Neutron scattering studies of magnetic order and spin dynamics in two-dimensional van der Waals magnetic materials

二维范德华磁性材料中磁序和自旋动力学的中子散射研究

• 批准号: 2100741
• 负责人: Pengcheng Dai
• 金额: $ 60.11万
• 依托单位: William Marsh Rice University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2021
• 资助国家: 美国
• 起止时间: 2021-12-01 至 2025-05-31
• 项目状态: 未结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=2100741&HistoricalAwards=false
• 关键词: Neutron; scattering; studies; magnetic; order

Non-Technical abstractWhy does your cell phone get so hot? And how come the battery never lasts long enough? It is because cell phones — and other common devices like laptops and TVs — need to send electric currents through pieces of metal and transistors to power on, and they produce heat, called Ohmic heating, in the process. In fact, most of your battery’s energy is not going toward getting you online: It is producing wasted heat. Scientists are now reaching a ceiling on making those transistors better. But there is progress on a material that might make our devices even faster and last longer: a spin electronic device. Colloquially called a “spintronic,” these materials are built out of insulators instead of metal, and as such, do not produce Ohmic heating. Instead of electric currents, they rely on the intrinsic spin of an electron — which means they could transmit information without generating heat. The goal of this NSF grant is to study materials that might work as spintronics. This experimental research aims to explore and understand the magnetic properties of the materials, which are called two-dimensional van der Waals materials. To do it, we will be using a process called neutron scattering. Because neutrons do not have a charge but carry spin, the way that they scatter when aimed at a material can help us understand its magnetic properties. Practically speaking, these experiments will help further the research around spintronics and could revolutionize the electronic device industry. They can also provide deeper insight into nature: about how the inherent magnetic properties of the world around us fundamentally work. Broad impacts of this program will include training of graduate students, particularly women and under-represented minorities, and hosting undergraduate and high school students during summer. Technical abstractThis NSF project is an innovative experimental program that integrates neutron scattering experiments with lab-based materials efforts, aimed at gaining a fundamental understanding of the magnetic order and spin dynamics in bulk two-dimensional (2D) van der Waals (vdW) magnetic materials. The objective of this program is to explore and understand the microscopic origin of magnetic order and interactions in various phases of 2D vdW honeycomb and Kagomé lattice structure magnetic materials. In particular, the team will focus on bulk single crystals of CrI3, CrBr3, CrCl3, Cr(I,Br,Cl)3, Cr2Ge2Te6, alpha-RuCl3, and YMn6Sn6. The program has three components: bulk single crystal synthesis, initial materials characterization, and neutron scattering. The focus of the program will be on neutron scattering. For synthesis, the PI has established a comprehensive materials laboratory and can grow single crystals of the proposed materials. The initial characterization of these single crystals will be performed using facilities in the group, including an in-situ uniaxial pressure device. Neutron scattering will be used to study the magnetic order and spin dynamical properties of these materials. These experiments will be performed at the best facilities in the US, including the high-flux isotope reactor (HFIR) and the Spallation Neutron Source (SNS) at Oak Ridge National Laboratory (ORNL), and the NIST Center for Neutron Research (NCNR). In addition, world-class neutron scattering facilities in Europe and Japan will also be utilized when similar capabilities are unavailable in the US.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

