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Fundamental Properties and Applications of pi-Conjugated Platinum Carbene Chromophores and Polymers

π-共轭铂卡宾发色团和聚合物的基本性质和应用

基本信息

批准号：
1904288
负责人：
Kirk Schanze
金额：
$ 45万
依托单位：
University of Texas at San Antonio
依托单位国家：
美国
项目类别：
Standard Grant
财政年份：
2019
资助国家：
美国
起止时间：
2019-09-01 至 2023-08-31
项目状态：
已结题

来源：
https://www.nsf.gov/awardsearch/showAward?AWD_ID=1904288&HistoricalAwards=false
关键词：
Fundamental Properties Applications pi Conjugated

项目摘要

With this award, the Macromolecular, Supramolecular and Nanochemistry Program in the Division of Chemistry is supporting Professor Kirk Schanze at the University of Texas at San Antonio. This investigation brings together several distinct studies that probe the fundamental, excited state properties of molecules when exposed to light. Potential applications are based on efficient light emission (phosphorescence) which enables the materials to serve as organic light-emitting diodes (OLEDs ? particularly efficient deep blue phosphors), solar cells, photodetectors, sensor and materials for medical diagnostics and therapy, which are widely used in today's society. This research will advance fundamental insights with respect to the design and synthesis of molecules that efficiently react with light contribution to large sectors of new technologies in the commercial, military and health sectors. This award provides new opportunities for undergraduate and graduate student training. Professor Schanze develops education and outreach activities involving underrepresented groups in the science-technology-engineering-math (STEM) fields at a Hispanic Serving Institution. Specifically, he will develop and distribute a module entitled 'Navigating Scientific/Technical Literature for Non-Scientists' (NSTL) with the goal of teaching the general public how to search and access the scientific, technical, and patent literature by using publicly-accessible resources and/or by using traditional subscription-based search and access tools typically available at local Universities.Platinum acetylide molecules and polymers that contain pi-conjugated organic ligands provide a unique opportunity to investigate fundamental properties of spin-allowed and -forbidden electronic excited states in delocalized electronic systems. This research focuses on several distinct studies that probe fundamental excited state properties and explore potential applications, focused particularly on new platinum-carbene based chromophores and polymers that exhibit efficient light emission. Development of such materials expands the range of accessible optoelectronic organometallic materials and improves the understanding of relationships between chromophore structure and excited state properties. A significant potential benefit could also emerge by the development of a new class of efficient deep blue phosphors for application in OLEDs. The project advances knowledge in the fields of organic, organometallic and polymer materials chemistry with potential impacts on applications of organic electronics. Special emphasis is placed on broadening the diversity of students working on this project.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

凭借这一奖项，化学学部的大分子、超分子和纳米化学项目支持德克萨斯大学圣安东尼奥分校的Kirk Schanze教授。这项研究汇集了几个不同的研究，探索暴露在光下分子的基本激发态特性。潜在的应用是基于有效的发光（磷光），使材料能够作为有机发光二极管（oled）？特别是高效的深蓝荧光粉、太阳能电池、光电探测器、传感器和医学诊断和治疗材料，这些在当今社会被广泛使用。这项研究将在设计和合成与光有效反应的分子方面推进基本见解，为商业、军事和卫生部门的大量新技术做出贡献。该奖项为本科生和研究生的培训提供了新的机会。Schanze教授在西班牙裔服务机构开展教育和推广活动，涉及科学-技术-工程-数学（STEM）领域的代表性不足的群体。具体来说，他将开发和分发一个名为“为非科学家导航科学/技术文献”（NSTL）的模块，目的是教公众如何通过使用公共可访问的资源和/或使用传统的基于订阅的搜索和访问工具来搜索和访问科学、技术和专利文献，这些工具通常在当地大学可用。铂乙酰基分子和聚合物包含π共轭有机配体提供了一个独特的机会来研究在离域电子系统中允许自旋和禁止自旋的电子激发态的基本性质。本研究的重点是几个不同的研究，探索基本的激发态性质和探索潜在的应用，特别关注新的铂-碳基发色团和聚合物，表现出高效的发光。这些材料的发展扩大了光电有机金属材料的范围，提高了对发色团结构和激发态性质之间关系的理解。开发一种新型高效的深蓝荧光粉用于oled，也可能带来显著的潜在效益。该项目推进了有机、有机金属和高分子材料化学领域的知识，对有机电子学的应用有潜在的影响。特别强调的是要扩大参与这个项目的学生的多样性。该奖项反映了美国国家科学基金会的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。

项目成果

期刊论文数量（11）

专著数量（0）

科研奖励数量（0）

会议论文数量（0）

专利数量（0）

Charge-Transfer Dynamics between Cesium Lead Halide Perovskite Nanocrystals and Surface-Anchored Naphthalimide Acceptors

DOI：
10.1021/acs.jpcc.1c02622
发表时间：
2021-07
期刊：
The Journal of Physical Chemistry C
影响因子：
0
作者：
Meng Li;Silvano R. Valandro;Ru He;Yan Zhao;P. Yang;K. Schanze
通讯作者：
Meng Li;Silvano R. Valandro;Ru He;Yan Zhao;P. Yang;K. Schanze

N-heterocyclic carbene platinum-butadiyne Click/iClick complexes. Towards blue-violet phosphorescence

N-杂环卡宾铂-丁二炔 Click/iClick 络合物。

DOI：
10.1016/j.jorganchem.2022.122440
发表时间：
2022
期刊：
Journal of Organometallic Chemistry
影响因子：
2.3
作者：
He, Ru;Chakraborty, Jhonti;Islam, Tanjila;Arman, Hadi D.;Griffith, Wendell P.;Veige, Adam S.;Schanze, Kirk S.
通讯作者：
Schanze, Kirk S.

Effect of bromine substitution on blue phosphorescent trans -(N-heterocyclic carbene)Pt( ii ) acetylide complexes

溴取代对蓝色磷光反式-(N-杂环卡宾)Pt(ii)乙炔配合物的影响

DOI：
10.1039/d3dt01483e
发表时间：
2023
期刊：
Dalton Transactions
影响因子：
4
作者：
Khan, Amran A.;Gobeze, Habtom B.;Islam, Tanjila;Arman, Hadi D.;Schanze, Kirk S.
通讯作者：
Schanze, Kirk S.

Platinum Poly-yne Featuring N-Heterocyclic Carbene Ligands: Synthesis, Properties, and Organic Light-Emitting Diode Application