Establishment and exploration of a gas ion source for micro-scale radiocarbon dating of glaciers and groundwater

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Recent progress in the operation of CO2 gas ion sources for accelerator mass spectrometer (AMS) 14C analysis on microgram-size samples opens a wide range of new applications in dating studies, e.g. for environmental and archeological applications. This proposal aims at implementing a gas ion source at the AMS system MICADAS at the Klaus-Tschira Laboratory of the Curt-Engelhorn-Zentrum für Archäometrie (CEZA) in Mannheim and to use this new capability for cutting-edge applications in environmental studies, namely the dating of small amounts of organic carbon contained in glacier ice and of specific organic compounds in ground water. Cold glaciers hold unique records on past climate and atmospheric composition. Mid-latitude ice cores furthermore enable reconstructions of recent ice chemistry changes, but cannot be dated by stratigraphic methods. For such ice bodies, only radiometric dating based on 14C analysis of organic matter contained in the ice matrix presently offers a reasonable dating potential in the late Holocene and beyond. The challenge of this approach lies in the very restricted availability of this matter, but the ability to analyse microgram samples of organic carbon from ice via a gas ion source should now enable reliable 14C dating of ice. Ground water constitutes an important water resource worldwide, especially in semi-arid regions, and in addition constitutes a useful climate archive. Dating of ground water by 14C in the dissolved inorganic carbon (DIC) is standard but problematic due to the complex carbonate geochemistry. Dating of ground water based on dissolved organic carbon (DOC) has been attempted with mixed success, but now the new analytical developments enable compound-specific 14C analyses of the various DOC components, offering the chance to identify compounds suitable for dating. This project is based on the extensive experience of the collaborating scientists in 14C analytics and applications as well as in the use of glacier ice and ground water as archives, including the development and application of 14C dating methods for these systems. It will establish 14C-measurements at the MICADAS AMS of the CEZA via a gas ion source on a routine base to analyse CO2-samples in the range of 5 to 40 microgram C at a precision down to 0,5 %. By improving existing sample preparation techniques for glacier ice samples, reliable 14C values of the particulate and dissolved organic fractions from small (some 100 g) ice samples shall be obtained. This capability will be applied to constrain ages of cold, sedimentary glaciers as well as of small scale, cold Alpine congelation ice bodies. The project will further develop and test the tools required for micro-scale, compound-specific radiocarbon dating of ground water via its organic fraction. For this purpose, ground water samples from the Upper Rhine Graben area will be analysed, where extensive isotopic data, including DIC 14C values, are available for comparison.