Collaborative Research: Molecular-level Understanding of Small Molecule Transport in Glassy Polymers Exhibiting Configurational Free Volume

合作研究：对具有构型自由体积的玻璃状聚合物中小分子输运的分子水平理解

• 批准号: 1926868
• 负责人: Michele Galizia
• 金额: $ 39.19万
• 依托单位: University of Oklahoma Norman Campus
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2019
• 资助国家: 美国
• 起止时间: 2019-09-01 至 2023-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1926868&HistoricalAwards=false
• 关键词: Collaborative; Research; Molecular; level; Understanding

Many new membrane materials have been developed in recent years; however, very few of them have made it to industrial applications, mainly due to lack of durability and robustness under realistic operating conditions. This research project aims to develop a molecular-level understanding of transport mechanisms in membrane materials and to inform the development of the next generation of membrane materials that can compete with traditional energy-intensive gas separations technologies. The types of membrane materials that will be investigated have a molecular structure that creates permanent, non-collapsible voids (free volume) in the material. The free volume is available for selective gas sorption, and the molecular structure around the voids helps the material to maintain its free volume and separation performance, unlike current separation membranes. The scientific knowledge generated by this research should enable significant advances in separation membranes that will meet the needs for a broad range of industrial applications. The research project serves as a training ground for undergraduate and graduate students to perform cutting edge research and will engage students from groups underrepresented in STEM fields. The researchers will also engage in well-structured education and outreach activities, including developing new courses, formulating educational and research components for high school students, giving presentations at a public "research night" event, and creating an educational video streaming for general public. The goal of this research project is to elucidate how conformation- and configuration-based free volume contribute, individually and synergistically, to the membrane transport properties. The research hypothesis is that configurational free volume is much more stable than conformational free volume, and thus it provides unprecedented resistance to physical aging and plasticization even under harsh conditions, i.e., at high temperature and in chemically challenging environments. Iptycene-based polymers with specifically, yet systematically, varied free volume architecture will be synthesized, and the effect of configurational free volume on molecular transport will be studied. Fundamental transport properties (i.e., sorption, diffusion and permeation) will be investigated experimentally and theoretically under both ambient and harsh conditions. Finally, atomistic simulations will be performed to elucidate the underlying transport mechanism in polymers with configuration-based free volume and the effect of nano-confinement. The outcome of this project will be improved membranes for industrial gas separations, especially under harsh conditions.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

近年来开发了许多新的膜材料;然而，它们中很少有用于工业应用，主要是由于在实际操作条件下缺乏耐用性和鲁棒性。该研究项目旨在从分子水平上了解膜材料中的传输机制，并为开发可与传统能源密集型气体分离技术竞争的下一代膜材料提供信息。将被研究的膜材料类型具有在材料中产生永久的、不可塌陷的空隙（自由体积）的分子结构。自由体积可用于选择性气体吸附，并且空隙周围的分子结构有助于材料保持其自由体积和分离性能，这与当前的分离膜不同。这项研究所产生的科学知识应该能够在分离膜方面取得重大进展，以满足广泛的工业应用需求。该研究项目作为本科生和研究生进行前沿研究的培训基地，并将吸引来自STEM领域代表性不足的群体的学生。研究人员还将参与结构良好的教育和推广活动，包括开发新课程，为高中生制定教育和研究内容，在公共“研究之夜”活动中发表演讲，并为公众创建教育视频流。本研究项目的目标是阐明如何构象和构型为基础的自由体积的贡献，单独和协同作用，膜运输性能。研究假设是，构型自由体积比构象自由体积稳定得多，因此即使在苛刻条件下，它也提供了前所未有的抗物理老化和增塑性，即，在高温和具有化学挑战性的环境中。将合成具有特定但系统地变化的自由体积结构的基于异蝶烯的聚合物，并将研究构型自由体积对分子输运的影响。基本输运性质（即，吸附、扩散和渗透）将在环境和苛刻条件下进行实验和理论研究。最后，将进行原子模拟，以阐明在聚合物与配置为基础的自由体积和纳米约束的效果的基本传输机制。该项目的成果将是用于工业气体分离的膜的改进，特别是在恶劣条件下。该奖项反映了NSF的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。

项目成果

Evidence for size-sieving driven vapor sorption in polymers exhibiting configurational free volume

具有构型自由体积的聚合物中尺寸筛分驱动的蒸汽吸附的证据

• 发表时间: 2021
• 期刊: Industrial engineering chemistry research
• 作者: Box, William J.;Huang, Zihan;Guo, Ruilan;Galizia, Michele
• 通讯作者: Galizia, Michele

The mechanism of light gas transport through configurational free volume in glassy polymers

• DOI: 10.1016/j.memsci.2022.120608
• 发表时间: 2022-05-24
• 期刊: JOURNAL OF MEMBRANE SCIENCE
• 影响因子: 9.5
• 作者: Box, William J.;Huang, Zihan;Galizia, Michele
• 通讯作者: Galizia, Michele

Effect of thermal treatment on the structure and gas transport properties of a triptycene-based polybenzoxazole exhibiting configurational free volume

热处理对具有构型自由体积的三蝶烯基聚苯并恶唑的结构和气体传输性能的影响

• DOI: 10.1016/j.memsci.2019.117759
• 发表时间: 2020
• 期刊: Journal of membrane science
• 影响因子: 9.5
• 作者: Crist, R.D;Huang, Z;Guo, R;Galizia, M.
• 通讯作者: Galizia, M.