脱颖而出,成为下一代研究人员。该奖项反映了NSF的法定使命,并通过使用基金会的智力价值和更广泛的影响审查标准进行评估,被认为值得支持。

项目成果

期刊论文数量(15)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
Crystal Structure and Preferential Site Occupancy in Cs6Mn(H2O)2(VO3)8 and Cs5KMn(H2O)2(VO3)8
Cs6Mn(H2O)2(VO3)8 和 Cs5KMn(H2O)2(VO3)8 的晶体结构和择优位点占据
  • DOI:
    10.1007/s10870-019-00787-4
  • 发表时间:
    2019
  • 期刊:
  • 影响因子:
    0.8
  • 作者:
    Pellizzeri, Tiffany M.;McMillen, Colin D.;Ivey, Kimberly;Kolis, Joseph W.
  • 通讯作者:
    Kolis, Joseph W.
Magnetic Ground State Crossover in a Series of Glaserite Systems with Triangular Magnetic Lattices
一系列具有三角形磁晶格的玻璃晶系统中的磁基态交叉
  • DOI:
    10.1021/acs.inorgchem.8b03418
  • 发表时间:
    2019
  • 期刊:
  • 影响因子:
    4.6
  • 作者:
    Sanjeewa, Liurukara D.;Garlea, V. Ovidiu;McGuire, Michael A.;McMillen, Colin D.;Kolis, Joseph W.
  • 通讯作者:
    Kolis, Joseph W.
Lanthanide rhenium oxide single crystals from hydrothermal fluids: Synthesis and Structures of Ln2ReO5 (Ln = Pr, Nd), Ln3ReO7 (Ln = Gd and Tb) and Ln6ReO12 (Ln = Yb, Lu)
热液中的镧系氧化铼单晶:Ln2ReO5 (Ln = Pr, Nd)、Ln3ReO7 (Ln = Gd 和 Tb) 和 Ln6ReO12 (Ln = Yb, Lu) 的合成和结构
  • DOI:
    10.1016/j.jssc.2021.122779
  • 发表时间:
    2022
  • 期刊:
  • 影响因子:
    3.3
  • 作者:
    Kolambage, Mudithangani T.K.;Wetzel, George;Koehler, Kelliann;McMillen, Colin D.;Kolis, Joseph W.
  • 通讯作者:
    Kolis, Joseph W.
Hydrothermal Single Crystal Growth and Structural Investigation of the Stuffed Tridymite Family as NLO materials
  • DOI:
    10.1016/j.jallcom.2022.164634
  • 发表时间:
    2022-03
  • 期刊:
  • 影响因子:
    6.2
  • 作者:
    R. Terry;Daniel Vinton;C. McMillen;Xiangfeng Chen;Lin Zhu;J. Kolis
  • 通讯作者:
    R. Terry;Daniel Vinton;C. McMillen;Xiangfeng Chen;Lin Zhu;J. Kolis
Yb:Lu2O3 hydrothermally grown single-crystal high-resolution absorption spectra obtained between 8 and 300 K
在 8 至 300 K 范围内获得 Yb:Lu2O3 水热生长单晶高分辨率吸收光谱
  • DOI:
    10.1007/s00340-020-7412-8
  • 发表时间:
    2020
  • 期刊:
  • 影响因子:
    0
  • 作者:
    Brown, David C.;Fleischman, Zackery;Merkle, Larry D.;Sanjeewa, Liurukara D.;McMillen, Colin D.;Kolis, Joseph W.
  • 通讯作者:
    Kolis, Joseph W.
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Joseph Kolis其他文献

Synthesis and Structural Characterization of K3Th2(PO4)3F2 and RbThPO4F2 as Potential Nuclear Waste Storage Materials
  • DOI:
    10.1007/s10870-009-9658-1
  • 发表时间:
    2009-11-15
  • 期刊:
  • 影响因子:
    0.600
  • 作者:
    Matthew Mann;Joseph Kolis
  • 通讯作者:
    Joseph Kolis

Joseph Kolis的其他文献

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{{ truncateString('Joseph Kolis', 18)}}的其他基金

Low Dimensional Transition Metal Oxyanion Mulitferroics
低维过渡金属氧阴离子多铁性材料
  • 批准号:
    2219129
  • 财政年份:
    2022
  • 资助金额:
    $ 54.07万
  • 项目类别:
    Standard Grant
Novel Optical Hosts: Chemistry, Single Crystal Growth and Applications
新型光学主体:化学、单晶生长和应用
  • 批准号:
    1410727
  • 财政年份:
    2014
  • 资助金额:
    $ 54.07万
  • 项目类别:
    Continuing Grant
High Temperature Hydro Thermal Synthesis and Crystal Growth of Inorganic Oxides
无机氧化物的高温水热合成与晶体生长
  • 批准号:
    0907395
  • 财政年份:
    2009
  • 资助金额:
    $ 54.07万
  • 项目类别:
    Continuing Grant
Hydrothermal Synthesis of New Solids for Optics Applications
用于光学应用的新型固体的水热合成
  • 批准号:
    0305377
  • 财政年份:
    2003
  • 资助金额:
    $ 54.07万
  • 项目类别:
    Continuing Grant
Chemistry of New Zintl Phases in Supercritical Fluids
超临界流体中新 Zintl 相的化学
  • 批准号:
    9714408
  • 财政年份:
    1998
  • 资助金额:
    $ 54.07万
  • 项目类别:
    Continuing Grant
Coordination Chemistry of Novel Main Group Anions
新型主族阴离子的配位化学
  • 批准号:
    9102548
  • 财政年份:
    1991
  • 资助金额:
    $ 54.07万
  • 项目类别:
    Continuing Grant
Chemistry of Anionic Clusters of the P-Block Elements
P 区元素阴离子簇的化学
  • 批准号:
    8802217
  • 财政年份:
    1988
  • 资助金额:
    $ 54.07万
  • 项目类别:
    Continuing Grant

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锂盐水的生物处理
  • 批准号:
    BB/X011658/1
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    2023
  • 资助金额:
    $ 54.07万
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CAS-SC: Thermally Switchable Organic Solvents for Targeted Harvesting of Lithium Ions from Alkali Metal Cations Mixtures in Hypersaline Brines
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