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Collaborative research: Understanding relationships between synthesis, structure, solid-state electrochemistry, and phase stability in clathrates and related materials

合作研究：了解包合物和相关材料的合成、结构、固态电化学和相稳定性之间的关系

基本信息

批准号：
2004579
负责人：
Svilen Bobev
金额：
$ 28.5万
依托单位：
University of Delaware
依托单位国家：
美国
项目类别：
Continuing Grant
财政年份：
2020
资助国家：
美国
起止时间：
2020-07-01 至 2025-03-31
项目状态：
未结题

来源：
https://www.nsf.gov/awardsearch/showAward?AWD_ID=2004579&HistoricalAwards=false
关键词：
Collaborative research Understanding relationships between

项目摘要

NON-TECHNICAL DESCRIPTION:Clathrates are a class of materials with cage-like structures that can naturally hold guest ions, a feature that may be exploited for energy storage in rechargeable batteries. However, more research is needed to understand how the structure of the clathrate affects ion migration and the durability of the material under repeated electrochemical cycling. Through this collaborative project, supported by the Solid State and Materials Chemistry program in the Division of Materials Research at NSF, researchers at Arizona State and University of Delaware jointly identify structural features of the clathrates that promote fast ion diffusion and develop new approaches to synthesize these materials. Thereby they gather new knowledge connecting the structural effects of clathrates and related compounds to their physical, electrochemical, and materials chemistry properties. The fundamental science gained from these studies could have far reaching impacts in other fields where these materials have potential applications, such as superconductors, thermoelectrics, optoelectronics, magnets, and photovoltaics. Additionally, this collaboration between two universities and three different departments (materials science, chemistry, and physics) exposes students to multidisciplinary research. Outreach and educational activities also engage students and provide interdisciplinary training and immerse them into areas outside their immediate field of expertise. TECHNICAL DESCRIPTION:This collaborative project, supported by the Solid State and Materials Chemistry program in the Division of Materials Research at NSF, identifies structural features that lead to fast ion diffusion and obtain better understanding of electrochemically driven phase transformations in Li-Tetrel (Tt) systems, particularly for clathrates and other open framework structures. The specific objectives of the research are to: (1) Understand the structural parameter space for Tt (Tt = Si, Ge, Sn) clathrate and clathrate-like materials with high ionic mobility; (2) Re-map the phase space of Li-Tt systems, including non-equilibrium phases, coupled with studies on understanding the ionic transport within these phases, and (3) Use electrochemistry to inform solid-state synthesis and vice versa, to enable new synthetic approaches for clathrates and related materials that are either intermediates in the lithiation pathways or can be used as precursors for the synthesis steps. Through a concerted approach combining the synthetic, structural and electrochemical characterization, and theoretical expertise of the PIs, this work furthers the electrochemical understanding of clathrate materials, leading to new insights on structural features that result in fast diffusion pathways, low ion migration barriers, and phase stability. Novel synthetic approaches combining high temperature coulometric titration and low temperature flux methods are used to trap kinetic/metastable phases and controllably synthesize high quality single-crystalline materials. Isostructural compounds containing key Li local environments are employed as model compounds to understand the ion (de)insertion processes in Li-Tt binary (and ternary/quaternary) compounds, with an emphasis on Tt = Ge. By means of a unique feedback loop connecting electrochemistry and synthesis, information about phases formed during electrochemical lithiation is used to design novel precursors for synthesis of clathrates, and solid-state reactions using chemical oxidation are adapted to develop electrochemical synthesis methods with finer control over composition. Synchrotron X-ray studies are used to characterize the local and crystalline structures and phase evolution during electrochemical reaction and/or synthesis. In all cases, density functional theory calculations support experimental findings and guide materials design, particularly by identifying formation energies and ionic transport mechanisms.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

非技术描述：笼形物是一类具有笼状结构的材料，可以自然地容纳客体离子，这是一种可以用于可充电电池中的能量存储的特征。然而，需要更多的研究来了解笼形物的结构如何影响离子迁移和材料在重复电化学循环下的耐久性。通过这个合作项目，在NSF材料研究部的固态和材料化学计划的支持下，亚利桑那州立大学和特拉华州大学的研究人员共同确定了促进快速离子扩散的笼形物的结构特征，并开发了合成这些材料的新方法。因此，他们收集了新的知识，将笼形物和相关化合物的结构效应与其物理，电化学和材料化学性质联系起来。从这些研究中获得的基础科学可能会对这些材料具有潜在应用的其他领域产生深远的影响，例如超导体，热电，光电子学，磁体和光电子学。此外，两所大学和三个不同部门（材料科学，化学和物理）之间的这种合作使学生能够进行多学科研究。外联和教育活动也吸引学生参与，并提供跨学科培训，使他们沉浸在其直接专业领域以外的领域。该合作项目由NSF材料研究部门的固态和材料化学计划支持，确定了导致快速离子扩散的结构特征，并更好地理解了Li-Tetrel（Tt）系统中的电化学驱动相变，特别是笼形物和其他开放式框架结构。研究的具体目标是：（1）了解Tt的结构参数空间具有高离子迁移率的（Tt = Si，Ge，Sn）笼形和类笼形材料;（2）重新绘制Li-Tt系统的相空间，包括非平衡相，并研究了解这些相中的离子输运，以及（3）使用电化学来告知固态合成，反之亦然，以实现笼形物和相关材料的新合成方法，所述笼形物和相关材料是锂化途径中的中间体或可用作合成步骤的前体。通过协调一致的方法相结合的合成，结构和电化学表征，和理论专业知识的PI，这项工作进一步的电化学理解的笼形材料，导致新的见解的结构特征，导致快速扩散途径，低离子迁移障碍，和相稳定性。结合高温库仑滴定法和低温助熔剂法的新型合成方法用于捕获动力学/亚稳相并可控地合成高质量单晶材料。同构化合物含有关键的锂局部环境作为模型化合物，以了解离子（脱）插入过程中的Li-Tt二元（和三元/四元）化合物，重点Tt = Ge。通过连接电化学和合成的独特反馈回路，关于在电化学锂化期间形成的相的信息用于设计用于合成笼形物的新型前体，并且使用化学氧化的固态反应适于开发具有对组成的更精细控制的电化学合成方法。同步辐射X射线研究用于表征电化学反应和/或合成过程中的局部和晶体结构以及相演变。在所有情况下，密度泛函理论计算支持实验结果和指导材料设计，特别是通过识别形成能和离子传输机制。该奖项反映了NSF的法定使命，并已被认为是值得通过使用基金会的智力价值和更广泛的影响审查标准进行评估的支持。