FMSG: Cyber: Establishing a Cyber-Physical Framework and Pilot System of Wavelength Selective Photopolymerization based Rapid Continuous Multi-Material Manufacturing

基于光聚合的3D打印是一种快速成型和制造的方法。通过以空间选择性的方式将光反应树脂暴露在光中，可以打印复杂的3D部件。这个未来制造种子资助(FMSG)网络制造项目将开发一种波长选择性3D打印的概念，其中在聚合过程中将使用紫外光和可见光波长，以在3D对象中实现不同的材料特性。该奖项支持一项系统的基础研究，为基于波长选择性光聚合的多材料3D打印的发展提供知识和能力。预计这项技术将有许多应用，包括柔性电子学、软机器人、建筑材料和生物组织。该项目促进了美国在先进制造业中的领导地位，促进了科学进步，促进了国家繁荣。它将拥有3D打印、聚合物化学、传感器和机器人等不同专业知识的研究人员团结在一起。研究人员将在本科生和K-12阶段就3D打印技术进行外展，通过与当地一所公立学校和科学博物馆的合作，吸引不同的学生进入STEM领域。3D打印技术旨在解决对先进技术的迫切需求，以快速和连续地制造多材料部件。这种3D打印方法简化了材料切换方法，避免了重新对准和清洁的繁琐步骤。具体地说，目前多材料光聚合印花需要的是“树脂换缸”，只允许层与层之间的材料变化，而不允许每一层内的材料变化。这项研究将填补双波长光聚合3D打印基本机理的知识空白，包括化学动力学、相变、热力学和界面力学。本项目开发了一个多物理模型和模拟方法，以阐明两种并发和不同的光聚合途径，以实现不同的性质。另一个推力是一个用于现场监测新工艺的高度仪表化的平台，具有新的现场光学干涉测量技术，可以提供独特的多固化工艺动态的无法实现的实时全场洞察。最终，新的过程-结构-性能关系将通过对理论模型模拟、现场监测和异地表征的数据的机器学习来量化。研究成果将促进新兴的多波长光聚合打印、新型光化学和聚合物以及多材料3D打印的新应用的研究。该奖项由ENG董事会的CMMI部门和MPS董事会的CHE部门支持。该奖项反映了NSF的法定使命，并通过使用基金会的智力优势和更广泛的影响审查标准进行评估，被认为值得支持。

Photopolymerization-based 3D printing is a method for rapid prototyping and manufacturing. Complex 3D parts can be printed by exposing a photoreactive resin to light in a spatially-selective manner. This Future Manufacturing Seed Grant (FMSG) CyberManufacturing project will develop a concept of wavelength-selective 3D printing wherein both ultraviolet and visible wavelengths of light will be used during polymerization to realize distinct material properties within a 3D object. This award supports a systematic fundamental study to provide knowledge and capabilities for the development of multi-material 3D printing based on wavelength-selective photopolymerization. Numerous applications are envisaged for this technology, ranging from flexible electronics, soft robotics, architected materials, and biological tissues. This project promotes US leadership in advanced manufacturing, promote scientific progress, and increase national prosperity. It unites researchers with diverse expertise including 3D printing, polymer chemistry, and sensors and robotics. The investigators will conduct outreach at undergraduate and K-12 level on 3D printing technology to attract diverse students towards STEM fields via collaborations with a local public school and science museum.A 3D printing technology aims to address the pressing need for an advanced technology to fabricate multi-material parts rapidly and continuously. This 3D printing method simplifies the material switch-over method avoiding tedious steps of re-alignment and cleaning. Specifically, at present, multi-material photopolymerization printing requires "resin vat changes", which only permits material variation between layers, but not within each layer. This research will fill the knowledge gap on fundamental mechanisms of two-wavelength photopolymerization 3D printing including chemical kinetics, phase transition, thermodynamics, and interfacial mechanics. This project develops a multi-physics model and simulation method for elucidating the two concurrent and different photopolymerization pathways to realize distinct properties. An additional thrust is a highly instrumented platform for in-situ monitoring of the new process, featuring a novel in-situ optical interferometry that can provide otherwise unattainable real-time full-field insights of the unique multi-curing process dynamics. Ultimately, the new process-structure-property relations will be quantified by machine learning of the data from theoretical model simulation, in-situ monitoring, and ex-situ characterization. The research outcomes will facilitate the research on emerging multi-wavelength photopolymerization printing, new photo chemistries and polymers, and novel applications of multi-material 3D printing. This award is supported by the CMMI Division in the ENG Directorate and the CHE Division in the MPS Directorate.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.