非技术摘要为什么你的手机变得这么热？为什么电池总是用不完？这是因为手机以及笔记本电脑和电视等其他常见设备需要通过金属片和晶体管发送电流才能通电，并且它们在此过程中会产生热量，称为欧姆加热。事实上，电池的大部分能量并没有用于上网：它产生了浪费的热量。科学家们现在正在努力使这些晶体管变得更好。但有一种材料取得了进展，可以使我们的设备运行得更快、寿命更长：自旋电子设备。这些材料通常被称为“自旋电子”，由绝缘体而不是金属制成，因此不会产生欧姆加热。它们不依赖电流，而是依赖于电子的固有自旋-这意味着它们可以在不产生热量的情况下传输信息。这项NSF资助的目标是研究可能作为自旋电子学工作的材料。本实验研究的目的是探索和了解二维货车德瓦耳斯材料的磁性。为了做到这一点，我们将使用一种称为中子散射的过程。由于中子不带电荷，但带有自旋，因此它们在瞄准材料时散射的方式可以帮助我们了解其磁性。实际上，这些实验将有助于进一步研究自旋电子学，并可能彻底改变电子器件行业。它们还可以提供对自然的更深入的了解：关于我们周围世界的固有磁性如何从根本上起作用。该方案的广泛影响将包括培训研究生，特别是妇女和代表性不足的少数民族，并在夏季接待本科生和高中生。技术摘要这个NSF项目是一个创新的实验计划，将中子散射实验与实验室为基础的材料的努力，旨在获得一个基本的理解，在散装二维（2D）货车德瓦尔斯（vdW）磁性材料的磁序和自旋动力学。该计划的目的是探索和理解磁序的微观起源和2D vdW蜂窝和Kagomé晶格结构磁性材料的各个相的相互作用。特别是，该团队将专注于CrI 3，CrBr 3，CrCl 3，Cr（I，Br，Cl）3，Cr2 Ge 2 Te 6，alpha-RuCl 3和YMn 6Sn 6的大块单晶。该计划有三个组成部分：体单晶合成，初始材料表征和中子散射。该计划的重点将是中子散射。在合成方面，PI建立了一个综合材料实验室，可以生长拟议材料的单晶。这些单晶的初步表征将使用该小组的设施进行，包括原位单轴压力装置。中子散射将用于研究这些材料的磁序和自旋动力学性质。这些实验将在美国最好的设施中进行，包括橡树岭国家实验室（ORNL）的高通量同位素反应堆（HFIR）和Spiritual中子源（SNS），以及NIST中子研究中心（NCNR）。此外，当美国没有类似的能力时，欧洲和日本的世界级中子散射设施也将被利用。该奖项反映了NSF的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。

项目成果

Imaging real-space flat band localization in kagome magnet FeSn

• DOI: 10.1038/s43246-022-00328-1
• 发表时间: 2022-12
• 期刊: Communications Materials
• 影响因子: 7.8
• 作者: Daniel Multer;Jia-Xin Yin;M. S. Hossain;Xian P. Yang;B. Sales;Hu Miao;W. Meier;Yu-Xiao Jiang

Discovery of Charge Order and Corresponding Edge State in Kagome Magnet FeGe

Kagome 磁体 FeGe 中电荷序和相应边缘态的发现

• DOI: 10.1103/physrevlett.129.166401
• 发表时间: 2022
• 期刊: Physical Review Letters
• 影响因子: 8.6
• 作者: Yin Jia-Xin;Jiang Yu-Xiao;Teng Xiaokun;Hossain Md. Shafayat;Mardanya Sougata;Chang Tay-Rong;Ye Zijin;Xu Gang;Denner M. Michael;Neupert Titus;Lienhard Benjamin;Deng Han-Bin;Setty Ch;an;Si Qimiao;Chang Guoqing;Guguchia Zurab;Gao Bin;Shumiya Nana;Zhang Qi
• 通讯作者: Zhang Qi

Evidence for Topological Magnon-Phonon Hybridization in a 2D Antiferromagnet down to the Monolayer Limit

• DOI: 10.1021/acs.nanolett.3c00351
• 发表时间: 2023-02-16
• 期刊: NANO LETTERS
• 影响因子: 10.8
• 作者: Luo, Jiaming;Li, Shuyi;Zhu, Hanyu
• 通讯作者: Zhu, Hanyu

Spin structure and dynamics of the topological semimetal Co3Sn2-xInxS2

• DOI: 10.1038/s41535-022-00523-w
• 发表时间: 2022-11
• 期刊: npj Quantum Materials
• 影响因子: 5.7
• 作者: Kelly J. Neubauer;F. Ye;Yue Shi;P. Malinowski;B. Gao;K. Taddei;P. Bourges;A. Ivanov;J. Chu;P. Dai

Spin waves and Dirac magnons in a honeycomb-lattice zigzag antiferromagnet BaNi2(AsO4)2

• DOI: 10.1103/physrevb.104.214432
• 发表时间: 2021-12
• 期刊: Physical Review B
• 影响因子: 3.7
• 作者: B. Gao;Tong Chen;Chong Wang;Lebing Chen;R. Zhong;D. Abernathy;Di Xiao;P. Dai