Collaborative Research: Interfacial Engineering for Stabilizing Hybrid Perovskites and Devices

合作研究：稳定混合钙钛矿和器件的界面工程

• 批准号: 2131608
• 负责人: Letian Dou
• 金额: $ 25.59万
• 依托单位: Purdue University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2021
• 资助国家: 美国
• 起止时间: 2021-09-01 至 2024-08-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=2131608&HistoricalAwards=false
• 关键词: Collaborative; Research; Interfacial; Engineering; Stabilizing

AbstractNon-Technical SummaryHighly efficient and low-cost light emitting diodes (LEDs) are critical for the future energy landscape in the United States. They are widely used in displays and lighting. Current technologies use high temperature and high vacuum for materials processing and device fabrication, which are energy- and infrastructure-demanding. In this project, LED devices based on a new type of semiconductors—the so-called organic-inorganic hybrid perovskites—will be studied. These materials exhibit excellent optical and optoelectronic properties required for LED applications. In addition, they can be processed at low temperature under mild conditions, making the device fabrication and integration much easier. This research will enable future LED devices that are scalable and cost-effective. This project will also provide interdisciplinary training to undergraduate and graduate students, providing them with critical-thinking and problem-solving skills needed for future careers in areas of semiconductor technology.Technical SummaryOrganic-inorganic hybrid perovskites have shown tremendous potential for low-cost, energy-efficient optoelectronics (e.g. LEDs and solar cells). Development of viable devices based on the perovskites, however, has been inhibited by materials and device instability. Among the factors that are responsible for the performance loss, ion migration appears to be intrinsic to this new class of semiconductors and remains challenging to be circumvented. This project aims to identify new ways to stabilize perovskite-LEDs by interfacial engineering. Three questions that are critical to the success of the proposed research will be answered: (1) which interface in perovskite devices is more vulnerable to ion migration? (2) could the ion migration be suppressed by introducing “extrinsic” interlayers at the grain boundary and interface? (3) what are the suitable techniques for implementing such interlayers? Leveraging comprehensive expertise on materials chemistry and device physics, the collaborative team will unravel fundamental roles of the interfaces in materials degradation and provide a practical strategy for stabilizing perovskite devices. The ultimate goal of the project is to break the current ceiling of device stability and demonstrate perovskite-LEDs with 1000-hour operation lifetime. On a broader scope, the approach of interfacial engineering established in this project will also be applicable to other perovskite devices such as solar cells and photodetectors, which share many common features with perovskite-LEDs from materials selection to device architecture.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

【摘要】高效、低成本的发光二极管（led）对美国未来的能源格局至关重要。它们广泛用于显示和照明。目前的技术使用高温和高真空进行材料加工和器件制造，这对能源和基础设施要求很高。在这个项目中，基于一种新型半导体——所谓的有机-无机混合钙钛矿——的LED器件将被研究。这些材料具有LED应用所需的优异光学和光电子特性。此外，它们可以在温和的条件下在低温下加工，使器件的制造和集成更加容易。这项研究将使未来的LED器件具有可扩展性和成本效益。该项目还将为本科生和研究生提供跨学科培训，为他们提供半导体技术领域未来职业所需的批判性思维和解决问题的能力。有机-无机杂化钙钛矿在低成本、高能效光电子（如led和太阳能电池）方面显示出巨大的潜力。然而，基于钙钛矿的可行器件的开发一直受到材料和器件不稳定性的抑制。在导致性能损失的因素中，离子迁移似乎是这种新型半导体所固有的，并且仍然具有挑战性。该项目旨在通过界面工程确定稳定钙钛矿led的新方法。将回答三个对拟议研究成功至关重要的问题：(1)钙钛矿器件中的哪个界面更容易受到离子迁移的影响？(2)在晶界和界面处引入“外源”中间层能否抑制离子迁移？(3)实现这些中间层的合适技术是什么？利用材料化学和器件物理方面的综合专业知识，合作团队将揭示界面在材料降解中的基本作用，并提供稳定钙钛矿器件的实用策略。该项目的最终目标是打破目前器件稳定性的天花板，并展示具有1000小时工作寿命的钙钛矿led。在更广泛的范围内，本项目建立的界面工程方法也将适用于其他钙钛矿器件，如太阳能电池和光电探测器，这些器件从材料选择到器件结构都与钙钛矿- led具有许多共同特征。该奖项反映了美国国家科学基金会的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。

项目成果

Two-Factor Phase Separations in Mixed-Halide Quasi-2D Perovskite LEDs: Dimensionality and Halide Segregations

• DOI: 10.1021/acsenergylett.3c01009
• 发表时间: 2023-08
• 期刊: ACS Energy Letters
• 影响因子: 22
• 作者: Seok Joo Yang;Kan Wang;Yanqi Luo;Jee Yung Park;Hanjun Yang;Aidan H Coffey;Ke Ma;Jiaonan Sun